基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器

秦夏彤; 刘根起; 刘晨辉; 刘建勋; 李欢欢; 曹云雷; 范晓东

doi:10.11777/j.issn1000-3304.2019.19170

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基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器

论文 | 更新时间：2021-01-26

- 基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器
- Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel
- 高分子学报 2020年51卷第2期页码：191-197
- 作者机构：
  
  西北工业大学理学院应用化学系陕西省高分子科学与技术重点实验室　西安 710129
- 作者简介：
  
  E-mail: liugenqi@nwpu.edu.cn Gen-qi Liu, E-mail: liugenqi@nwpu.edu.cn
- 基金信息：
  
  陕西省自然科学基础研究计划项目(项目号 2017JM5049)和西北工业大学研究生创意创新种子基金(基金号 ZZ2019232)资助
- DOI：10.11777/j.issn1000-3304.2019.19170
  中图分类号：
- 纸质出版日期：2020-2，
  
  网络出版日期：2019-11-20，
  
  收稿日期：2019-9-18，
  
  修回日期：2019-10-16，
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秦夏彤, 刘根起, 刘晨辉, 刘建勋, 李欢欢, 曹云雷, 范晓东. 基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器[J]. 高分子学报, 2020,51(2):191-197.

Xia-tong Qin, Gen-qi Liu, Chen-hui Liu, Jian-xun Liu, Huan-huan Li, Yun-lei Cao, Xiao-dong Fan. Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel[J]. Acta Polymerica Sinica, 2020,51(2):191-197.
秦夏彤, 刘根起, 刘晨辉, 刘建勋, 李欢欢, 曹云雷, 范晓东. 基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器[J]. 高分子学报, 2020,51(2):191-197. DOI： 10.11777/j.issn1000-3304.2019.19170.

Xia-tong Qin, Gen-qi Liu, Chen-hui Liu, Jian-xun Liu, Huan-huan Li, Yun-lei Cao, Xiao-dong Fan. Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel[J]. Acta Polymerica Sinica, 2020,51(2):191-197. DOI： 10.11777/j.issn1000-3304.2019.19170.

摘要

以聚苯乙烯二维光子晶体为模板，丙烯酸为功能单体，乙二醇二甲基丙烯酸酯为交联剂，2

2-二乙氧基苯乙酮为引发剂，紫外光引发聚合，制备聚丙烯酸二维光子晶体水凝胶(PAA 2D-PCH)，利用德拜环法研究了其对阳离子表面活性剂的刺激响应行为. 实验结果表明，在pH = 7.4的磷酸盐缓冲溶液中，PAA 2D-PCH对阳离子表面活性剂有灵敏的响应，凝胶体积收缩，引起颗粒间距减小，德拜环直径增大，衍射波长蓝移，当氯化十六烷基吡啶(CPC)、溴化十六烷基吡啶(CPB)、十六烷基三甲基溴化铵(CTAB)浓度由0增加到4 × 10

−3

mol/L时，德拜环直径分别增加了5.95、5.50、5.05 cm，颗粒间距分别减小了380、364、341 nm；而在阴离子表面活性剂、非离子表面活性剂和两性离子表面活性剂溶液中，PAA 2D-PCH的德拜环直径基本保持不变，表明其对阴离子型、非离子型和两性离子表面活性剂均无响应. 该PAA 2D-PCH制备简单，有望作为传感器用于水体中阳离子表面活性剂的检测，无需复杂的仪器设备，操作方便、可重复利用，兼具可视化的特点.

Abstract

A polyacrylic acid two-dimensional photonic crystal hydrogel (PAA 2D-PCH) was prepared with acrylic acid as monomers

ethylene glycol dimethylacrylate as cross-linkers

2-diethoxyacetophenone as initiators and polystyrene two-dimensional photonic crystal with bright diffraction under visible light illumination as a template

and its stimulating response properties to cationic surfactants were investigated. The results indicated that the PAA 2D-PCH had a sensitive response to cationic surfactants

while no response to anion

nonionic and zwitterionic surfactants. When the concentration of CPC

CPB and CTAB was increased from 0 to 4 × 10

−3

mol/L

the diameter of Debye ring increased by 5.95

5.50 and 4.95 cm

respectively

and the particle spacing decreased by 390

364

and 341 nm

respectively. In the anionic surfactant

nonionic surfactant and zwitterionic surfactant solution

the diameter of Debye ring of the PAA 2D-PCH showed almost no change. The selective recognition of cationic surfactants by PAA 2D-PCH stemed from the electrostatic interaction between the negatively charged carboxylate ions and the cationic surfactants in the phosphate buffer solution of pH = 7.4

causing the PAA 2D-PCH shrunk

the particle spacing reduced

the diameter of the Debye ring increased

and the diffraction wavelength blue shifted. Study on the response behavior of PAA 2D-PCH to cationic surfactants by Debye ring method is easy to operate and has the characteristics of reusability and visualization

which is expected to be used for the determination of cationic surfactants in water.

关键词

阳离子表面活性剂二维光子晶体聚丙烯酸水凝胶德拜环传感器

Keywords

Cationic surfactantTwo-dimensional photonic crystalPolyacrylic hydrogelDebye ringSensor

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