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面向燃料电池的聚苯醚基离子交换膜
Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells
- 高分子学报 2018年0卷第7期 页码：797-813
- 作者机构：
中国科学技术大学化学与材料科学学院 合肥 230026
- 作者简介：
[ "杨正金，男，1988年出生，现任中国科学技术大学化学材料学院特聘副研究员. 2009和2014年分别获北京化工大学学士和清华大学大学博士学位，之后先后在中国科学技术大学和哈佛大学做博士后研究. 2017年8月加入中国科学技术大学. 主要研究方向为多孔有机聚合物膜材料，有机液流电池及隔膜研究，离子膜限域传递效应研究，曾获北京市优秀博士毕业生，北京膜学会杰出青年成果奖" ]
[ "徐铜文，男，1967年出生，1989年和1992年分别获合肥工业大学学士和硕士学位，1995年获天津大学博士学位，1997年南开大学博士后出站加入中国科技大学工作至今，期间先后在东京大学、东京工业大学、韩国光州科技研究所访问交流，目前为中国科学技术大学二级教授、博士生导师、教育部“长江学者”特聘教授、国家杰出青年科学基金获得者，国家百千万人才工程入选者，英国皇家化学会会士，中国膜工业协会电驱动膜专委会主任，《Journal of Membrane Science》等10余种国际英文期刊的编委/编辑及《化工学报》等4种国内核心期刊编委. 在Adv Mater, Angnew Chem Int, JACS, AIChE J等期刊发表论文400余篇(本领域TOP期刊J Membrane Sci 120篇)，出版中文专著2部，主编英文专著3部，受邀撰写中英文专著有关章节20余章. 申请发明专利62项(58项授权)，部分成果已经推广应用. 课题组已培养研究生和博士后120余名" ]
- 基金信息：国家自然科学基金(基金号 21506201，21720102003)，中国科学院百人计划(D)和王宽诚产研人才基金(2016-11)资助.† 共同第一作者()
DOI：10.11777/j.issn1000-3304.2018.18055
中图分类号：纸质出版日期：2018-7，
收稿日期：2018-2-10，
修回日期：2018-4-14，
扫 描 看 全 文
刘雅芝, 丁亮, 刘娇, 杨正金, 徐铜文. 面向燃料电池的聚苯醚基离子交换膜[J]. 高分子学报, 2018,0(7):797-813.
Ya-zhi Liu, Liang Ding, Jiao Liu, Zheng-jin Yang, Tong-wen Xu. Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells[J]. Acta Polymerica Sinica, 2018,0(7):797-813.
刘雅芝, 丁亮, 刘娇, 杨正金, 徐铜文. 面向燃料电池的聚苯醚基离子交换膜[J]. 高分子学报, 2018,0(7):797-813. DOI： 10.11777/j.issn1000-3304.2018.18055.
Ya-zhi Liu, Liang Ding, Jiao Liu, Zheng-jin Yang, Tong-wen Xu. Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells[J]. Acta Polymerica Sinica, 2018,0(7):797-813. DOI： 10.11777/j.issn1000-3304.2018.18055.
摘要
离子交换膜凭借其对离子的选择透过性，可用于离子的分离、分级，在清洁生产、节能减排、能量转换等方面有着广泛的应用前景. 本文系统介绍了本课题组在以聚苯醚(PPO)为主链的离子交换膜的制备、结构和性能以及应用过程等方面的前沿性进展，并对亟待解决的问题和未来的发展方向做出展望. 基于PPO的阴、阳离子交换膜可通过引入侧链、交联、优化功能基团和掺杂等方法提高膜的电导率、溶胀率和机械强度等重要的性能，实现了离子膜功能的多样化及在燃料电池等方面的应用.
Abstract
Due to the unique ion transfer characteristics of ion exchange membranes (IEMs)
they can be used in the separation and classification of ionic systems. Hence
IEMs have a wide application prospect in clean production
energy conservation
emission reduction and energy conversion. Because of gradually depleted fossil fuel
the ever-increasing power demand of our modern lifestyle and the awareness of environment protection
the conversion and storage of energy from renewable sources (hydrogen
wind and solar energy
for instances) have attracted worldwide attention. For both fuel cells and aqueous organic redox flow batteries operated in neutral pH
ion exchange membranes are crucial in determining the internal resistance (conversion efficiency)
working life span of the former and the coulombic efficiency
cycle life of the latter. IEMs have great potential in diverse applications and play prominent roles in addressing energy and environment related issues. Over the past decade
the development of IEMs has attracted much research attention in terms of materials
preparation and applications
due to their academic and industrial values. In this review
we summarized the advanced research on polyphenylene oxide (PPO) polymer based ion exchange membranes. We introduced the membranes synthetic methods
polymer structures
key performances and application processes separately. Besides
we also discussed about the problems of the PPO based ion exchange membranes that should be solved and prospected the development direction in the future. As to the PPO based ion exchange membranes synthetic methods
we divided them into two parts
anion exchange membranes and cation exchange membranes
with a variety of methods enumerated
including introduction of side chains
polymers crosslinking
optimization of functional groups and doping to improve the performances
such as ion conductivity
swelling ratio
mechanical strength and other important performances of the PPO based exchange membranes. We also realized the diversification of the function of ion exchange membranes and application in fuel cells
etc
.
关键词
离子交换膜聚苯醚结构性能前景
Keywords
Ion exchange membranesPolyphenylene oxideStructurePropertiesProspect
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