苝二酰亚胺聚合物受体设计及在全聚合物太阳能电池中的应用

郭亦堃; 赵达慧

doi:10.11777/j.issn1000-3304.2018.17268

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苝二酰亚胺聚合物受体设计及在全聚合物太阳能电池中的应用

专论 | 更新时间：2021-01-26

- 苝二酰亚胺聚合物受体设计及在全聚合物太阳能电池中的应用
- New Perylenediimide Polymer Acceptor Design and Their Applications to All-polymer Solar Cells
- 高分子学报 2018年第2期页码：174-185
- 作者机构：
  
  北京大学化学与分子工程学院北京 100871
- 作者简介：
  
  [ "赵达慧, 女, 1974年出生, 北京大学化学学院教授、博士生导师.1997年毕业于北京大学化学学院, 获学士学位.2003年获得美国依利诺伊大学化学系博士学位, 之后于美国麻省理工学院进行博士后研究.2006年受聘于北京大学化学学院, 任副教授、博士生导师, 2014年晋升为教授.曾入选北京市科技新星计划, 获得霍英东基金会青年教师基金优选资助课题, 及日本化学会授予Distinguished Lectureship Award, 2012年入选教育部\"新世纪优秀人才支持计划\", 并获国家自然科学基金委优秀青年科学基金资助.目前担任副主编.主要研究方向为新型有机聚合物光电功能材料的设计合成, 有机共轭体系的超分子结构及其与光电功能的构效关系研究" ]
- 基金信息：
  
  国家自然科学基金(基金号21674001)
- DOI：10.11777/j.issn1000-3304.2018.17268
  中图分类号：
- 纸质出版日期：2018-2-20，
  
  收稿日期：2017-9-18，
  
  修回日期：2017-10-23，
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郭亦堃, 赵达慧. 苝二酰亚胺聚合物受体设计及在全聚合物太阳能电池中的应用[J]. 高分子学报, 2018,(2):174-185.

Yi-kun Guo, Da-hui Zhao. New Perylenediimide Polymer Acceptor Design and Their Applications to All-polymer Solar Cells[J]. Acta Polymerica Sinica, 2018,(2):174-185.
郭亦堃, 赵达慧. 苝二酰亚胺聚合物受体设计及在全聚合物太阳能电池中的应用[J]. 高分子学报, 2018,(2):174-185. DOI： 10.11777/j.issn1000-3304.2018.17268.

Yi-kun Guo, Da-hui Zhao. New Perylenediimide Polymer Acceptor Design and Their Applications to All-polymer Solar Cells[J]. Acta Polymerica Sinica, 2018,(2):174-185. DOI： 10.11777/j.issn1000-3304.2018.17268.

摘要

二元或多元聚合物组成的本体异质结具备高度稳定的微相分离形貌，带来潜在的器件寿命和稳定性方面的巨大优势，全聚合物活性层器件因而成为有机太阳能电池的重要发展方向和研究内容.本文系统介绍近年来苝二酰亚胺类聚合物受体的研究进展，以及将这类聚合物受体应用于全聚合物太阳能电池所取得的重要成果.通过多种不同共聚单元结构的设计和筛选、主链和侧链化学结构的调控和优化，获得了一系列性能优越的苝二酰亚胺聚合物受体，这些材料的运用大幅度地提升了全聚合物太阳能电池的能量转化效率.相关的研究数据和结果也为后续酰亚胺类聚合物受体的设计开发、全聚合物本体异质结活性层的形貌特征和光电转化机制的分析和研究，以及全聚合物太阳能电池器件性能的优化和提升提供了良好的实验基础.

Abstract

Bulk-heterojunction (BHJ) polymer solar cells (PSCs) have attracted attention over the past decades due to their distinct advantages of low cost

light weight

and the suitability for flexible-device fabrications. Despite the remarkable success in improving the efficiency of PSCs

fullerene-based acceptors have shown evident limitations. Accordingly

increased research efforts have been invested in developing non-fullerene acceptors

and great development has been witnessed in this field in recent years. Among all different kinds of BHJ PSCs

all polymer solar cells (all-PSCs) potentially possess the most stable donor-acceptor phase separation morphology

and all-polymer films are expected to boast superior mechanical properties. Yet

the bottle neck of enhancing the power conversion efficiency (PCE) of all-PSCs currently lies in the performance of the polymer acceptors. In the past years

we have been focusing on designing new polymer acceptors using perylenediimide (PDI) as the main building block and studying their performance in all-PSCs. A series of PDI-based polymer acceptors have been synthesized and studied since 2013. Due to the steric hindrance induced by the bay-region substitution

the PDI polymers mostly manifest low crystallinity. Accordingly

by enhancing the conjugation and rigidity of the polymer backbone

and thereby improving the aggregation and crystallization ability of the polymers

increased PCE has been achieved with all-PSC devices. Consistently

experimental evidence has also been collected showing improved morphology of the active layer. As a result of the continued and systematic studies on designing and synthesizing new polymer acceptors

along with the optimization of device fabrication conditions

the best PCE of all-PSC incorporating a PDI polymer acceptor has now been boosted to 8.59%. Very similar PCE values can be obtained from devices fabricated under ambient conditions

proving the high chemo-stability of the active-layer materials. The synthetic methods of these PDI-based polymers and the device fabrication conditions are much more convenient and economical. All these properties are friendly to the large-scale material preparation and device production.

关键词

苝二酰亚胺全聚合物太阳能电池能量转化效率

Keywords

All-polymer solar cellsPerylenediimide polymer acceptorsPower conversion efficiency

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