圆偏振光在手性聚合物合成与结构调控中的应用

杨光; 何晨露; 邹纲

doi:10.11777/j.issn1000-3304.2017.17167

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圆偏振光在手性聚合物合成与结构调控中的应用

专论 | 更新时间：2021-01-26

- 圆偏振光在手性聚合物合成与结构调控中的应用
- Synthesis of Optically Active Polymer and Structural Modulation Using Circularly Polarized Light
- 高分子学报 2017年第11期页码：1725-1738
- 作者机构：
  
  中国科学院软物质化学重点实验室中国科技大学合肥 230026
- 作者简介：
  
  [ "邹纲, 男, 1976年8月生.1999和2004年分别获得中国科学技术大学化学和高分子化学与物理专业理学学士、博士学位.2004~2006年在日本东京工业大学从事博士后工作, 入选日本学术振兴会外国人特别研究员\"JSPS Fellow\".2014年7月至今, 任中国科学技术大学化学与材料学院教授, 博士生导师.2016年获安徽省杰出青年科学基金资助.主要研究方向包括手性共轭聚合物的合成及螺旋结构调控、环境响应共轭聚合物功能材料" ]
- 基金信息：
  
  国家自然科学基金(21574120);国家自然科学基金(21774115)
- DOI：10.11777/j.issn1000-3304.2017.17167
  中图分类号：
- 纸质出版日期：2017-11-20，
  
  收稿日期：2017-6-26，
  
  修回日期：2017-7-20，
扫描看全文
杨光, 何晨露, 邹纲. 圆偏振光在手性聚合物合成与结构调控中的应用[J]. 高分子学报, 2017,(11):1725-1738.

Yang Guang, He Chen-lu, Zou Gang. Synthesis of Optically Active Polymer and Structural Modulation Using Circularly Polarized Light[J]. Acta Polymerica Sinica, 2017,(11):1725-1738.
杨光, 何晨露, 邹纲. 圆偏振光在手性聚合物合成与结构调控中的应用[J]. 高分子学报, 2017,(11):1725-1738. DOI： 10.11777/j.issn1000-3304.2017.17167.

Yang Guang, He Chen-lu, Zou Gang. Synthesis of Optically Active Polymer and Structural Modulation Using Circularly Polarized Light[J]. Acta Polymerica Sinica, 2017,(11):1725-1738. DOI： 10.11777/j.issn1000-3304.2017.17167.

摘要

手性是自然界中普遍存在的有趣现象之一，在生命体中手性大分子特有的不对称结构在维持生命过程、新陈代谢和进化等面均起着决定性作用.受此启发，合成具有新型结构的光学活性聚合物，研究其独特的物理化学性质和功能已成为当今高分子领域研究的热点.左旋和右旋的圆偏振光已被广泛应用于氨基酸衍生物的不对称光合成、光分解和去消旋化反应，以及诱导含有偶氮苯或三苯胺等特定功能基团的超分子组装体或无机纳米粒子形成稳定螺旋结构.本文详细地介绍了圆偏振光辐照在手性聚合物合成与螺旋结构调控中的应用，初步揭示了圆偏振光的作用机制以及优势，归纳总结了已取得的研究进展，并对圆偏振光在手性聚合物合成与结构调控中的应用及发展进行了简单的评述和展望.

Abstract

Helical conformation is a representative secondary structure of biomacromolecules such as DNA and proteins in nature

and plays an important role in the metabolism of organisms. Partially inspired by such natural biological helices

considerable studies have been conducted on the design and synthesis of polymers with stable helical conformations in recent decades. The objectives of these researches are not only to mimic the structure and function of biological helices

but also to widen their applications in many fields

as helical polymers can display optical activity based solely on their main-chain helical conformation. In the past decades

various helical polymers

including polythiophene

polypyrrole

polyaniline and polydiacetylene (PDA)

have been synthesized through asymmetric polymerization

which can proceed if chiral monomers

dopants or catalysts are involved

or if some external chiral influence is present. One such external influence is circularly polarized light (CPL)

which is inherently chiral and has been regarded as one source for the origin of homochirality in nature. Left-and right-handed CPL have been applied in asymmetry photochemical reactions including photosynthetic or photolytic

and modulated the helical structure in supramolecular assemblies of azobenzene-containing compounds and inorganic nanoparticles. In this paper

CPL-triggered enantio-selective synthesis of optically active polymers

including helical polydiacetylene

chiral coordination polymers

chiral linear and hyperbranched polymers

are reviewed for the great efforts done towards the understanding of the mechanism of CPL-triggered enantio-selective polymerization

and the applications of CPL to induce chiral packing structure into azobenzene-containing polymers

polyfluorene and photo-responsive ketone-containing polymers. The enantioselective interaction between CPL and the enantiomers possibly played a key role in above asymmetric photo-polymerization reactions and the helical structural modulation. The unique features

the advantages of CPL-triggered enantio-selective synthesis of chiral polymers as well as modulation of the helical structure

and the involved mechanism are simply revealed. The progress up to now is summarized and a short prospect concerning the development of CPL triggered asymmetry photo-synthesis and structural modulation have been also provided.

关键词

圆偏振光手性聚合物不对称聚合螺旋结构调控

Keywords

Circularly polarized lightChiral polymerAsymmetry photo-polymerizationModulation of helical structure

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