稠环电子受体光伏材料

代水星; 占肖卫

doi:10.11777/j.issn1000-3304.2017.17214

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稠环电子受体光伏材料

专论 | 更新时间：2021-01-26

- 稠环电子受体光伏材料
- Fused-ring Electron Acceptors for Organic Solar Cells
- 高分子学报 2017年第11期页码：1706-1714
- 作者机构：
  
  北京大学工学院北京 100871
- 作者简介：
  
  [ "占肖卫, 男, 1967年8月生, 北京大学工学院教授、博士生导师、材料系副系主任、高分子化学与物理教育部重点实验室副主任.1986~1990年, 浙江大学化学系本科.1993~1998年, 浙江大学高分子系博士.1998~2000年, 中国科学院化学研究所博士后, 其中, 1999年, 香港科技大学化学系访问学者.2000~2002年, 中国科学院化学研究所副研究员.2002~2003年, 美国亚利桑那大学化学系博士后.2003~2006年, 美国佐治亚理工大学化学系博士后.2006~2012年, 中科院化学所研究员.2012年至今, 北京大学工学院教授.2002年获中国化学会青年化学奖.2006年入选中科院\"百人计划\", 并在终期评估中获得优秀.2010年获国家杰出青年科学基金资助.2013年担任副主编, 2014年入选英国皇家化学会会士.主要研究方向为有机高分子光电功能材料和器件" ]
- 基金信息：
  
  国家自然科学基金(21734001);国家自然科学基金(91433114);国家自然科学基金(21673011)
- DOI：10.11777/j.issn1000-3304.2017.17214
  中图分类号：
- 纸质出版日期：2017-11-20，
  
  收稿日期：2017-8-3，
  
  修回日期：2017-8-27，
扫描看全文
代水星, 占肖卫. 稠环电子受体光伏材料[J]. 高分子学报, 2017,(11):1706-1714.

Dai Shui-xing, Zhan Xiao-wei. Fused-ring Electron Acceptors for Organic Solar Cells[J]. Acta Polymerica Sinica, 2017,(11):1706-1714.
代水星, 占肖卫. 稠环电子受体光伏材料[J]. 高分子学报, 2017,(11):1706-1714. DOI： 10.11777/j.issn1000-3304.2017.17214.

Dai Shui-xing, Zhan Xiao-wei. Fused-ring Electron Acceptors for Organic Solar Cells[J]. Acta Polymerica Sinica, 2017,(11):1706-1714. DOI： 10.11777/j.issn1000-3304.2017.17214.

摘要

基于非富勒烯受体的有机太阳能电池是化学和材料领域的热点前沿之一，中国领跑这个热点前沿.中国学者在非富勒烯受体材料方面取得了一系列重要的创新成果.我们提出了"稠环电子受体（FREA）"这一新概念，构建了高性能稠环电子受体新体系，发明了明星分子ITIC.我们的原创性工作引起了国内外同行的广泛关注和跟进.目前，基于稠环电子受体的有机太阳能电池效率已达到13%~14%，超过富勒烯体系.ITIC等稠环电子受体的出现颠覆了富勒烯受体在有机太阳能电池领域的统治地位，开创了有机太阳能电池的非富勒烯时代.本文简要评述了我们在高性能稠环电子受体设计与器件应用中的研究进展，并展望稠环电子受体的未来发展.

Abstract

Nonfullerene organic solar cell (OPV) is one of the hottest frontiers in chemistry and materials science. China has been leading this hot frontier

and Chinese researchers have made great contribution to this research field. We proposed a novel concept-fused-ring electron acceptor (FREA)

established a brand-new

high-performance nonfullerene acceptor system

and invented star molecule ITIC. These FREAs show some advantages:(1) they have high electron mobility similar to those of fullerenes; (2) they exhibit strong and broad absorption

especially in the 700-1000 nm range

and can match with wide-bandgap donor materials to achieve complementary absorption; (3) their energy level can be tuned and thus they match with various high-performance electron donors; (4) their crystallinity and film morphology can be tuned; (5) their synthesis is easy to scale up. Our original and pioneering work has received extensive attention. FREAs are now commercial available. Many well-known research groups across the world have already utilized these FREAs to fabricate high-efficiency OPV. FREA-based OPV now has achieved a power conversation efficiency of 13%-14%

surpassing the fullerene counterpart. Moreover

the FREA-based OPV exhibits better device stability than the fullerene-based counterpart. The emergence of ITIC-like FREAs has overturned predominant position of fullerene acceptor in OPV and is inaugurating the nonfullerene OPV era. In this review

we summarize our progress of FREA design and application in OPV

and give an outlook of the FREAs. We first introduce the background information

concept and working mechanism of OPV; then the advantages and disadvantages of fullerene acceptors are compared with nonfullerene acceptors; and the concept and merits of FREAs are finally discussed. The main text focuses on fused-ring core engineering

electron-withdrawing group engineering and side chain engineering

and we emphasize effects of electron-donating fused-ring cores

electron-withdrawing end groups and side chains on solubility

crystallinity

energy levels

absorption spectra

electron mobilities and photovoltaic properties of FREAs.

关键词

稠环电子受体非富勒烯受体有机太阳能电池

Keywords

Fused-ring electron acceptorNonfullerene acceptorOrganic solar cell

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