超分子形状记忆水凝胶研究进展

简钰坤; 路伟; 张佳玮; 陈涛

doi:10.11777/j.issn1000-3304.2018.18150

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超分子形状记忆水凝胶研究进展

综述 | 更新时间：2021-01-26

- 超分子形状记忆水凝胶研究进展
- Research Progress in Supramolecular Shape Memory Hydrogels
- 高分子学报 2018年0卷第11期页码：1385-1399
- 作者机构：
  
  中国科学院宁波材料技术与工程研究所　宁波 315201
- 作者简介：
  
  E-mail: zhangjiawei@nimte.ac.cn Jia-wei Zhang, E-mail: zhangjiawei@nimte.ac.cn
  E-mail: tao.chen@nimte.ac.cn Tao Chen, E-mail: tao.chen@nimte.ac.cn
- 基金信息：
  
  国家重点研发计划(项目号 2018YFB1105103)、国家自然科学基金(基金号 51773215)、中国科学院前沿科学重点研究项目(项目号 QYZDB-SSW-SLH036)和中国科学院青年创新促进会(项目号 2017337)资助()
- DOI：10.11777/j.issn1000-3304.2018.18150
  中图分类号：
- 纸质出版日期：2018-11，
  
  收稿日期：2018-6-28，
  
  修回日期：2018-7-26，
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简钰坤, 路伟, 张佳玮, 陈涛. 超分子形状记忆水凝胶研究进展[J]. 高分子学报, 2018,0(11):1385-1399.

Yu-kun Jian, Wei Lu, Jia-wei Zhang, Tao Chen. Research Progress in Supramolecular Shape Memory Hydrogels[J]. Acta Polymerica Sinica, 2018,0(11):1385-1399.
简钰坤, 路伟, 张佳玮, 陈涛. 超分子形状记忆水凝胶研究进展[J]. 高分子学报, 2018,0(11):1385-1399. DOI： 10.11777/j.issn1000-3304.2018.18150.

Yu-kun Jian, Wei Lu, Jia-wei Zhang, Tao Chen. Research Progress in Supramolecular Shape Memory Hydrogels[J]. Acta Polymerica Sinica, 2018,0(11):1385-1399. DOI： 10.11777/j.issn1000-3304.2018.18150.

摘要

超分子形状记忆水凝胶(SSMHs)是一类利用超分子作用或动态共价键作为分子开关来固定临时形状，并能在特定的刺激下恢复初始形状的高分子水凝胶. 本文简要介绍了SSMHs的定义和发展历程，总结了利用不同种类的可逆作用构建SSMHs的最新进展，并扩展介绍了具有多重形状记忆效应和多功能的SSMHs. 最后，也对SSMHs所面临的挑战和未来发展方向进行了讨论.

Abstract

As one of the most important stimuli-responsive polymeric materials

shape memory polymers could fix temporary shapes and subsequently recover to the original shape under specific stimuli

and have thus aroused tremendous attention and shown promising applications in many fields such as biomedical

textile

aerospace and so on. The currently developed shape memory polymers are mainly thermo-responsive

in which vitrification or crystallization of the polymer chains are applied as temporary crosslinks to achieve shape memory property

and the shape recovery is induced by heat. In order to realize shape memory performance under mild conditions

supramolecular interactions (hydrogen bonds

host-guest recognition

metal-ligand coordination) and dynamic covalent bonds (boronate ester interactions

Schiff base bonds) have been employed as temporary switches to construct supramolecular shape memory hydrogels (SSMHs). Because of the reversible and dynamic nature of molecular switches

SSMHs could display excellent shape memory behavior at room temperature. In the early stage

only one kind of reversible interaction was utilized to fix one temporary shape in each shape memory cycle

resulting in a dual shape memory effect. Since the number of temporary shapes that could be stabilized normally has a great impact on the potential applications

two or more non-interfering dynamic switches have been incorporated in one system to realize triple or multiple shape memory effect. Moreover

other properties such as self-healing

adhesion

shape deformation and fluorescence have been successfully introduced into SSMHs

a series of multi-functional SSMHs have been developed to broaden their potential applications. In this review

the definition and development of SSMHs are briefly introduced

and recent progress in SSMHs with different kinds of reversible interactions is summarized

followed by the presentation of SSMHs with multiple shape memory effect and multi-functions. Finally

current challenges and future perspectives in this field are also discussed to promote new developing directions.

关键词

可逆作用形状记忆水凝胶

Keywords

Reversible interactionsShape memoryHydrogel

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