间甲钴黏合体系在轮胎骨架材料中的黏合机理研究

殷浩; 宋彦哲; 李云峰; 杜孟成; 逄见光; 史新妍

doi:10.11777/j.issn1000-3304.2019.19184

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间甲钴黏合体系在轮胎骨架材料中的黏合机理研究

论文 | 更新时间：2021-01-26

- 间甲钴黏合体系在轮胎骨架材料中的黏合机理研究
- Study on Adhesion Mechanism of Resorcinol Formaldehyde Cobalt Salt Adhesive System in Tire Skeleton Materials
- 高分子学报 2020年51卷第4期页码：411-420
- 作者机构：
  
  1.青岛科技大学高分子科学与工程学院橡塑材料与工程教育部重点实验室　青岛 266042
  2.山东阳谷华泰化工股份有限公司　阳谷 252300
- 作者简介：
  
  E-mail: lindashi88@hotmail.com
- 基金信息：
  
  山东省自然科学基金(基金号 ZR2018MEM025)资助项目
- DOI：10.11777/j.issn1000-3304.2019.19184
  中图分类号：
- 纸质出版日期：2020-4，
  
  网络出版日期：2020-3-20，
  
  收稿日期：2019-10-17，
  
  修回日期：2019-12-30，
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殷浩, 宋彦哲, 李云峰, 杜孟成, 逄见光, 史新妍. 间甲钴黏合体系在轮胎骨架材料中的黏合机理研究[J]. 高分子学报, 2020,51(4):411-420.

Hao Yin, Yan-zhe Song, Yun-feng Li, Meng-cheng Du, Jian-guang Pang, Xin-yan Shi. Study on Adhesion Mechanism of Resorcinol Formaldehyde Cobalt Salt Adhesive System in Tire Skeleton Materials[J]. Acta Polymerica Sinica, 2020,51(4):411-420.
殷浩, 宋彦哲, 李云峰, 杜孟成, 逄见光, 史新妍. 间甲钴黏合体系在轮胎骨架材料中的黏合机理研究[J]. 高分子学报, 2020,51(4):411-420. DOI： 10.11777/j.issn1000-3304.2019.19184.

Hao Yin, Yan-zhe Song, Yun-feng Li, Meng-cheng Du, Jian-guang Pang, Xin-yan Shi. Study on Adhesion Mechanism of Resorcinol Formaldehyde Cobalt Salt Adhesive System in Tire Skeleton Materials[J]. Acta Polymerica Sinica, 2020,51(4):411-420. DOI： 10.11777/j.issn1000-3304.2019.19184.

摘要

为验证与进一步探索黏合树脂及钴盐对轮胎与镀铜钢丝帘线的增黏作用机理，选取传统黏合树脂R80与2种新型黏合树脂HT1005和H620，通过对2种新型黏合树脂的结构分析、橡胶硫化特性、静态T抽出测试与力学性能测试，并设计了一种新的黏合层强度测试方法与黏合层表征方法，进行机理探索，得出如下结论：含有羟基的极性黏合树脂在橡胶硫化时，会由于与非极性天然橡胶的极性差异产生的热力学不相容从而产生自动相分离，向橡胶与镀铜钢丝的界面层进行迁移汇集，且极性越高迁移能力越强，产生一个介于橡胶与镀铜钢丝之间的树脂富集层. 因为黏合树脂交联反应温度为140 °C左右，会在天然橡胶硫化反应时发生同步交联反应，黏合树脂形成的网络模量高于橡胶硫化网络，会增强镀铜钢丝与橡胶之间的黏合层强度，并形成一个镀铜钢丝与橡胶之间的模量过渡层，进一步增强黏合层. 且极性越强，树脂网络交联程度与橡胶硫化网络交联程度越接近，增黏效果越好；钴盐会活化橡胶中的S，使更多的S迁移到镀铜钢丝表面从生成更多硫化亚铜键，增强黏合.

Abstract

The strong adhesion between the rubber and the skeleton material determines the performance of the tire. Most of the damage such as puncture

fatigue

and delamination of the tire are caused by the failure of the adhesion between the rubber and the skeleton material. The adhesion of the material is directly related to the performance and life of the tire. In order to verify and further explore the mechanism of adhesion of the adhesive resin and cobalt salt to the tire and the copper-plated steel cord

the conventional adhesive resin R80 and two new adhesive resins HT1005 and H620 were selected to analyze the mechanism of adhesion through structural analysis

rubber vulcanization characteristics

T extraction test

a new adhesive layer strength test method and adhesive layer characterization method. The results show that the polar adhesive resin containing hydroxyl groups will be auto-phase-separated due to thermodynamic incompatibility with the polarity difference of non-polar natural rubber when vulcanized. The adhesive resin migrates to the interface layer between the rubber and the copper-plated steel wire

producing a resin-rich layer between the rubber and the copper-plated steel wire. Since the crosslinking temperature of the binder resin is about 140 °C

synchronous crosslinking reaction will occur in natural rubber vulcanization reaction. The network modulus of the binder resin is higher than that of the rubber vulcanization network

which will enhance the adhesion strength between the copper-plated steel wire and the rubber

and form a modulus transition layer between the copper-plated steel wire and the rubber. A modulus transition layer between the rubber and the rubber further enhances the adhesive layer.

