我国离子交换与吸附树脂的发展历程回顾与展望

张全兴; 张政朴; 李爱民; 潘丙才; 张孝林

doi:10.11777/j.issn1000-3304.2018.17317

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我国离子交换与吸附树脂的发展历程回顾与展望

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- 我国离子交换与吸附树脂的发展历程回顾与展望
  增强出版
- Advance in Ion Exchange and Adsorption Resins in China
- 高分子学报 2018年0卷第7期页码：814-828
- 作者机构：
  
  1.南京大学环境学院有机毒物污染控制与资源化国家工程技术研究中心南京 210023
  2.南开大学高分子化学研究所吸附分离功能高分子材料教育部重点实验室天津 300071
- 作者简介：
  
  E-mail: zhqx@nju.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.17317
  中图分类号：
- 纸质出版日期：2018-7，
  
  收稿日期：2017-11-22，
  
  修回日期：2017-11-30，
扫描看全文
张全兴, 张政朴, 李爱民, 潘丙才, 张孝林. 我国离子交换与吸附树脂的发展历程回顾与展望[J]. 高分子学报, 2018,0(7):814-828.

Quan-xing Zhang, Zheng-pu Zhang, Ai-min Li, Bing-cai Pan, Xiao-lin Zhang. Advance in Ion Exchange and Adsorption Resins in China[J]. Acta Polymerica Sinica, 2018,0(7):814-828.
张全兴, 张政朴, 李爱民, 潘丙才, 张孝林. 我国离子交换与吸附树脂的发展历程回顾与展望[J]. 高分子学报, 2018,0(7):814-828. DOI： 10.11777/j.issn1000-3304.2018.17317.

Quan-xing Zhang, Zheng-pu Zhang, Ai-min Li, Bing-cai Pan, Xiao-lin Zhang. Advance in Ion Exchange and Adsorption Resins in China[J]. Acta Polymerica Sinica, 2018,0(7):814-828. DOI： 10.11777/j.issn1000-3304.2018.17317.

摘要

1949年以来，我国离子交换与吸附树脂领域在一代代科研工作者的不懈努力下取得了飞速发展，先后发展了凝胶树脂、大孔树脂、超高交联树脂、复合功能树脂及树脂基复合吸附剂等五代树脂，广泛应用于国防工业、医药卫生、精细化工、湿法冶金以及环境保护等领域，在我国不同发展时期均做出了突出贡献. 本文总结了半个多世纪以来我国离子交换与吸附树脂领域发展的主要历程，重点回顾了以“中国离子交换树脂之父”何炳林先生为代表的离子交换与吸附事业先驱的历史贡献，并对离子交换与吸附树脂近年来的最新发展动向与成果进行简要介绍.

Abstract

Since 1949

China has been witnessing a rapid development in ion exchange and adsorption technology. Up to date

at least five generations of polymeric resins have been developed

including gel-type resin

macroporous resin

hyper-cross-linked resin

bifunctional resin and resin-based composite adsorbent. These resin-based materials have been widely utilized in various industries

including military defense

medical and health

fine chemicals

hydrometallurgy

environmental protection

making considerable contributions to the modernization of China. In brief

gel-type resin

characterized by non-porous nature

was first developed for uranium extraction and later expanded to other fields such as water softening. Due to abundant porous structure

macroporous resin exhibited faster ion exchange rate and higher mechanical strength over the gel-type one. A variety of macroporous adsorption resins were developed and widely utilized in separation and/or purification in the industries of food

chemicals

rare elements

drugs

toxins

and environmental remediation. Hyper-cross-linked resin was mainly prepared

via

Friedel-Crafts reaction

possessing ultra-high specific surface area (usually high than 800 m

/g) and abundant microporous structure. Hyper-cross-linked resins have been successfully applied for hemoperfusion purpose

representing one of the most promising adsorbents for organic pollutants in chemical industry effluents. Bifunctional resins were designed for adsorptive removal of highly water-soluble organic pollutants from industrial effluents

because they could offer multiple interactions with target pollutants such as

interaction

electrostatic attraction

hydrophobic interaction and hydrogen bonds. In the past decade

resin-based composite adsorbents

including resin-supported nanocomposite and magnetic resin

were obtained by integrating resin hosts with inorganic (nano) particles for advanced (waste) water treatment. The present review summarizes the development of ion exchange and adsorption resins in China since its foundation

particularly focusing on the historic contributions of Prof. Binglin He

the father of China’s ion exchange resins

to the progress of ion exchange and adsorption technology in China. Also

it provides an outlook of the perspective of ion exchange and adsorption resins in emerging applications.

关键词

离子交换与吸附树脂凝胶树脂大孔树脂超高交联树脂复合功能树脂树脂基复合吸附剂

Keywords

Ion exchange and adsorption resinGel-type resinMacroporous resinHyper-cross-linked resinBifunctional resinResin-based composite adsorbent

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