有机及有机无机杂化太阳电池中的界面研究

许景琦; 傅伟飞; 杨时达; 刘唐; 李昌治; 陈红征

doi:10.11777/j.issn1000-3304.2018.17251

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有机及有机无机杂化太阳电池中的界面研究

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- 有机及有机无机杂化太阳电池中的界面研究
- Interface Engineering in Organic and Organic/Inorganic Hybrid Solar Cells
- 高分子学报 2018年第2期页码：164-173
- 作者机构：
  
  浙江大学高分子科学与工程学系杭州 310027
- 作者简介：
  
  [ "傅伟飞, 男, 1988年出生.2006~2010年, 浙江大学高分子系大学本科.2010~2015年, 浙江大学高分子系博士.2015~2017年, 浙江大学高分子系博士后.2017年9月至今, 美国华盛顿大学博士后.主要研究方向为有机无机复合光电器件" ]
  [ "陈红征, 女, 1966年出生, 浙江大学求是特聘教授, 博士生导师.国家杰出青年基金获得者(2002年), 入选教育部跨世纪优秀人才培养计划(2001年), 中国化学会青年化学奖获得者(2000年), 浙江省\"151人才工程\"入选者(2000年).1988年浙江大学本科毕业, 1994年浙江大学博士毕业后留校任教, 1999年晋升为教授.先后在香港科技大学、比利时Antewerp大学和欧洲高校微电子中心(IMEC)、美国Stanford大学进行访问研究.主要从事有机高分子光电功能材料与器件的研究与教学工作" ]
- 基金信息：
  
  国家自然科学基金(21734008);国家自然科学基金(51620105006);国家自然科学基金(21722404);国家自然科学基金(51473142);科技部国际合作项目(2016YFE0102900);国家重点基础研究发展计划973计划(2014CB643503)
- DOI：10.11777/j.issn1000-3304.2018.17251
  中图分类号：
- 纸质出版日期：2018-2-20，
  
  收稿日期：2017-9-1，
  
  修回日期：2017-9-27，
扫描看全文
许景琦, 傅伟飞, 杨时达, 刘唐, 李昌治, 陈红征. 有机及有机无机杂化太阳电池中的界面研究[J]. 高分子学报, 2018,(2):164-173.

Jing-qi Xu, Wei-fei Fu, Shi-da Yang, Tang Liu, Chang-zhi Li, Hong-zheng Chen. Interface Engineering in Organic and Organic/Inorganic Hybrid Solar Cells[J]. Acta Polymerica Sinica, 2018,(2):164-173.
许景琦, 傅伟飞, 杨时达, 刘唐, 李昌治, 陈红征. 有机及有机无机杂化太阳电池中的界面研究[J]. 高分子学报, 2018,(2):164-173. DOI： 10.11777/j.issn1000-3304.2018.17251.

Jing-qi Xu, Wei-fei Fu, Shi-da Yang, Tang Liu, Chang-zhi Li, Hong-zheng Chen. Interface Engineering in Organic and Organic/Inorganic Hybrid Solar Cells[J]. Acta Polymerica Sinica, 2018,(2):164-173. DOI： 10.11777/j.issn1000-3304.2018.17251.

摘要

第3代可溶液加工的太阳电池（包括有机太阳电池、钙钛矿太阳电池等），因为制备成本低、可制备柔性器件等特点备受关注.它们的迅速发展与活性层材料、界面材料与修饰以及器件工程等方面的快速发展息息相关，其中器件中的各个界面对激子的分离、载流子传递和收集有着巨大的影响，影响着器件的性能.本文重点介绍了近年来我们课题组在有机太阳电池、聚合物/量子点杂化太阳电池以及钙钛矿太阳电池研究中，如何设计界面材料以及通过自组装层对电极进行界面修饰，实现活性层和电极之间的欧姆接触和载流子的有效收集；如何在界面层中引入具有等离激元效应的纳米粒子实现光场的有效利用和性能的提升；以及如何对聚合物和纳米粒子间的界面修饰实现载流子的高效分离，制备高性能的杂化太阳电池器件.

Abstract

Third generation solar cells including organic solar cells

perovskite solar cells have attracted much attention due to their advantages of low cost

solution processability and flexibility. The rapid progress in this field is attributed to the development of absorbing layers

interfacial materials or interfacial modification

device architectures and so on. Especially

the interfaces in the devices significantly affect the exciton dissociation

charge carrier transport and collection

and subsequently affect the device performance. This review focuses on the interface engineering in organic solar cells

polymer/nanocrystal hybrid solar cells and perovskite solar cells in our group. We summarize the strategies of designing effective interfacial materials including hole-transporting materials

electron-transporting materials and their modification to achieve ohmic contact at the interface of active layer and electrodes. A series of low-temperature solution processed low-cost inorganic materials and organic small molecules are developed. With appropriate energy levels

high mobility and low defect or ability to passivate perovskites

highly efficient organic and perovskite solar cells are achieved. Self-assembly monolayer technologies are also discussed here. It is an efficient way to modify the work function of electrodes to obtain ohmic contact between electrodes and active layer. On one hand

the self-assembly monolayer can also be used to passivate the defect of metal oxide buffer layer such as ZnO or TiO

to reduce recombination

which may improve the morphology of perovskite film to enhance the performance. Plasmonic effect is introduced to enhance the light absorption of active layer by incorporating Au or Ag nanoparticles into the interface layers. At last

the optimized strategies for interface modification between polymer and nanocrystals to improve the exciton dissociation and charge transport are discussed in details. By attaching benzenedithiol ligands onto the surface of CdSe nanocrystals in the "face-on" geometry

the nanocrystal-nanocrystal or polymer-nanocrystal distance is minimized. Furthermore

the "electroactive"

-orbitals of the benzenedithiol can further enhance the electronic coupling

which facilitates charge carrier dissociation and transport. On the other hand

judicious choice of ligands with appropriate molecular dipoles has a strong impact on chemical and electronic structures at the polymer-nanocrystal interface and subsequently on photovoltaic device performance. With these strategies

highly efficient polymer/CdSe nanocrystal hybrid solar cells have been achieved. A few viewpoints on further developing interface engineering for high-performance solar cells are also provided.

关键词

界面材料自组装层等离激元太阳电池

Keywords

Interfacial materialsSelf-assembly monolayerPlasmonic effectSolar cell

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