关键词

镀铜钢丝黏合树脂钴盐黏合机理

Keywords

Copper-plated steel wireAdhesive resinCobalt saltBonding mechanism

references

Das S, Koli P, Mathur J, Dey A, Bhattacharyya T, Bhattacharyya S. Failure Anal Prev , 2013 . 13 ( 6 ): 684 - 688 . DOI:10.1007/s11668-013-9750-xhttp://doi.org/10.1007/s11668-013-9750-x .

Daws J W. Practical Fail Anal , 2003 . 3 ( 5 ): 73 - 80 . DOI:10.1007/BF02717489http://doi.org/10.1007/BF02717489 .

Sarkar A. Saf Reliab , 2012 . 32 ( 2 ): 17 - 32.

Ooij W J V. Surf Sci , 1977 . 68 1 - 9 . DOI:10.1016/0039-6028(77)90184-4http://doi.org/10.1016/0039-6028(77)90184-4 .

Patil P Y, Ooij W J V. J Adhes Sci Technol , 2004 . 18 ( 12 ): 1367 - 1394 . DOI:10.1163/1568561042323266http://doi.org/10.1163/1568561042323266 .

Abou-Kandil A I, Saleh B K, Darwish N A. Rev Adhes Adhes , 2013 . 1 ( 4 ): 365 - 396 . DOI:10.7569/RAA.2013.097313http://doi.org/10.7569/RAA.2013.097313 .

Abou-Kandil A I, Awad A, Darwish N, Shehata A B, Sale B K. Int J Adhes Adhes , 2013 . 44 ( 44 ): 26 - 35.

Campion R P. Mater Sci Tech-lond , 1989 . 5 ( 3 ): 209 - 221 . DOI:10.1179/mst.1989.5.3.209http://doi.org/10.1179/mst.1989.5.3.209 .

Nah C, Sohn B Y, Park S J. J Adhes Sci Technol , 2002 . 16 ( 6 ): 653 - 667 . DOI:10.1163/156856102760099861http://doi.org/10.1163/156856102760099861 .

Kasperovich A V, Krotova O A, Potapov E E, Reznichenko S V, Shkodich V F. Polym Sci Ser , 2016 . 9 ( 1 ): 68 - 71 . DOI:10.1134/S1995421215040061http://doi.org/10.1134/S1995421215040061 .

Jeon, S G. J Adhes Sci Technol , 2008 . 22 ( 12 ): 1223 - 1253 . DOI:10.1163/156856108X319926http://doi.org/10.1163/156856108X319926 .

Jeon, S G. J Adhes Sci Technol , 2003 . 17 ( 6 ): 797 - 814 . DOI:10.1163/156856103321645167http://doi.org/10.1163/156856103321645167 .

Jeon G S, Seo G. Korean J Chem Eng , 2003 . 20 ( 3 ): 496 - 502 . DOI:10.1007/BF02705555http://doi.org/10.1007/BF02705555 .

Patil P Y. Mechanistic Investigation of Rubber-brass Adhesion. Doctoral Dissertation of University of Cincinnati, 2005

Chandra A K, Biswas A, Mukhopadhyay R, Bhowmick A K. J Adhes , 1994 . 44 ( 3 ): 20 - 22.

Sajith P, Ummer M T, Mandal N, Mandot S K, Agrawal S L, Bandyopadhyay S, Cruz B D, Deuri A S, Kuriakose A P. J Adhes Sci Technol , 2005 . 19 ( 16 ): 1475 - 1491 . DOI:10.1163/156856105774805868http://doi.org/10.1163/156856105774805868 .

Pu Qijun(蒲启君), Li Huating(李花婷), Xu Chunhua(许春华), Wu Jinwei(吴锦伟), Xu Chuanda(徐川大),Shi Jinkuan(时金宽), Jiang Zhiping(江志平). China Rubber Industry(橡胶工业) , 1996 . ( 12 ): 716 - 722.

Pu Qijun(蒲启君). China Rubber Industry(橡胶工业) , 1999 . ( 11 ): 683 - 695.

Lin Xiangyang(林向阳), Guan Qingjun(管清军), Huang Yigang(黄义钢). China Rubber(中国橡胶) , 2007 . 23 ( 3 ): 37 - 40 . DOI:10.3969/j.issn.1009-5640.2007.03.013http://doi.org/10.3969/j.issn.1009-5640.2007.03.013 .

Du Mengcheng(杜孟成), Li Yunfeng(李云峰), Yang Zhenlin(杨振林). Tire Industry(轮胎工业) , 2014 . 34 ( 4 ): 225 - 228 . DOI:10.3969/j.issn.1006-8171.2014.04.008http://doi.org/10.3969/j.issn.1006-8171.2014.04.008 .

Zhou Shunxu(周顺旭), Liu Qian(刘谦), Shan Guoling(单国玲). Tire Industry(轮胎工业) , 1997 . ( 12 ): 722 - 725.

Qian Honglian(钱红莲), Wang Pingyue(王平粤), Yang Chunliang(杨春亮). Special Purpose Rubber Products(特种橡胶制品) , 2004 . 25 ( 3 ): 51 - 53 . DOI:10.3969/j.issn.1005-4030.2004.03.017http://doi.org/10.3969/j.issn.1005-4030.2004.03.017 .

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