高分子复合物纤维的研究进展

刘德中; 李皆富; 黄文弢; 杨曙光

doi:10.11777/j.issn1000-3304.2017.17285

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高分子复合物纤维的研究进展

综述 | 更新时间：2021-01-26

- 高分子复合物纤维的研究进展
- Progress in Polymer Complex Fibers
- 高分子学报 2018年第4期页码：445-455
- 作者机构：
  
  纤维材料改性国家重点实验室东华大学先进低维材料中心材料与科学工程学院上海 201620
- 作者简介：
  
  杨曙光, E-mail: shgyang@dhu.edu.cn Shu-guang Yang, E-mail: shgyang@dhu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.17285
  中图分类号：
- 纸质出版日期：2018-4-20，
  
  收稿日期：2017-10-16，
  
  修回日期：2017-11-11，
扫描看全文
刘德中, 李皆富, 黄文弢, 杨曙光. 高分子复合物纤维的研究进展[J]. 高分子学报, 2018,(4):445-455.

De-zhong Liu, Jie-fu Li, Wen-tao Huang, Shu-guang Yang. Progress in Polymer Complex Fibers[J]. Acta Polymerica Sinica, 2018,(4):445-455.
刘德中, 李皆富, 黄文弢, 杨曙光. 高分子复合物纤维的研究进展[J]. 高分子学报, 2018,(4):445-455. DOI： 10.11777/j.issn1000-3304.2017.17285.

De-zhong Liu, Jie-fu Li, Wen-tao Huang, Shu-guang Yang. Progress in Polymer Complex Fibers[J]. Acta Polymerica Sinica, 2018,(4):445-455. DOI： 10.11777/j.issn1000-3304.2017.17285.

摘要

功能化和智能化是纤维发展的趋势.单一组分纤维难以满足日益发展的需求，而多组分纤维能够集中不同组分的特点，实现性能的集成与优化.通过非共价相互作用，高分子聚集而形成多组分均相体系，称为高分子复合物.利用高分子复合物的形成过程使纤维成型；或者直接利用高分子复合物进行纺丝而得到的纤维称为高分子复合物纤维.高分子复合物纤维，各组分可以达到分子层面上的相容性，给我们提供了一个功能纤维和智能纤维设计开发的平台.本文详细阐述了各类高分子复合物纤维的研究现状，并展望高分子复合物纤维的未来发展.

Abstract

Functionalization and intelligentialization are the trends of the fiber development. The single component fiber is hard for performace optimization. The multi-component fiber could combine the characteristic of different components

and realize the properties integration and optimization. Different polymers aggregate together based on non-covalent bonds to form homogenous phase

which is defined as polymer complex. Polymer complex can be classified into several categories according to their characteristic rmolecular interaction

including polyelectrolyte complex

stereocomplex

hydrogen-bonded complex

inclusion complex

polymer-metal complex and charge-transfer complex. Polymer complex fibers are defined as those prepared through polymer complexation process or by directly spinning polymer complex. In polymer complex fibers

different polymers have miscibility on the molecular level

which provides a platform to design the functionality and to futher explore intelligentialization. Polymer complex fibers could be retrospected to stereocomplex fibers in early 1990s

but the mainly investigated ones were polyelectrolyte complex fibers (polyion complex fibers). Recently

hydrogen-bonded polymer complex fibers have been reported. Wan

et al

. made a review on polyelectrolyte complex fibers. But up to now

there is no unified concept for polymer complex fiber. This review collects research works on fibers of different types of compexes

and puts forward to the concept of polymer complex fibers. Different approaches that adopted to fabricate polymer complex fibers

like interfacial drawing

coaxial spinning

and electrospinning

are discussed. The review summarizes the properties of polymer complex fibers

such as conductivity

fluorescence

and elasticity

and focuses on their apllications in separation

controlled release

tissue engineering

anti-bacterials and catalysis. Using newly synthetized polymers or modified polymers to fabricate polymer complex fibers with multi-functionality and developing new methods and technologies to improve the efficiency of fiber fabrication are our effort directions of polymer complex fiber research.

关键词

纤维高分子复合物聚电解质氢键多组分多功能

Keywords

Polymer complexPolyelectrolyteHydrogen bondingMulticomponentMultifunction

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