多相聚合物微观结构和分子间相互作用的固体NMR研究

张荣纯

doi:10.11777/j.issn1000-3304.2019.19175

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多相聚合物微观结构和分子间相互作用的固体NMR研究

综述 | 更新时间：2021-01-26

- 多相聚合物微观结构和分子间相互作用的固体NMR研究
- The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy
- 高分子学报 2020年51卷第2期页码：136-147
- 作者机构：
  
  华南理工大学分子科学与工程学院华南软物质科学与技术高等研究院　广州 510640
- 作者简介：
  
  [ "张荣纯，男，1987年生. 2009年和2014年在南开大学分别获得凝聚态物理学士和博士学位，随后在美国密歇根大学安娜堡分校生物物理和化学系及南开大学药物化学生物学国家重点实验室从事博士后研究，2018年加入华南理工大学华南软物质科学与技术高等研究院，任特聘副研究员. 主要研究方向包括：(1)发展高分辨高灵敏固体核磁共振新方法用于研究复杂体系的微观结构和动力学，包括聚合物、无机材料、药物、有机-无机杂化纳米复合材料、生物大分子等；(2)高分子材料的交联/缠结网络结构和黏弹性；(3)高性能多相聚合物材料的设计、合成及表征" ]
- 基金信息：
  
  国家自然科学基金(基金号 21973031，21704046)、中央高校业务费(项目号 2019XX06)和广东省珠江人才创新创业团队引进项目(项目号 2016ZT06C322)资助
- DOI：10.11777/j.issn1000-3304.2019.19175
  中图分类号：
- 纸质出版日期：2020-2，
  
  网络出版日期：2019-11-25，
  
  收稿日期：2019-9-29，
  
  修回日期：2019-10-28，
扫描看全文
张荣纯. 多相聚合物微观结构和分子间相互作用的固体NMR研究[J]. 高分子学报, 2020,51(2):136-147.

Rong-chun Zhang. The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy[J]. Acta Polymerica Sinica, 2020,51(2):136-147.
张荣纯. 多相聚合物微观结构和分子间相互作用的固体NMR研究[J]. 高分子学报, 2020,51(2):136-147. DOI： 10.11777/j.issn1000-3304.2019.19175.

Rong-chun Zhang. The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy[J]. Acta Polymerica Sinica, 2020,51(2):136-147. DOI： 10.11777/j.issn1000-3304.2019.19175.

摘要

近年来固体核磁共振(NMR)技术在聚合物材料表征领域正发挥着越来越重要的作用，已经成为研究聚合物微观结构、链段动力学、分子间相互作用等微观信息及阐明材料结构-功能-性质关系必不可少的重要手段. 本文将综述我们近年来系统构建和发展的固体NMR方法及其在研究多相聚合物微观结构、分子间相互作用和交联网络等问题中的应用. 此外，针对存在不均匀性动力学的多相聚合物体系，我们发展了增强固体NMR谱图灵敏度的新方法.

Abstract

In recent decades

solid-state nuclear magnetic resonance (NMR) spectroscopy has been playing an important role in the characterization of polymer materials. To some degree

it has become one of the indispensable tools for studying the microstructures

segmental dynamics and inter-/intra-molecular interactions and elucidating the structure-functionality-property relationship of multiphase polymer materials

because the anisotropic spin interactions in the molecules can be selectively manipulated

via

various radiofrequency pulse sequence design. As a result

NMR can provide important information on a length scale from 0.1 nm to 100 nm and a time scale from 1 ns to 100 s. Herein

in this current review article

we will review some of our recently developed solid-state NMR approaches specifically for applications in polymers

including quantitative determination of compositional contents

characterization of crosslinking/entanglement density and inhomogeneity of the network

hydrogen bonding interactions between segments

and so on. A variety of typical examples

including self-healing supramolecular rubbers

thermal reversible polyurethanes

dual-cross-linked hydrogels

elastomers

etc

are given in detail

showing how various solid-state NMR approaches were implemented to quantitatively characterizing the structures

molecular interactions

and crosslinking network. Furthermore

due to the presence of heterogeneous dynamic in multiphase polymers

the applications of traditional solid-state NMR techniques are sustainably limited

and we also developed corresponding novel solid-state NMR approaches to overcome the limitations and enhance the spectral resolution and signal sensitivity.

