功能微纳米聚合物纤维材料

丁彬

doi:10.11777/j.issn1000-3304.2019.19069

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功能微纳米聚合物纤维材料

专论 | 更新时间：2021-01-26

- 功能微纳米聚合物纤维材料
- Functional Polymeric Micro/Nano-fibrous Materials
- 高分子学报 2019年50卷第8期页码：764-774
- 作者机构：
  
  东华大学纺织科技创新中心　上海 200051
- 作者简介：
  
  [ "丁彬，男，1975年生，东华大学教授、博士生导师. 1998年本科毕业于东北师范大学化学系，2003年获得韩国全北大学高分子材料系硕士学位，2005年获得日本庆应义塾大学工学部博士学位，随后在日本、美国进行博士后研究. 2008年被东华大学引进回国，先后获评上海市曙光学者(2010年)、教育部新世纪优秀人才(2011年)、国家基金委优青(2014年)、美国纤维学会杰出成就奖(2014年)、教育部长江学者特聘教授(2016年)、国家“万人计划”科技创新领军人才(2018年)等荣誉和人才计划. 主要从事微纳米纤维材料的成型理论和结构设计及其在国防军工、环境保护、柔性能源、生物医用等领域的应用研究" ]
- 基金信息：
  
  国家自然科学基金(基金号51673037，51873029)资助项目()
- DOI：10.11777/j.issn1000-3304.2019.19069
  中图分类号：
- 纸质出版日期：2019-8，
  
  网络出版日期：2019-6-12，
  
  收稿日期：2019-4-9，
  
  修回日期：2019-5-21，
扫描看全文
丁彬. 功能微纳米聚合物纤维材料[J]. 高分子学报, 2019,50(8):764-774.

Bin Ding. Functional Polymeric Micro/Nano-fibrous Materials[J]. Acta Polymerica Sinica, 2019,50(8):764-774.
丁彬. 功能微纳米聚合物纤维材料[J]. 高分子学报, 2019,50(8):764-774. DOI： 10.11777/j.issn1000-3304.2019.19069.

Bin Ding. Functional Polymeric Micro/Nano-fibrous Materials[J]. Acta Polymerica Sinica, 2019,50(8):764-774. DOI： 10.11777/j.issn1000-3304.2019.19069.

摘要

纤维直径细化带来的尺寸效应和表面效应赋予微纳米纤维许多独特的性质，使其成为当前纤维材料领域研究的重点和前沿. 在众多的微纳米纤维加工方法中，静电纺丝法因具有可纺原料种类丰富、纤维结构可调性好、多元技术结合性强等优势而成为当前制备微纳米聚合物纤维的重要方法之一. 近年来，本课题组在静电纺微纳米聚合物纤维材料的可控加工及应用方面开展了系列研究，本专论主要介绍了其中关于超细纳米蛛网材料、致密粘连微纳米纤维膜、多级网孔纤维气凝胶的结构成型机制及其特效应用方面的工作，并对功能微纳米聚合物纤维材料的未来发展方向进行了展望.

Abstract

Benefiting from intensive size effect and surface effect arising from thin fibers

micro/nano-fibrous membranes exhibit many fascinating properties and have become a hot spot and leading edge in the fiber materials. Among the existing processing approaches for micro/nano-fibers

electrospinning has proven to be one of the most effective and promising method due to its integrated characteristics

including broad availability to varieties of polymers

adjustable porous structure

and superior technological convergence. In recent years

our research group have endeavored systematic researches on the controllable fabrication and applications of electrospun micro/nano-fibrous materials

especially in the terms of ultra-thin nanonets

compactly bonded membranes and porous fibrous aerogels. This review mainly puts focus on the formation mechanisms and applications of these distinctive micro/nano-fibrous materials

which are summarized as follows. Firstly

the two-dimensional nanonets with extremely small diameters (

20 nm) are fabricated by a novel electrospinning/netting technique

and the deformation-phase transition of the charged jets/droplets from polymer solution during the period is also revealed

which have broken the bottleneck of the thinning on diameter of electrospun fibers. And the novel nanonets demonstrate lower air resistance due to the slip flow of air molecules on the periphery of nanofibers

holding great promise as an exceptional candidate for air filtration. Secondly

compactly bonded membranes with stable porous structures are constructed directly through the regulation of the relative humidity

and the effects of relative humidity on electrospinning jet stretching and solidification are investigated. Additionally

hydrophobicly modified compactly bonded membranes demonstrate excellent waterproofness and breathability

thus implying their potential application in selective separation of gas-liquid medium. Thirdly

the ultralight polymeric micro/nano-fibrous aerogels with hierarchical cellular structure and superelasticity are prepared

via

a novel three-dimensional fibrous framework reconstruction method

which exhibit the integrated properties of extremely low density (minimum of 0.12 mg/cm

)

super recyclable compressibility and multifunctionality of combining the thermal insulation

sound absorption

emulsion separation and elasticity-responsive electric conduction. The future perspectives of micro/nano-fibrous materials were also given at the end of this review.

关键词

微纳米纤维静电纺丝纳米蛛网致密粘连纤维膜纤维气凝胶

Keywords

Micro/nano-fibersElectrospinningNanonetsCompactly bonded membranesFibrous aerogels

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