防冰高分子材料

吕健勇; 贺志远; 王健君

doi:10.11777/j.issn1000-3304.2017.17216

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防冰高分子材料

专论 | 更新时间：2021-01-26

- 防冰高分子材料
- Recent Research on Polymeric Anti-icing Materials
- 高分子学报 2017年第12期页码：1870-1882
- 作者机构：
  
  中国科学院化学研究所北京 100190
- 作者简介：
  
  [ "王健君, 男, 1976年2月生, 中国科学院化学研究所研究员, 博士生导师.1999年获华东理工大学学士学位; 2002年获华东理工大学硕士学位; 2006年获德国美因茨大学博士学位; 2007年5月担任德国马普高分子所课题组长; 2010年2月在中国科学院化学研究所工作, 任研究员/课题组长.主要研究方向为防冰防霜理论、防冰防霜高分子材料设计、制备与应用等" ]
- 基金信息：
  
  国家自然科学基金重点项目(51436004);国家自然科学基金委员会创新研究群体项目(21421061)
- DOI：10.11777/j.issn1000-3304.2017.17216
  中图分类号：
- 纸质出版日期：2017-12-20，
  
  收稿日期：2017-8-4，
  
  修回日期：2017-9-1，
扫描看全文
吕健勇, 贺志远, 王健君. 防冰高分子材料[J]. 高分子学报, 2017,(12):1870-1882.

Jian-yong Lv, Zhi-yuan He, Jian-jun Wang. Recent Research on Polymeric Anti-icing Materials[J]. Acta Polymerica Sinica, 2017,(12):1870-1882.
吕健勇, 贺志远, 王健君. 防冰高分子材料[J]. 高分子学报, 2017,(12):1870-1882. DOI： 10.11777/j.issn1000-3304.2017.17216.

Jian-yong Lv, Zhi-yuan He, Jian-jun Wang. Recent Research on Polymeric Anti-icing Materials[J]. Acta Polymerica Sinica, 2017,(12):1870-1882. DOI： 10.11777/j.issn1000-3304.2017.17216.

摘要

防冰高分子材料作为一种新型功能高分子材料，在电力、通讯及运输等领域有广泛应用.表面的覆冰现象往往开始于冰的成核，发展于冰的传递，危害于冰的积聚.针对材料表面冰晶形成的环节，揭示冰晶形成的分子机制是设计和开发防冰高分子材料的关键.本文简要介绍了本课题组在防冰高分子材料领域的研究进展，包括设计搭建的基本研究设备，以及具有调控冰成核、控制冰传递、降低冰黏附等不同功能的防冰高分子材料.

Abstract

Anti-icing polymeric materials have attracted extensive interest and concerns

as undesired ice accumulation always leads to inconvenience and disasters

in extreme cases even loss of lives of human beings. To deal with the icing problem

molecular mechanisms of ice formation have to be unravelled

which have been pending for more than one hundred years. In this review

we firstly introduce basic instruments for investigating ice formation. In order to reliably evaluate the capability of surfaces on tuning ice nucleation

propagation and adhesion

instruments with controlled environmental conditions

such as humidity and surface temperature

are required. We discuss the set-ups built in our lab for investigating the properties of anti-icing materials. Then we summarize our recent research progress on polymeric materials that can tune ice nucleation

control ice propagation

and reduce ice adhesion. The initial and control step for ice formation is ice nucleation

which often starts on foreign surfaces

i.e

heterogeneous nucleation

and different surfaces possess distinct capabilities in tuning ice nucleation.

Via

. investigating and mimicking the mechanism of antifreeze proteins in the body of organisms living in cold environments

we fabricated polymeric surfaces for regulating the ice nucleation temperature. When ice nucleation triggers freezing of water droplets

ice propagation from frozen water droplets to unfrozen ones follows. In this case

polymeric materials with the functionality of trapping different amount of free water was developed and applied to inhibit ice propagation. Once ice accumulates on solid surfaces

one of the anti-icing strategies is to minimize ice adhesion for easy de-icing. Polymeric materials with aqueous lubricating layer have been prepared and ice on the surface could be blown off under a strong breeze. In addition

solid organogel material with a regenerable solid surface layer is proposed to improve the durability of the materials.

关键词

防冰高分子材料冰成核冰传递冰黏附

Keywords

Anti-icingPolymeric functional materialIce nucleationIce propagationIce adhesion

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