基于聚硼硅氧烷的自愈合光子晶体弹性体

李苗苗; 吕全乾; 朱锦涛; 张连斌

doi:10.11777/j.issn1000-3304.2019.18213

您当前的位置：

首页 >

文章列表页 >

基于聚硼硅氧烷的自愈合光子晶体弹性体

研究论文 | 更新时间：2021-01-26

- 基于聚硼硅氧烷的自愈合光子晶体弹性体
- Polyborosiloxane-based Photonic Elastomers with Self-healing Capability
- 高分子学报 2019年50卷第3期页码：271-280
- 作者机构：
  
  华中科技大学化学与化工学院能量转换与存储材料化学教育部重点实验室　武汉 430074
- 作者简介：
  
  E-mail: zhanglianbin@hust.edu.cn Lian-bin Zhang, E-mail: zhanglianbin@hust.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 51525302)资助项目()
- DOI：10.11777/j.issn1000-3304.2019.18213
  中图分类号：
- 纸质出版日期：2019-3，
  
  网络出版日期：2018-11-26，
  
  收稿日期：2018-10-10，
  
  修回日期：2018-11-3，
扫描看全文
李苗苗, 吕全乾, 朱锦涛, 张连斌. 基于聚硼硅氧烷的自愈合光子晶体弹性体[J]. 高分子学报, 2019,50(3):271-280.

Miao-miao Li, Quan-qian Lyu, Jin-tao Zhu, Lian-bin Zhang. Polyborosiloxane-based Photonic Elastomers with Self-healing Capability[J]. Acta Polymerica Sinica, 2019,50(3):271-280.
李苗苗, 吕全乾, 朱锦涛, 张连斌. 基于聚硼硅氧烷的自愈合光子晶体弹性体[J]. 高分子学报, 2019,50(3):271-280. DOI： 10.11777/j.issn1000-3304.2019.18213.

Miao-miao Li, Quan-qian Lyu, Jin-tao Zhu, Lian-bin Zhang. Polyborosiloxane-based Photonic Elastomers with Self-healing Capability[J]. Acta Polymerica Sinica, 2019,50(3):271-280. DOI： 10.11777/j.issn1000-3304.2019.18213.

摘要

通过硼酸(BA)交联羟基封端的聚二甲基硅氧烷(Hydroxyl-PDMS)得到聚硼硅氧烷(PBS)弹性体，并与单分散的SiO

纳米粒子(SiO

NPs)和炭黑纳米粒子(CB NPs)共组装，进而得到无角度依赖的光子晶体弹性体. 通过光纤光谱仪表征了不同结构色光子晶体弹性体的光学性质，利用光学显微镜和应力-应变测试分别对光子晶体弹性体表面划痕和裂痕的自愈合性能进行了系统表征. 结果表明，该光子晶体弹性体材料的结构色不随观测角度的改变而发生变化，即具有无角度依赖的结构色. 同时，该光子晶体弹性体在形变过程中可实现颜色改变；更为重要的是，光子晶体弹性体的链柔性及动态可逆键使其在室温条件下即可展现出自愈合性能

可实现表面划痕及裂痕的快速愈合. 此外，通过喷涂法可简单快速地制备具有明亮结构色的大面积光子晶体膜材料，拓展了该光子晶体材料在彩色涂层、显示板、印刷等领域的应用.

Abstract

Recently

photonic crystals with short-range ordered structures have aroused extensive interest in scientific research owing to their structural color independent of angle variation. This unique property sets mateirals free from the angle-dependent color variation and plays a critical role in the practical applications involving color observation. However

such fascinating applications may be undesirably compromised by the poor durability of photonic crystals due to their delicate structures. In this study

we developed a series of polyborosiloxane-based photonic elastomers that possessed angle-independent structural color and self-healing capability. Specifically

hydroxyl-terminated poly(dimethylsiloxane) (Hydroxyl-PDMS) was reacted with boric acid (BA) by forming reversible dynamic covalent bonds

dative bonds

and hydrogen bonds

and as-obtained polyborosiloxane (PBS) elastomers were further incorporated with isotropically arranged SiO

nanoparticles (NPs) and carbon black NPs. Optical properties of the photonic elastomers were characterized by reflection spectroscopy at varied detection angles

and angle independence was found for structural colors. Futhermore

the structural color of these elastomers could be tuned by simply adjusting the size or loading fraction of the SiO

NPs in elastomers. The mateirals obtained had a Young’s modulus up to ~200 kPa and also exhibited mechanochromic behavior thanks to the good flexibility of polymeric matrix. Moreover

the intriguing combination of flexibility with reversible bonding endowed the photonic elastomers with a rapid self-healing ability towards superficial scratches or cuts at room temperature

which in turn afforded the necessary durabilities both optically and mechanically. In addition

since photonic elastomer films with a large area could be readily fabricated through a simple spray-coating process

the materials developed have shown great prospects for applications in color-coating

displaying

sensing

and printing.

