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两仪聚合——拓扑结构聚合物合成新方法
Janus Polymerization: A Novel Approach towards Topology Design
- 高分子学报 2019年50卷第11期 页码：1133-1145
- 作者机构：
教育部高分子合成与功能构造重点实验室 浙江大学高分子科学与工程学系 杭州 310027
- 作者简介：
[ "凌君，男，1975年生. 浙江大学高分子科学与工程学系教授、博士生导师. 2002年毕业于浙江大学高分子科学与工程学系，获得博士学位并留校任教，2004年获得全国优秀博士学位论文提名奖. 2005 ~ 2007年在美国南加州大学化学系Thieo E. Hogen-Esch教授课题组做博士后研究. 2011年获得德国洪堡科研基金，2012和2013年，作为洪堡高级研究学者分别在德国拜罗伊特大学和美因茨大学Axel H. E. Müller教授课题组工作. 自2017年起担任《中国化学快报》青年编委. 主要研究方向为活性/可控聚合方法、功能高分子的合成和分子模拟等" ]
- 基金信息：国家自然科学基金(基金号 21871232)和浙江省自然科学基金杰出青年项目(项目号 LR15B040001)资助()
DOI：10.11777/j.issn1000-3304.2019.19150
中图分类号：纸质出版日期：2019-11，
网络出版日期：2019-9-20，
收稿日期：2019-8-10，
修回日期：2019-8-21，
扫 描 看 全 文
邱欢, 李瑶, 白天闻, 凌君. 两仪聚合——拓扑结构聚合物合成新方法[J]. 高分子学报, 2019,50(11):1133-1145.
Huan Qiu, Yao Li, Tian-wen Bai, Jun Ling. Janus Polymerization: A Novel Approach towards Topology Design[J]. Acta Polymerica Sinica, 2019,50(11):1133-1145.
邱欢, 李瑶, 白天闻, 凌君. 两仪聚合——拓扑结构聚合物合成新方法[J]. 高分子学报, 2019,50(11):1133-1145. DOI： 10.11777/j.issn1000-3304.2019.19150.
Huan Qiu, Yao Li, Tian-wen Bai, Jun Ling. Janus Polymerization: A Novel Approach towards Topology Design[J]. Acta Polymerica Sinica, 2019,50(11):1133-1145. DOI： 10.11777/j.issn1000-3304.2019.19150.
摘要
两仪聚合(Janus polymerization)是在一条聚合增长链两端同时引发阳离子型和阴离子型开环聚合的聚合方法. 两仪聚合可以一步从单体直接合成具有复杂拓扑结构的聚合物，包括两/多嵌段聚合物、超支化聚合物、杂臂星形聚合物和柱状聚合物刷等. 本文总结了近年来本课题组有关两仪聚合方面的研究进展，介绍了两仪聚合特征与机理、两仪聚合在构筑拓扑结构聚合物上的应用、聚合产物独特而优异的性质、两仪聚合新体系等，并对两仪聚合发展作出了展望.
Abstract
Janus polymerization combines cationic and anionic polymerizations at two ends of a single propagating chain involving a living/controlled chain-growth polymerization and a self-triggered stepwise polycondensation
which provides a facile way to synthesize novel polymers with sophisticated topologies in one step directly from monomers. Di-/Multi-block copolymers
branch polymers
mikto-arm star copolymers and cylindrical polymer brushes are synthesized using rare earth triflates catalysts assisted by various epoxy initiators owing to their specific position at the middle of the chain. This work reviews recent progress on Janus polymerization in our group. Specifically
the characteristic of rare earth metal catalysts and mechanism of Janus polymerization are discussed in detail where tripedal crows are employed to illustrate the mechanism. New methodologies for the construction of topological polymers are introduced
together with the unique and prominent properties
such as thermoplastic properties
self-assembly and self-healing behaviors and the corresponding applications in self-sealing films for plants and electrostatic spinning. A new Janus system is put forward which affords a facile synthetic method for functional polyesters by incorporating a modifiable monomer 3
3-bis(chloromethyl)oxacyclobutane. Finally
the development of Janus polymerization including new catalytic systems and monomers is also prospected. The concept of Janus polymerization makes significant breakthroughs into traditional cognitions about incompatible cationic and anionic polymerization mechanisms in one system which motivates the power in the catalysis and synthesis of polymer chemistry.
关键词
两仪聚合拓扑结构多嵌段聚合物开环聚合稀土催化剂
Keywords
Janus polymerizationTopology designMultiblock copolymerRing opening polymerizationRare earth catalysts
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