关键词

多相聚合物固体核磁结构和动力学交联网络链段相互作用

Keywords

Multiphase polymerSolid-state NMRStructures and dynamicsCrosslinking networkSegmental interactions

references

Rubinstein M, Colby R H. Polymer Physics. New York: Oxford University Press, 2003

Ma Dezhu(马德柱). Structures and Performance of Polymers(高聚物的结构与性能). Beijing(北京): Science Press(科学出版社), 2012

Hansen M R, Graf R, Spiess H W. Chem Rev , 2016 . 116 ( 3 ): 1272 - 1308 . DOI:10.1021/acs.chemrev.5b00258http://doi.org/10.1021/acs.chemrev.5b00258 .

Zhang R, Miyoshi T, Sun P. ed.. NMR Methods for Characterization of Synthetic and Natural Polymers. London: Royal Society of Chemistry , 2019 .

Spiess H W. Macromolecules , 2017 . 50 ( 5 ): 1761 - 1777 . DOI:10.1021/acs.macromol.6b02736http://doi.org/10.1021/acs.macromol.6b02736 .

Zhang Rongchun(张荣纯), Sun Pingchuan(孙平川). Chinese Journal of Magnetic Resonance(波谱学杂志) , 2012 . 29 ( 3 ): 307 - 338 . DOI:10.3969/j.issn.1000-4556.2012.03.001http://doi.org/10.3969/j.issn.1000-4556.2012.03.001 .

Schmidt-Rohr K, Spiess H W. Multidimensional Solid-state NMR and Polymers. London: Academic Press, 1994

Xue Gi(薛奇). Spectroscopy for Studying Structures of Organic Compounds and Polymers(有机及高分子化合物结构研究中的光谱方法). Beijing(北京): Science Press(科学出版社), 2016

Ernst R R, Bodenhausen G, Wokaun A. Principles of Nuclear Magnetic Resonance in one and Two Dimensions. New York: Oxford University Press, 1987

Mehring M. Principles of High Resolution NMR in Solids. Springer Science & Business Media, 2012

Paul D R, Bucknall C B. Polymer Blends: Formulation & Performance. Beijing(北京): Science Press(科学出版社), 2004.

Mark J, Ngai K, Graessley W, Mandelkern L, Samulski E, Wignall G, Koenig J. Physical Properties of Polymers. Cambridge: Cambridge University Press, 2004

Pavlidou S, Papaspyrides C D. Prog Polym Sci , 2008 . 33 ( 12 ): 1119 - 1198 . DOI:10.1016/j.progpolymsci.2008.07.008http://doi.org/10.1016/j.progpolymsci.2008.07.008 .

Yang Y, Ding X, Urban M W. Prog Polym Sci , 2015 . 49-50 34 - 59 . DOI:10.1016/j.progpolymsci.2015.06.001http://doi.org/10.1016/j.progpolymsci.2015.06.001 .

Hager M D, Bode S, Weber C, Schubert U S. Prog Polym Sci , 2015 . 49-50 3 - 33 . DOI:10.1016/j.progpolymsci.2015.04.002http://doi.org/10.1016/j.progpolymsci.2015.04.002 .

Yilgör I, Yilgör E, Wilkes G L. Polymer , 2015 . 58 A1 - A36 . DOI:10.1016/j.polymer.2014.12.014http://doi.org/10.1016/j.polymer.2014.12.014 .

Deanin R D. High Performance Biomaterials: A Complete Guide to Medical and Pharmaceutical Applications, 1st ed. New York: Routledge Press, 2017

Hernandez R, Weksler J, Padsalgikar A, Choi T, Angelo E, Lin J, Xu L-C, Siedlecki C A, Runt J. Macromolecules , 2008 . 41 ( 24 ): 9767 - 9776 . DOI:10.1021/ma8014454http://doi.org/10.1021/ma8014454 .

Bates F S, Fredrickson G. Phys Today , 2000 . 52 32 - 38.

Yang C, Yin T, Suo Z. J Mech Phys Solids , 2019 . 131 43 - 55 . DOI:10.1016/j.jmps.2019.06.018http://doi.org/10.1016/j.jmps.2019.06.018 .

Zhong M, Wang R, Kawamoto K, Olsen B D, Johnson J A. Science , 2016 . 353 ( 6305 ): 1264 - 1268 . DOI:10.1126/science.aag0184http://doi.org/10.1126/science.aag0184 .

Saalwaechter K, Seiffert S. Soft Matter , 2018 . 14 1976 - 1991 . DOI:10.1039/C7SM02444Dhttp://doi.org/10.1039/C7SM02444D .

Saalwachter K, Chasse W, Sommer J U. Soft Matter , 2013 . 9 6587 - 6593 . DOI:10.1039/c3sm50194ahttp://doi.org/10.1039/c3sm50194a .

