杂化共聚反应

张广照

doi:10.11777/j.issn1000-3304.2018.18074

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杂化共聚反应

专论 | 更新时间：2021-01-26

- 杂化共聚反应
- Hybrid Copolymerization
- 高分子学报 2018年0卷第6期页码：668-673
- 作者机构：
  
  华南理工大学材料科学与工程学院　广州 510640
- 作者简介：
  
  [ "张广照，男，1966年出生，华南理工大学材料科学与工程学院教授. 1987年本科毕业于四川大学高分子材料系，1998年在复旦大学获博士学位. 先后在香港中文大学(1999 ~ 2001年)和美国麻省大学(2001 ~ 2002年)做博士后研究. 2002 ~ 2010年任中国科学技术大学教授，2010至今在华南理工大学工作. 获得荣誉包括国家杰出青年基金获得者(2007年)，科技部重大研究计划项目首席科学家(2012年)，教育部“长江学者”特聘教授(2013年)，国际海洋材料保护研究常设委员会(COIPM)委员(2017年). 先后担任中国材料研究学会高分子材料与工程分会副主任，广东省化学会高分子化学专业委员会主任；研究方向为高分子溶液与界面物理化学，在大分子构象与相互作用、高分子表征方法学、杂化共聚反应、海洋防污材料方面做出了原创性工作" ]
- 基金信息：
  
  国家自然科学基金重点基金(基金号 21734004)资助项目()
- DOI：10.11777/j.issn1000-3304.2018.18074
  中图分类号：
- 纸质出版日期：2018-6，
  
  收稿日期：2018-3-7，
  
  修回日期：2018-3-27，
扫描看全文
张广照. 杂化共聚反应[J]. 高分子学报, 2018,0(6):668-673.

Guang-zhao Zhang. Hybrid Copolymerization[J]. Acta Polymerica Sinica, 2018,0(6):668-673.
张广照. 杂化共聚反应[J]. 高分子学报, 2018,0(6):668-673. DOI： 10.11777/j.issn1000-3304.2018.18074.

Guang-zhao Zhang. Hybrid Copolymerization[J]. Acta Polymerica Sinica, 2018,0(6):668-673. DOI： 10.11777/j.issn1000-3304.2018.18074.

摘要

杂化共聚是具有不同可聚合基团的2种或2种以上单体的共聚合反应. 它颠覆了传统共聚的概念，因为传统共聚的单体必须具有相同的可聚合基团. 显然，杂化共聚为高分子合成提供了新路径. 然而，由于具有不同可聚合基团的单体聚合机理不同、反应活性相差大，杂化共聚十分具有挑战性. 20世纪80年代，先后出现了自由基开环杂化共聚和两性离子杂化共聚. 近年来，随着有机小分子引发/催化的发展，人们创立了阴离子杂化共聚和阳离子杂化共聚. 本文将介绍杂化共聚的进展情况.

Abstract

Hybrid copolymerization is the process where two or more unlike monomers with different polymerizable groups polymerize together. It is revolutionary to the conventional copolymerization where the monomers have the same polymerizable groups. Hybrid copolymerization provides new routes for synthesis of polymers and gives great possibility to produce polymers with novel properties. However

because the unlike monomers follow different polymerization mechanisms and their reactivities are quite different

hybrid copolymerization has long been a challenge. Fortunately

some breakthroughs have been made in vinyl addition and ring-opening hybrid copolymerization since 1980’s. Bailey

et al

. first reported the radical ring-opening hybrid copolymerization of 2-methylene-1

3-dioxepane (MDO) with vinyl monomers such as styrene (St) and methyl methacrylate (MMA) in 1982. Such a copolymerization can yield relatively high molecular weight polymers (10

− 10

)

but the cyclic monomers are only limited to cyclic ketene acetals. Zwitteronic hybrid copolymerization was reported later but it only produces oligomers. With the development of organocatalysis

anionic and cationic hybrid copolymerizations were studied in recent years. Cationic hybrid copolymerization or the so-called concurrent cationic copolymerization of isobutylene oxide and vinyl ether was reported in 2013. The copolymerization is also applicable to other cyclic monomers with epoxides

but it produces polymers with a relatively low molecular weight (10

− 10

). In 2012

anionic hybrid copolymerization of

-caprolactone (CL) and methyl methacrylate (MMA) was reported by our laboratory for the first time. Such a copolymerization is applicable to many common monomers including cyclic ester or cyclic ether and vinyl esters. The polymer synthesized by anionic hybrid copolymerization has a high molecular weight (10

− 10

) so that it can be used in different materials. Actually

clickable or hybranched biodegradable polymers were already prepared

via

the copolymerization. Particularly

it was used to develop high performance biodegradable polymers for marine anti-biofouling. The work describes the progress in hybrid copolymerization.

关键词

杂化共聚阴离子聚合阳离子聚合自由基开环聚合有机小分子催化

Keywords

Hybrid copolymerizationAnionic polymerizationCationic polymerizationRadical ring-opening polymerizationOrganocatalysis

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