共轭聚合物在多组分共混体系中的聚集结构研究进展

郑介明; 文新博; 周家东; 郑楠; 解增旗

doi:10.11777/j.issn1000-3304.2019.19062

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共轭聚合物在多组分共混体系中的聚集结构研究进展

综述 | 更新时间：2021-01-26

- 共轭聚合物在多组分共混体系中的聚集结构研究进展
- Research Progress on Aggregation Structure of Conjugated Polymers in Multicomponent Blends
- 高分子学报 2019年50卷第8期页码：775-807
- 作者机构：
  
  华南理工大学发光材料与器件国家重点实验室　广州 510640
- 作者简介：
  
  E-mail: zhengn@scut.edu.cn Nan Zheng, E-mail: zhengn@scut.edu.cn
  E-mail: msxiez@scut.edu.cn Zeng-qi Xie, E-mail: msxiez@scut.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 51761135101，51573055，21334002，21733005，51521002)和国家重点基础研究发展计划(973计划，项目号 2014CB643504)资助()
- DOI：10.11777/j.issn1000-3304.2019.19062
  中图分类号：
- 纸质出版日期：2019-8，
  
  网络出版日期：2019-6-21，
  
  收稿日期：2019-3-27，
  
  修回日期：2019-4-30，
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郑介明, 文新博, 周家东, 郑楠, 解增旗. 共轭聚合物在多组分共混体系中的聚集结构研究进展[J]. 高分子学报, 2019,50(8):775-807.

Jie-ming Zheng, Xin-bo Wen, Jia-dong Zhou, Nan Zheng, Zeng-qi Xie. Research Progress on Aggregation Structure of Conjugated Polymers in Multicomponent Blends[J]. Acta Polymerica Sinica, 2019,50(8):775-807.
郑介明, 文新博, 周家东, 郑楠, 解增旗. 共轭聚合物在多组分共混体系中的聚集结构研究进展[J]. 高分子学报, 2019,50(8):775-807. DOI： 10.11777/j.issn1000-3304.2019.19062.

Jie-ming Zheng, Xin-bo Wen, Jia-dong Zhou, Nan Zheng, Zeng-qi Xie. Research Progress on Aggregation Structure of Conjugated Polymers in Multicomponent Blends[J]. Acta Polymerica Sinica, 2019,50(8):775-807. DOI： 10.11777/j.issn1000-3304.2019.19062.

摘要

基于本体异质结的聚合物太阳电池性能与相分离结构特别是聚合物的聚集结构密切相关. 本文综述了一些典型共轭聚合物聚集结构方面的研究进展，详细介绍了基于齐聚噻吩、二噻吩、苯并二噻吩及噻吩衍生物的D-A共聚物、二维共轭聚合物以及嵌段共聚物等体系的聚集结构特点，系统总结了一系列共轭聚合物在不同共混物、处理溶剂、退火温度、共混比例、分子量、侧链原子或基团等条件下相应的聚集结构变化规律. 在众多共轭聚合物中，研究最多的是D-A共聚物，故作重点介绍，而二维共轭聚合物、嵌段共聚物作简要介绍.

Abstract

Conjugated polymers have attracted much attention due to their unique electronic properties and solution processing methods. The rigid and planar conformational backbone manifests extended

-system and the flexible alkyl chain assures the sufficient solubility

which contribute to their tuneable physical and chemical properties and increase the tolerance of film forming and mechanical flexibility. In general

the orthogonal design of functional fragments for conjugated polymers make it accessible for

-stacking of conjugated segments and lamellar stacking of interchain interactions. Short-range aggregates or long-range microcrystals would be selectively and/or successively formed by controlling their chemical structures and processing conditions. Such stacking structure in the phase-separated domain is crucial to the high efficient performance of bulk heterojunction solar cells. The aggregation structure of some typical conjugated polymers has recently been reviewed with a view to providing reference for the development of optoelectrics in this study. Here

D-A copolymers based on oligothiophene

dithiophene

benzothiophene and thiophene derivatives

two-dimensional conjugated polymers and block copolymers are introduced in detail. The aggregation structure of a series of conjugated polymers is systematically summarized by using the different processing techniques

such as selective counterpart components

treating solvents and annealing temperature. In addition

the intrinsic motivation of the controllable aggregation structure is discussed from the aspects of molecular weight and side chain groups.

关键词

共轭聚合物聚集结构D-A共聚物嵌段共聚物

Keywords

Conjugated polymersAggregated structuresD-A copolymersBlock copolymers

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