Shen Jiacong(沈家骢), Zhang Wenke(张文科), Sun Junqi(孙俊奇). Introduction to Supramolecular Materials(超分子材料引论). Beijing(北京): Science Press(科学出版社), 2019

Xu Jiangfei(徐江飞), Zhang Xi(张希). Acta Polymerica Sinica(高分子学报) , 2017 . ( 1 ): 37 - 49 . DOI:10.11777/j.issn1000-3304.2017.16262http://doi.org/10.11777/j.issn1000-3304.2017.16262 .

Kuo S W, Chang F C. Macromolecules , 2001 . 34 ( 15 ): 5224 - 5228 . DOI:10.1021/ma010517ahttp://doi.org/10.1021/ma010517a .

He Y, Zhu B, Inoue Y. Prog Polym Sci , 2004 . 29 ( 10 ): 1021 - 1051 . DOI:10.1016/j.progpolymsci.2004.07.002http://doi.org/10.1016/j.progpolymsci.2004.07.002 .

Tseng T C, Kuo S W. Macromolecules , 2018 . 51 ( 16 ): 6451 - 6459 . DOI:10.1021/acs.macromol.8b00751http://doi.org/10.1021/acs.macromol.8b00751 .

Rhim W K, Pines A, Waugh J S. Phys Rev B , 1971 . 3 ( 3 ): 684 - 696 . DOI:10.1103/PhysRevB.3.684http://doi.org/10.1103/PhysRevB.3.684 .

Mauri M, Thomann Y, Schneider H, Saalwächter K. Solid State Nucl Magn Reson , 2008 . 34 ( 1-2 ): 125 - 141 . DOI:10.1016/j.ssnmr.2008.07.001http://doi.org/10.1016/j.ssnmr.2008.07.001 .

Maus A, Hertlein C, Saalwächter K. Macro Chem Phys , 2006 . 207 ( 13 ): 1150 - 1158 . DOI:10.1002/macp.200600169http://doi.org/10.1002/macp.200600169 .

Zhang R, Yu S, Chen S, Wu Q, Chen T, Sun P, Li B, Ding D. J Phys Chem B , 2014 . 118 ( 4 ): 1126 - 1137 . DOI:10.1021/jp409893fhttp://doi.org/10.1021/jp409893f .

Wang F, Zhang R, Lin A, Chen R, Wu Q, Chen T, Sun P. Polymer , 2016 . 107 61 - 70 . DOI:10.1016/j.polymer.2016.11.009http://doi.org/10.1016/j.polymer.2016.11.009 .

Zhao Shouyuan(赵守远), Wang Yuanyuan(王媛媛), Zhang Rongchun(张荣纯), Chen Tiehong(陈铁红),Sun Pingchuan(孙平川). Chinese Journal of Magnetic Resonance(波谱学杂志) , 2014 . 31 ( 2 ): 172 - 184 . DOI:10.3969/j.issn.1000-4556.2014.02.004http://doi.org/10.3969/j.issn.1000-4556.2014.02.004 .

Anderson P W, Weiss P. Rev Mod Phys , 1953 . 25 ( 1 ): 269 - 276 . DOI:10.1103/RevModPhys.25.269http://doi.org/10.1103/RevModPhys.25.269 .

Papon A, Saalwächter K, Schäler K, Guy L, Lequeux F, Montes H. Macromolecules , 2011 . 44 ( 4 ): 913 - 922 . DOI:10.1021/ma102486xhttp://doi.org/10.1021/ma102486x .

Zhang R, Yan T, Lechner B-D, Schröter K, Liang Y, Li B, Furtado F, Sun P, Saalwächter K. Macromolecules , 2013 . 46 ( 5 ): 1841 - 1850 . DOI:10.1021/ma400019mhttp://doi.org/10.1021/ma400019m .

Sturniolo S, Saalwächter K. Chem Phys Lett , 2011 . 516 ( 1-3 ): 106 - 110 . DOI:10.1016/j.cplett.2011.09.059http://doi.org/10.1016/j.cplett.2011.09.059 .

Saalwachter K. Prog Nucl Magn Reson Spectrosc , 2007 . 51 ( 1 ): 1 - 35 . DOI:10.1016/j.pnmrs.2007.01.001http://doi.org/10.1016/j.pnmrs.2007.01.001 .

Saalwächter K. Multiple-Quantum NMR studies of anisotropic polymer chain dynamics. In: Webb G A, ed. Modern Magnetic Resonance. Cham: Springer International Publishing, 2018. Chapter 38

Chassé W, Saalwächter K, Sommer J U. Macromolecules , 2012 . 45 ( 13 ): 5513 - 5523 . DOI:10.1021/ma3009004http://doi.org/10.1021/ma3009004 .

