纳米多孔有机聚合物电化学应用研究

陈东洋; 刘程; 王锦艳; 潘春跃; 喻桂朋; 蹇锡高

doi:10.11777/j.issn1000-3304.2017.17298

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纳米多孔有机聚合物电化学应用研究

综述 | 更新时间：2021-01-26

- 纳米多孔有机聚合物电化学应用研究
- Research Progress on the Electrochemical Application of Nanoporous Organic Polymers
- 高分子学报 2018年0卷第5期页码：559-570
- 作者机构：
  
  1.中南大学化学化工学院　长沙 410083
  2.大连理工大学精细化工国家重点实验室　大连 116012
- 作者简介：
  
  E-mail: gilbertyu@csu.edu.cn Gui-peng Yu, E-mail: gilbertyu@csu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 21674129，21376272)资助项目()
- DOI：10.11777/j.issn1000-3304.2017.17298
  中图分类号：
- 纸质出版日期：2018-5，
  
  收稿日期：2017-10-27，
  
  修回日期：2017-11-28，
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陈东洋, 刘程, 王锦艳, 潘春跃, 喻桂朋, 蹇锡高. 纳米多孔有机聚合物电化学应用研究[J]. 高分子学报, 2018,0(5):559-570.

Dong-yang Chen, Cheng Liu, Jin-yan Wang, Chun-yue Pan, Gui-peng Yu, Xi-gao Jian. Research Progress on the Electrochemical Application of Nanoporous Organic Polymers[J]. Acta Polymerica Sinica, 2018,0(5):559-570.
陈东洋, 刘程, 王锦艳, 潘春跃, 喻桂朋, 蹇锡高. 纳米多孔有机聚合物电化学应用研究[J]. 高分子学报, 2018,0(5):559-570. DOI： 10.11777/j.issn1000-3304.2017.17298.

Dong-yang Chen, Cheng Liu, Jin-yan Wang, Chun-yue Pan, Gui-peng Yu, Xi-gao Jian. Research Progress on the Electrochemical Application of Nanoporous Organic Polymers[J]. Acta Polymerica Sinica, 2018,0(5):559-570. DOI： 10.11777/j.issn1000-3304.2017.17298.

摘要

纳米多孔有机聚合物(nanoporous organic polymers

NOPs)是一类由轻元素组成的新型高分子材料，具有比表面积大、孔容高、化学和物理性质稳定等优点，在电化学领域表现出巨大的应用潜力. 其合成方法多样，孔结构可控，表面易修饰更推进了NOPs在电化学应用的快速发展. 本文总结了NOPs在电化学应用的研究进展，重点介绍NOPs的骨架改性和孔结构调控对电化学性能的影响，分析其分子结构和聚集态结构与性能的构效关系，展望了其在电化学领域未来的发展趋势.

Abstract

As new emerged polymer materials

nanoporous organic polymers (NOPs)

derived completely from light elements

are featured by high surface areas

low skeleton densities

and good chemical and thermal stabilities

which have led to numerous potential applications in heterogeneous catalysis

gas storage

and separation. Furthermore

their versatile synthetic methodology

controllable pore structure and easy modification significantly accelerate their development. Recently

the applications of NOPs targeted for organic electronic devices and solid state sensors have drawn increasing attention. The study of NOP-based electrochemical sensor technologies has become a very active and robust research area

and is expected to provide high-performance technologies for electrode materials

electrocatalytic carrier

and electrochemical detection

etc

. One potential advantage of these materials is derived from their porous robust frameworks with high accessible surface areas

which enable structural preservation and efficient metal uptake and diffusion. However

the weak electron transport and wettability of NOPs somewhat limit their practical application in electrochemistry. In response

novel strategies have been developed to enhance their conductivity and wettability

including the incorporation of heteroatoms

extending of the skeleton conjugation

and the introduction of metal sites into the porous networks. Especially

the introduction of heteroatoms into the electrode materials is the mostly utilized technology

because it not only enables the increase in conductivity

wettablity and electroactive surface area of the electrodes

but also endows the electrodes with high pseudocapacitance. Furthermore

pore-size engineering

i.e.

enhancing microporosity and constructing hierarchical structure

is crucial to improve the electrochemical performance. Hierarchically porous materials used as electrode matrices appear to be much more favorable for mass loading and ion diffusion or transport

endowing them with technological importance for applications in energy storage and sensor applications. This study summarizes recent research progress of NOPs in electrochemical applications

focuses on rational design

pore engineering and the structure-electrochemical property relationship

and also prospects their future development.

关键词

纳米多孔有机聚合物电极材料电催化电化学性能

Keywords

Nanoporous organic polymersElectrode materialsElectrocatalysisElectrochemical properties

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