关键词

光子晶体无角度依赖结构色自愈合弹性体聚硼硅氧烷

Keywords

Photonic crystalAngle-independent structural colorSelf-healingElastomerPolyborosiloxane

references

. 高分子学报 , Acta Polymerica Sinica , 2010 . ( 6 ): 733 - 740.

Liu J, Ren J, Xie Z, Guan B, Wang J, Ikeda T, Jiang L . Nanoscale , 2018 . 10 ( 10 ): 4642 - 4649 . DOI:10.1039/C7NR09387Jhttp://doi.org/10.1039/C7NR09387J .

Liu J, Wang L, Zhang M, Jiang K, Song K, Wang J, Ikeda T, Jiang L . Adv Funct Mater , 2017 . 27 ( 7 ): 1605221 - 1605228 . DOI:10.1002/adfm.v27.7http://doi.org/10.1002/adfm.v27.7 .

. 化学学报 , Acta Chimica Sinica , 2017 . 75 ( 10 ): 967 - 980 . DOI:10.6023/A17070302http://doi.org/10.6023/A17070302 .

Kuang M, Wang J, Jiang L . Chem Soc Rev , 2016 . 45 ( 24 ): 6833 - 6854 . DOI:10.1039/C6CS00562Dhttp://doi.org/10.1039/C6CS00562D .

Liu J, Xie Z, Shang Y, Ren J, Hu R, Guan B, Wang J, Ikeda T, Jiang L . ACS Appl Mater Interfaces , 2018 . 10 ( 7 ): 6701 - 6710 . DOI:10.1021/acsami.7b17936http://doi.org/10.1021/acsami.7b17936 .

Oh J W, Chung W J, Heo K, Jin H E, Lee B Y, Wang E, Zueger C, Wong W, Meyer J, Kim C, Lee S Y, Kim W G, Zemla M, Auer M, Hexemer A, Lee S W . Nat Commun , 2014 . 5 ( 3 ): 3043 - 3050.

Li Q, Zhang Y, Shi L, Qiu H, Zhang S, Qi N, Hu J, Yuan W, Zhang X, Zhang K Q . ACS Nano , 2018 . 12 ( 4 ): 3095 - 3102 . DOI:10.1021/acsnano.7b08259http://doi.org/10.1021/acsnano.7b08259 .

Lee G H, Choi T M, Kim B, Han S H, Lee J M, Kim S H . ACS Nano , 2017 . 11 ( 11 ): 11350 - 11357 . DOI:10.1021/acsnano.7b05885http://doi.org/10.1021/acsnano.7b05885 .

Wang W, Fan X, Li F, Qiu J, Umair M M, Ren W, Ju B, Zhang S, Tang B . Adv Optical Mater , 2018 . 6 ( 4 ): 1701093 - 1701102 . DOI:10.1002/adom.v6.4http://doi.org/10.1002/adom.v6.4 .

. 高分子学报 , Acta Polymerica Sinica , 2017 . ( 8 ): 1261 - 1276.

Xiao F, Sun Y, Du W, Shi W, Wu Y, Liao S, Wu Z, Yu R . Adv Funct Mater , 2017 . 27 ( 42 ): 1702147 - 1702153 . DOI:10.1002/adfm.v27.42http://doi.org/10.1002/adfm.v27.42 .

Jia X, Zhang T, Wang J, Wang K, Tan H, Wang J, Hu Y, Zhang L, Zhu J . Langmuir , 2018 . 34 ( 13 ): 3987 - 3992 . DOI:10.1021/acs.langmuir.8b00186http://doi.org/10.1021/acs.langmuir.8b00186 .

Forster J D, Noh H, Liew S F, Saranathan V, Schreck C F, Yang L, Park J G, Prum R O, Mochrie S G, O’Hern C S, Cao H, Dufresne E R . Adv Mater , 2010 . 22 ( 26-27 ): 2939 - 2944 . DOI:10.1002/adma.200903693http://doi.org/10.1002/adma.200903693 .

Takeoka Y, Honda M, Seki T, Ishii M, Nakamura H . ACS Appl Mater Interfaces , 2009 . 1 ( 5 ): 982 - 986 . DOI:10.1021/am900074vhttp://doi.org/10.1021/am900074v .

Wang F, Zhang X, Lin Y, Wang L, Zhu J . ACS Appl Mater Interfaces , 2016 . 8 ( 7 ): 5009 - 5016 . DOI:10.1021/acsami.5b11919http://doi.org/10.1021/acsami.5b11919 .

Kumano N, Seki T, Ishii M, Nakamura H, Takeoka Y . Angew Chem Int Ed , 2011 . 50 ( 17 ): 4012 - 4015 . DOI:10.1002/anie.201008182http://doi.org/10.1002/anie.201008182 .

Xia T, Luo W, Hu F, Qiu W, Zhang Z, Lin Y, Liu X Y . ACS Appl Mater Interfaces , 2017 . 9 ( 26 ): 22037 - 22041 . DOI:10.1021/acsami.7b04653http://doi.org/10.1021/acsami.7b04653 .