Zou X, Kui X, Zhang R, Zhang Y, Wang X, Wu Q, Chen T, Sun P. Macromolecules , 2017 . 50 ( 23 ): 9340 - 9352 . DOI:10.1021/acs.macromol.7b01854http://doi.org/10.1021/acs.macromol.7b01854 .

Saalwächter K, Heuer A. Macromolecules , 2006 . 39 ( 9 ): 3291 - 3303 . DOI:10.1021/ma052567bhttp://doi.org/10.1021/ma052567b .

Saalwächter K, Herrero B, López-Manchado M A. Macromolecules , 2005 . 38 ( 23 ): 9650 - 9660 . DOI:10.1021/ma051238ghttp://doi.org/10.1021/ma051238g .

Chasse W, Valentin J L, Genesky G D, Cohen C, Saalwächter K. J Chem Phys , 2011 . 134 ( 4 ): 044907 .

Voda M, Demco D, Perlo J, Orza R, Blümich B. J Magn Reson , 2005 . 172 ( 1 ): 98 - 109 . DOI:10.1016/j.jmr.2004.10.001http://doi.org/10.1016/j.jmr.2004.10.001 .

Fechete R, Demco D, Blümich B. Macromolecules , 2002 . 35 ( 16 ): 6083 - 6085 . DOI:10.1021/ma020532vhttp://doi.org/10.1021/ma020532v .

Baum J, Pines A. J Am Chem Soc , 1986 . 108 ( 24 ): 7447 - 7454 . DOI:10.1021/ja00284a001http://doi.org/10.1021/ja00284a001 .

Wang M, Bertmer M, Demco D, Blümich B, Litvinov V, Barthel H. Macromolecules , 2003 . 36 ( 12 ): 4411 - 4413 . DOI:10.1021/ma0217534http://doi.org/10.1021/ma0217534 .

Gao Y, Zhang R, Lv W, Liu Q, Wang X, Sun P, Winter H H, Xue G. J Phys Chem C , 2014 . 118 ( 10 ): 5606 - 5614 . DOI:10.1021/jp5013472http://doi.org/10.1021/jp5013472 .

Saalwächter K, Kleinschmidt F, Sommer J U. Macromolecules , 2004 . 37 ( 23 ): 8556 - 8568 . DOI:10.1021/ma048803khttp://doi.org/10.1021/ma048803k .

Wang F, Chen S, Wu Q, Zhang R, Sun P. Polymer , 2019 . 163 154 - 161 . DOI:10.1016/j.polymer.2018.12.062http://doi.org/10.1016/j.polymer.2018.12.062 .

Demco D E, Johansson A, Tegenfeldt J. Solid State Nucl Magn Reson , 1995 . 4 ( 1 ): 13 - 38 . DOI:10.1016/0926-2040(94)00036-Chttp://doi.org/10.1016/0926-2040(94)00036-C .

Huang C, Huang G, Li S, Luo M, Liu H, Fu X, Qu W, Xie Z, Wu J. Polymer , 2018 . 154 90 - 100 . DOI:10.1016/j.polymer.2018.08.057http://doi.org/10.1016/j.polymer.2018.08.057 .

Liu H, Huang G S, Wei L Y, Zeng J, Fu X, Huang C, Wu J R. Chinese J Polym Sci , 2019 . 37 ( 11 ): 1142 - 1151 . DOI:10.1007/s10118-019-2267-3http://doi.org/10.1007/s10118-019-2267-3 .

Kim S Y, Meyer H W, Saalwächter K, Zukoski C F. Macromolecules , 2012 . 45 ( 10 ): 4225 - 4237 . DOI:10.1021/ma300439khttp://doi.org/10.1021/ma300439k .

Ott M, Pérez-Aparicio R, Schneider H, Sotta P, Saalwächter K. Macromolecules , 2014 . 47 ( 21 ): 7597 - 7611 . DOI:10.1021/ma5012655http://doi.org/10.1021/ma5012655 .

Coleman M M, Painter P C, Graf J F. Specific Interactions and the Miscibility of Polymer Blends. New York: CRC Press, 2017

Tian D, Li T, Zhang R, Wu Q, Chen T, Sun P, Ramamoorthy A. J Phys Chem B , 2017 . 121 ( 25 ): 6108 - 6116 . DOI:10.1021/acs.jpcb.7b02838http://doi.org/10.1021/acs.jpcb.7b02838 .

Radloff D, Boeffel C, Spiess H W. Macromolecules , 1996 . 29 ( 5 ): 1528 - 1534 . DOI:10.1021/ma950405hhttp://doi.org/10.1021/ma950405h .

