高分子修饰金纳米粒子的自组装研究进展

周加境; 吴迪; 卢德荣; 段宏伟

doi:10.11777/j.issn1000-3304.2018.18050

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高分子修饰金纳米粒子的自组装研究进展

综述 | 更新时间：2021-01-26

- 高分子修饰金纳米粒子的自组装研究进展
- Progress in Self-assembly of Polymer-coated Au Nanoparticles
- 高分子学报 2018年0卷第8期页码：1033-1047
- 作者机构：
  
  1.南洋理工大学化学与生物医学工程学院新加坡 637459
  2.浙江大学化学系杭州 310058
- 作者简介：
  
  E-mail: hduan@ntu.edu.sg
- 基金信息：
  
  新加坡教育部(基金号 MOE2015-T2-1-112)和南洋理工大学及中国国家留学基金管理委员会(基金号 201706320290)资助项目.† 共同第一作者()
- DOI：10.11777/j.issn1000-3304.2018.18050
  中图分类号：
- 纸质出版日期：2018-8，
  
  收稿日期：2018-2-7，
  
  修回日期：2018-4-5，
扫描看全文
周加境, 吴迪, 卢德荣, 段宏伟. 高分子修饰金纳米粒子的自组装研究进展[J]. 高分子学报, 2018,0(8):1033-1047.

Jia-jing Zhou, Di Wu, De-rong Lu, Hong-wei Duan. Progress in Self-assembly of Polymer-coated Au Nanoparticles[J]. Acta Polymerica Sinica, 2018,0(8):1033-1047.
周加境, 吴迪, 卢德荣, 段宏伟. 高分子修饰金纳米粒子的自组装研究进展[J]. 高分子学报, 2018,0(8):1033-1047. DOI： 10.11777/j.issn1000-3304.2018.18050.

Jia-jing Zhou, Di Wu, De-rong Lu, Hong-wei Duan. Progress in Self-assembly of Polymer-coated Au Nanoparticles[J]. Acta Polymerica Sinica, 2018,0(8):1033-1047. DOI： 10.11777/j.issn1000-3304.2018.18050.

摘要

近年来，高分子修饰金纳米粒子的自组装行为逐渐成为新的研究热点. 当金纳米粒子修饰上高分子后，在维持其自身光电特性的同时展现出了与高分子类似的自组装行为，从而能够在适当的条件下形成结构明确的零维、一维、二维和三维自组装结构. 这些自组装结构的出现不仅促进了金纳米粒子组装的基础研究，并且极大地丰富了金纳米粒子的应用潜力，为金/高分子纳米复合材料的发展开拓了新的方向. 本文总结了金/高分子纳米复合粒子形成的不同维度组装体，着重讨论了金纳米粒子自组装构筑单元的设计、组装方法以及组装体的性质，分类讨论了相应的自组装材料在环境和生物医药中的应用，并展望了相关研究在未来发展的机遇与挑战.

Abstract

Gold nanostructures with unique optical

electrical and catalytic properties have found widespread use in diverse fields ranging from optics and sensing to nanomedicine and catalysis. There is growing interest in self-assembly of gold nanostructures because their localized surface plasmon resonance undergoes strongly interparticle coupling in close proximity

leading to collective properties that are distinctively different from that of individual building blocks. Considerable progress has been made in tailored synthesis of gold nanostructures and surface-engineering approaches to introduce functional coatings on the nanostructures

giving rise to nanoscale building blocks with defined structural parameters and properties

which make them excellent model systems to study the self-assembly of nanoparticles driven by functiona coatings. Polymers

especially amphiphilic block copolymers

exhibit intrinsic self-assembly in solution and bulk phase. Accumulated evidence has demonstrated that both molecular structures of the polymers and self-assembly conditions have a key impact on the structures formed by self-assembly

producing a wide spectrum of structures such as spherical micelles

cylindrical micelles

lamellae

and vesicles. As such

polymer coatings

which are commonly explored to impart colloidal stability of nanostructures

have emerged as an intriguing class of functional coatings to direct their self-assembly. The ability to tailor the structural details of the polymer coatings such as molecular weight

graft density and amphiphilicity is key to achieve controlled morphology and functionality of the resultant plasmonic assemblies. In this review

we summarize current strategies for constructing well-defined Au nanoparticle building blocks including " one-pot synthesis”

" grafting to”

and " grafting from” strategies. Based on these methods

assemblies of polymer-decorated nanoparticles were designed and formed across multiple dimensions

which brings about potential applications resulting from emerging optical

electronic

and catalytic properties. A protypical example is surface-enhanced Raman scattering (SERS) which is greatly amplified in the interstitial space of the assemblies because of interparticle plasmonic coupling

providing a transduction mechanism for ultrasensitve detection. The ability of dissipating the energy of light irradiate through the combination of photothermal conversion and Mie-scattering makes it possible for the assemblies of Au nanoparticles to serve as imaging probes and therapeutic agents. Representative assemblies of Au nanoparticles

that have shown potentials for sensing and biomedicine

are highlighted in this review. We also emphasize the fundamental and technical challenges for precise control over polymer-guided self-assembly of gold nanoparticles. The combination of simulation and experiment open the avenue to a systematic understanding on the self-assembly of nanoparticles.

关键词

高分子金纳米粒子自组装多维组装体

Keywords

PolymerAu nanoparticlesSelf-assemblyMulti-dimensional assemblies

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