Chen W P, Hao D Z, Hao W J, Guo X L, Jiang L . ACS Appl Mater Interfaces , 2018 . 10 ( 1 ): 1258 - 1265 . DOI:10.1021/acsami.7b17118http://doi.org/10.1021/acsami.7b17118 .

Cash J J, Kubo T, Bapat A P, Sumerlin B S . Macromolecules , 2015 . 48 ( 7 ): 2098 - 2106 . DOI:10.1021/acs.macromol.5b00210http://doi.org/10.1021/acs.macromol.5b00210 .

Cui J, Del C A . Chem Commun , 2012 . 48 ( 74 ): 9302 - 9304 . DOI:10.1039/c2cc34701fhttp://doi.org/10.1039/c2cc34701f .

Zhou H, Xu G, Li J, Zeng S, Zhang X, Zheng Z, Ding X, Chen W, Wang Q, Zhang W . Macromol Res , 2015 . 23 ( 12 ): 1098 - 1102 . DOI:10.1007/s13233-015-3145-7http://doi.org/10.1007/s13233-015-3145-7 .

Wu J, Cai L H, Weitz D A . Adv Mater , 2017 . 29 ( 38 ): 1702616 - 1702623 . DOI:10.1002/adma.201702616http://doi.org/10.1002/adma.201702616 .

Takashima Y, Yonekura K, Koyanagi K, Iwaso K, Nakahata M, Yamaguchi H, Harada A . Macromolecules , 2017 . 50 ( 11 ): 4144 - 4150 . DOI:10.1021/acs.macromol.7b00875http://doi.org/10.1021/acs.macromol.7b00875 .

Fu F, Chen Z, Zhao Z, Wang H, Shang L, Gu Z, Zhao Y . Proc Natl Acad Sci USA , 2017 . 114 ( 23 ): 5900 - 5905 . DOI:10.1073/pnas.1703616114http://doi.org/10.1073/pnas.1703616114 .

Zhou J, Han P, Liu M, Zhou H, Zhang Y, Jiang J, Liu P, Wei Y, Song Y, Yao X . Angew Chem Int Ed , 2017 . 56 ( 35 ): 10462 - 10466 . DOI:10.1002/anie.v56.35http://doi.org/10.1002/anie.v56.35 .

Ge D, Lee E, Yang L, Cho Y, Li M, Gianola D S, Yang S . Adv Mater , 2015 . 27 ( 15 ): 2489 - 2495 . DOI:10.1002/adma.201500281http://doi.org/10.1002/adma.201500281 .

Fudouzi H, Sawada T . Langmuir , 2006 . 22 ( 3 ): 1365 - 1368 . DOI:10.1021/la0521037http://doi.org/10.1021/la0521037 .

. 高分子学报 , Acta Polymerica Sinica , 2014 . ( 6 ): 860 - 864.

Wu T, Chen B . ACS Appl Mater Interfaces , 2016 . 8 ( 36 ): 24071 - 24078 . DOI:10.1021/acsami.6b06137http://doi.org/10.1021/acsami.6b06137 .

Tang M, Wang W, Xu D, Wang Z . Ind Eng Chem Res , 2016 . 55 ( 49 ): 12582 - 12589 . DOI:10.1021/acs.iecr.6b03823http://doi.org/10.1021/acs.iecr.6b03823 .

Liu Z, Picken S J, Besseling N A M . Macromolecules , 2014 . 47 ( 14 ): 4531 - 4537 . DOI:10.1021/ma500632fhttp://doi.org/10.1021/ma500632f .

Li X, Zhang D, Xiang K, Huang G . RSC Adv , 2014 . 4 ( 62 ): 32894 - 32901 . DOI:10.1039/C4RA01877Jhttp://doi.org/10.1039/C4RA01877J .

Zeng Q, Ding C, Li Q, Yuan W, Peng Y, Hu J, Zhang K Q . RSC Adv , 2017 . 7 ( 14 ): 8443 - 8452 . DOI:10.1039/C6RA26526Jhttp://doi.org/10.1039/C6RA26526J .

Takeoka Y, Yoshioka S, Takano A, Arai S, Khanin N, Nishihara H, Teshima M, Ohtsuka Y, Seki T . Angew Chem Int Ed , 2013 . 52 ( 28 ): 7261 - 7265 . DOI:10.1002/anie.201301321http://doi.org/10.1002/anie.201301321 .

Wang F, Zhang X, Zhang L, Cao M, Lin Y, Zhu J . Dyes Pigments , 2016 . 130 202 - 208 . DOI:10.1016/j.dyepig.2016.03.022http://doi.org/10.1016/j.dyepig.2016.03.022 .

更多指标>

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

羧基丁苯橡胶/羧基化纤维素纳米晶自愈合复合材料的制备及性能研究

微相分离结合氢键复合构筑弹性体

动态共价键高分子材料的研究进展

海藻酸动态共价交联水凝胶的制备及其自愈合性能

基于动态建构化学的自愈合水凝胶及其在生物医学领域的应用展望