Zhang C, Yang Z, Duong N T, Li X, Nishiyama Y, Wu Q, Zhang R, Sun P. Macromolecules , 2019 . 52 ( 13 ): 5014 - 5025 . DOI:10.1021/acs.macromol.9b00503http://doi.org/10.1021/acs.macromol.9b00503 .

Li M, Zhang R, Li X, Wu Q, Chen T, Sun P. Polymer , 2018 . 148 127 - 137 . DOI:10.1016/j.polymer.2018.06.024http://doi.org/10.1016/j.polymer.2018.06.024 .

Yang Z, Wang F, Zhang C, Li J, Zhang R, Wu Q, Chen T, Sun P. Polym Chem , 2019 . 10 ( 24 ): 3362 - 3370 . DOI:10.1039/C9PY00383Ehttp://doi.org/10.1039/C9PY00383E .

Wojtecki R J, Meador M A, Rowan S J. Nat Mater , 2011 . 10 ( 1 ): 14 - 27 . DOI:10.1038/nmat2891http://doi.org/10.1038/nmat2891 .

Fantner G E, Hassenkam T, Kindt J H, Weaver J C, Birkedal H, Pechenik L, Cutroni J A, Cidade G A G, Stucky G D, Morse D E, Hansma P K. Nat Mater , 2005 . 4 ( 8 ): 612 - 616 . DOI:10.1038/nmat1428http://doi.org/10.1038/nmat1428 .

Sun T L, Kurokawa T, Kuroda S, Ihsan A B, Akasaki T, Sato K, Haque M A, Nakajima T, Gong J P. Nat Mater , 2013 . 12 ( 10 ): 932 - 937 . DOI:10.1038/nmat3713http://doi.org/10.1038/nmat3713 .

Sijbesma R P, Beijer F H, Brunsveld L, Folmer B J B, Hirschberg J H K K, Lange R F M, Lowe J K L, Meijer E W. Science , 1997 . 278 ( 5343 ): 1601 - 1604 . DOI:10.1126/science.278.5343.1601http://doi.org/10.1126/science.278.5343.1601 .

Robertson A J, Pandey M K, Marsh A, Nishiyama Y, Brown S P. J Magn Reson , 2015 . 260 89 - 97 . DOI:10.1016/j.jmr.2015.09.005http://doi.org/10.1016/j.jmr.2015.09.005 .

Zhang R, Mroue K H, Ramamoorthy A. Acc Chem Res , 2017 . 50 ( 4 ): 1105 - 1113 . DOI:10.1021/acs.accounts.7b00082http://doi.org/10.1021/acs.accounts.7b00082 .

Schaefer J, Stejskal E. J Am Chem Soc , 1976 . 98 ( 4 ): 1031 - 1032 . DOI:10.1021/ja00420a036http://doi.org/10.1021/ja00420a036 .

Pines A, Gibby M G, Waugh J. J Chem Phys , 1973 . 59 ( 2 ): 569 - 590 . DOI:10.1063/1.1680061http://doi.org/10.1063/1.1680061 .

Zhang R, Mroue K H, Ramamoorthy A. J Magn Reson , 2016 . 266 59 - 66 . DOI:10.1016/j.jmr.2016.03.006http://doi.org/10.1016/j.jmr.2016.03.006 .

Zhang R, Nishiyama Y, Ramamoorthy A. J Magn Reson , 2019 . 309 106615 DOI:10.1016/j.jmr.2019.106615http://doi.org/10.1016/j.jmr.2019.106615 .

Zhang R, Duong N T, Nishiyama Y, Ramamoorthy A. J Phys Chem B , 2017 . 121 ( 24 ): 5944 - 5952 . DOI:10.1021/acs.jpcb.7b03480http://doi.org/10.1021/acs.jpcb.7b03480 .

Zhang R, Mroue K H, Sun P, Ramamoorthy A. High-resolution proton NMR spectroscopy of polymers and biological solids. In: Webb G A. ed. Modern Magnetic Resonance. Cham: Springer International Publishing, 2018. Chapter 25

Zhang R, Chen Y, Rodriguez-Hornedo N, Ramamoorthy A. ChemPhysChem , 2016 . 17 ( 19 ): 2962 - 2966 . DOI:10.1002/cphc.201600637http://doi.org/10.1002/cphc.201600637 .

Maly T, Debelouchina G T, Bajaj V S, Hu K N, Joo C G, Mak-Jurkauskas M L, Sirigiri J R, Patrick C A V, Herzfeld J, Temkin R J, Griffin R G. J Chem Phys , 2008 . 128 ( 5 ): 052211 DOI:10.1063/1.2833582http://doi.org/10.1063/1.2833582 .

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