基于吡咯并吡咯二酮的二元和三元共轭聚合物的光电性能研究

章中强; 刘志玺; 严康荣; 李焕斌; 刘文清; 路新慧; 李寒莹; 陈红征; 李昌治

doi:10.11777/j.issn1000-3304.2018.17253

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基于吡咯并吡咯二酮的二元和三元共轭聚合物的光电性能研究

研究论文 | 更新时间：2021-01-26

- 基于吡咯并吡咯二酮的二元和三元共轭聚合物的光电性能研究
- Photovoltaic Properties of DPP-based Two-and Three-component Polymers
- 高分子学报 2018年第2期页码：295-303
- 作者机构：
  
  1.浙江大学高分子科学与工程学系硅材料国家重点实验室杭州 310027
  2.香港中文大学物理系香港
- 作者简介：
  
  李昌治, E-mail: czli@zju.edu.cn Chang-Zhi Li, E-mail: czli@zju.edu.cn
- 基金信息：
  
  国家自然科学基金(51620105006);国家自然科学基金(21722404);科技部国际合作项目(2016YFE0102900);国家重点基础研究发展计划973计划(2014CB643503);国家自然科学基金(21674093);浙江省自然科学基金杰出青年科学基金(LR17E030001)
- DOI：10.11777/j.issn1000-3304.2018.17253
  中图分类号：
- 纸质出版日期：2018-2-20，
  
  收稿日期：2017-9-4，
  
  修回日期：2017-9-19，
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章中强, 刘志玺, 严康荣, 李焕斌, 刘文清, 路新慧, 李寒莹, 陈红征, 李昌治. 基于吡咯并吡咯二酮的二元和三元共轭聚合物的光电性能研究[J]. 高分子学报, 2018,(2):295-303.

Zhong-qiang Zhang, Zhi-xi Liu, Kang-rong Yan, Huan-bin Li, Wen-qing Liu, Xin-hui Lu, Han-ying Li, Hong-zheng Chen, Chang-zhi Li. Photovoltaic Properties of DPP-based Two-and Three-component Polymers[J]. Acta Polymerica Sinica, 2018,(2):295-303.
章中强, 刘志玺, 严康荣, 李焕斌, 刘文清, 路新慧, 李寒莹, 陈红征, 李昌治. 基于吡咯并吡咯二酮的二元和三元共轭聚合物的光电性能研究[J]. 高分子学报, 2018,(2):295-303. DOI： 10.11777/j.issn1000-3304.2018.17253.

Zhong-qiang Zhang, Zhi-xi Liu, Kang-rong Yan, Huan-bin Li, Wen-qing Liu, Xin-hui Lu, Han-ying Li, Hong-zheng Chen, Chang-zhi Li. Photovoltaic Properties of DPP-based Two-and Three-component Polymers[J]. Acta Polymerica Sinica, 2018,(2):295-303. DOI： 10.11777/j.issn1000-3304.2018.17253.

摘要

设计合成了基于吡咯[3，4-c]并吡咯二酮（DPP）和烷氧基苯的二元共轭聚合物

，并通过聚合中分别引入缺电子性第三单体二氟代苯并噻二唑（DFBT）和萘二酰亚胺（NDI），进一步得到三元聚合物

和

.结果显示，缺电子第三单体的设计引入能调节聚合物的吸光、能级并改变聚合物在薄膜状态下的聚集行为，从而影响材料的聚合物太阳能电池光电转换效率和有机场效应晶体管电荷迁移率，采取face-on聚集取向的

在太阳电池中表现更好，而edge-on取向的

则在晶体管中表现出更高的空穴迁移率.

Abstract

Diketopyrrolopyrrole (DPP) is attractive for building conjugated polymers for polymer solar cell (PSC) and organic field effect transistor (OFET). Yet the usual access to DPP conjugated polymers is

via

donor-acceptor (D-A) two-component polymerization. However

the number of excellent polymers based on the D-A combination is still limited

which promotes researchers to explore new strategy for preparation of novel conjugated polymers and to understand their structure-property relationship. In this work

a DPP-based polymer

was first obtained with co-polymerization of DPP (A) and alkoxyl benzene (D). Further

two novel polymers (

and

) were developed

via

introducing a third electron-deficient monomer X (difluoro-benzothiadiazole or naphthalene diimide) in the polymerization process.

polymers (molecular weight:3.83×10

5.30×10

and 6.56×10

) showed good solubility in common organic solvents. Due to the hybridization of the molecular orbitals between their three components (D

A and X)

and

showed narrower bandgaps (1.26 and 1.27 eV) than

and their absorption thus red-shifted up to 1000 nm in comparison to that of D-A polymer

(bandgap of 1.50 eV). The introduction of electron-deficient monomers also deepened the highest occupied molecular orbital (HOMO) levels of

and

to -5.28 and -5.33 eV

which was beneficial to a larger open circuit voltage (

) in PSCs. Moreover

the introduction of the third monomer X altered the film properties of the polymers. It showed that

with preference of face-on orientation exhibited a good power conversion efficiency (PCE) in PSCs

while

demonstrated an improved hole mobility in OFET due to the preferable edge-on orientation. When blended with [6

-phenyl-C

-butyric acid methyl ester (PC

BM)

showed a PCE of 2.56%

with a

of 0.68 V

a short circuit current density (

) of 5.71 mA cm

-2

and a fill factor (FF) of 0.66

while

gave a lower PCE of 1.79%

with a

of 0.71 V

of 3.91 mA cm

-2

and a FF of 0.65. This work provides references for the design of novel conjugated polymers for PSCs and OFETs.

关键词

聚合物太阳能电池共聚吡咯并吡咯二酮缺电子单元

Keywords

Polymer solar cellsCopolymerizationDiketopyrrolopyrroleElectron deficient unit

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