接枝点分布对ABA三嵌段共聚物刷自组装形态的影响

徐纪华; 陈印启; 尹玉华; 蒋润; 王铮; 李宝会

doi:10.11777/j.issn1000-3304.2019.19204

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接枝点分布对ABA三嵌段共聚物刷自组装形态的影响

论文 | 更新时间：2021-01-26

- 接枝点分布对ABA三嵌段共聚物刷自组装形态的影响
- Influence of Grafting Point Distribution on Self-assembly Morphology of ABA Triblock Copolymer Brush
- 高分子学报 2020年51卷第6期页码：632-640
- 作者机构：
  
  1.山东师范大学物理与电子科学学院　济南 250358
  2.南开大学物理科学学院　天津 300071
- 作者简介：
  
  E-mail: xujihua23@163.com Ji-hua Xu, E-mail: xujihua23@163.com
- 基金信息：
  
  国家自然科学基金(基金号 11504208，21674053)资助项目
- DOI：10.11777/j.issn1000-3304.2019.19204
  中图分类号：
- 纸质出版日期：2020-6，
  
  网络出版日期：2020-4-13，
  
  收稿日期：2019-12-5，
  
  修回日期：2020-1-7，
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徐纪华, 陈印启, 尹玉华, 蒋润, 王铮, 李宝会. 接枝点分布对ABA三嵌段共聚物刷自组装形态的影响[J]. 高分子学报, 2020,51(6):632-640.

Ji-hua Xu, Yin-qi Chen, Yu-hua Yin, Run Jiang, Zheng Wang, Bao-hui Li. Influence of Grafting Point Distribution on Self-assembly Morphology of ABA Triblock Copolymer Brush[J]. Acta Polymerica Sinica, 2020,51(6):632-640.
徐纪华, 陈印启, 尹玉华, 蒋润, 王铮, 李宝会. 接枝点分布对ABA三嵌段共聚物刷自组装形态的影响[J]. 高分子学报, 2020,51(6):632-640. DOI： 10.11777/j.issn1000-3304.2019.19204.

Ji-hua Xu, Yin-qi Chen, Yu-hua Yin, Run Jiang, Zheng Wang, Bao-hui Li. Influence of Grafting Point Distribution on Self-assembly Morphology of ABA Triblock Copolymer Brush[J]. Acta Polymerica Sinica, 2020,51(6):632-640. DOI： 10.11777/j.issn1000-3304.2019.19204.

摘要

采用模拟退火方法研究了接枝点分布对ABA 三嵌段共聚物刷在选择性溶剂中自组装形态的影响，其中溶剂对A单体为不良溶剂，对B单体为良溶剂. 主要以高接枝密度体系为例，研究了均匀接枝、区域随机接枝和全随机接枝时共聚物刷聚集体的形态，分别构建了3种接枝方式下体系的相图，并考察了接枝点分布对ABA三嵌段共聚物刷形态的影响机制. 研究表明3种接枝方式下，ABA三嵌段共聚物刷体系形成相图大致相同，并且单层A聚集体结构与双层A聚集体结构在相图中的分界线相同；接枝点分布主要对底部的A富集层胶束形态产生影响，而对顶层胶束形态影响很小. 在随机接枝时，接枝点的密度涨落导致底层A聚集体不易形成较规则的形态，其长程有序性较低.

Abstract

The simulated annealing method was used to study the self-assembly morphology of the symmetrical ABA triblock copolymer brush formed with one end of the A-blocks tethered onto a planar surface. The copolymer brush was immersed in a selective solvent which is poor for the A-blocks but good for the middle B-blocks. Taking the system at high grafting density as an example

the morphology of the copolymer brush aggregates during uniformal grafting

local random grafting and global random grafting were investigated

and the phase diagram was constructed. The simulation studies showed that the position distribution of the grafting point mainly affect the morphology of aggregates near the bottom layer for ABA triblock copolymer brushes. A similar self-assembled morphology could be formed during uniformal grafting

region random grafting

and global random grafting. However

the density fluctuation of the grafting point caused the micelle morphology formed under random grafting

which did not have the regular shape as that formed under uniformal grafting

and the long-range order in the microphase-segregated structures is reduced. The self-assembled morphologies of homopolymer brushes in poor solvent and AB diblock copolymer brushes in the solvent which is selective for the tethered A-blocks but poor for the top B-blocks were also investigated to further understand the results mentioned above.

关键词

三嵌段共聚物刷模拟退火自组装接枝点

Keywords

Triblock copolymer brushSimulated annealingSelf-assemblyGrafting point

references

Pochan D J, Chen Z, Cui H, Hales K, Qi K, Wooley K L. Science , 2004 . 306 ( 5693 ): 94 - 97 . DOI:10.1126/science.1102866http://doi.org/10.1126/science.1102866 .

He X, Schmid F. Phys Rev Lett , 2008 . 100 ( 13 ): 137802 DOI:10.1103/PhysRevLett.100.137802http://doi.org/10.1103/PhysRevLett.100.137802 .

Yu K, Eisenberg A. Macromolecules , 1998 . 31 ( 11 ): 3509 - 3518 . DOI:10.1021/ma971419lhttp://doi.org/10.1021/ma971419l .

Raez J, Barjovanu R, Massey J A, Winnik M A, Manners L. Angew Chem Int Ed , 2000 . 39 ( 21 ): 3862 - 3865 . DOI:10.1002/1521-3773(20001103)39:21<3862::AID-ANIE3862>3.0.CO;2-1http://doi.org/10.1002/1521-3773(20001103)39:21<3862::AID-ANIE3862>3.0.CO;2-1 .

Shen H, Eisenberg A. Angew Chem Int Ed , 2000 . 39 ( 18 ): 3310 - 3312 . DOI:10.1002/1521-3773(20000915)39:18<3310::AID-ANIE3310>3.0.CO;2-2http://doi.org/10.1002/1521-3773(20000915)39:18<3310::AID-ANIE3310>3.0.CO;2-2 .

Dimova R, Seifert U, Pouligny B, Förster S, Döbereiner H G. Eur Phys J E , 2002 . 7 ( 3 ): 241 - 250.

Lim Soo P, Eisenberg A. J Polym Sci, Part B: Polym Phys , 2004 . 42 ( 6 ): 923 - 938 . DOI:10.1002/polb.10739http://doi.org/10.1002/polb.10739 .

Nardin C, Hirt T, Leukel J, Meier W. Langmuir , 2000 . 16 ( 3 ): 1035 - 1041 . DOI:10.1021/la990951uhttp://doi.org/10.1021/la990951u .

Meng Jianqiang(孟建强), Dong Yongquan(董永全), Li Zichen(李子臣). Acta Polymerica Sinica(高分子学报) , 2010 . ( 5 ): 550 - 555 . DOI:10.3724/SP.J.1105.2010.09174http://doi.org/10.3724/SP.J.1105.2010.09174 .

Blanazs A, Armes S P, Ryan A J. Macromol Rapid Commun , 2009 . 30 ( 4-5 ): 267 - 277 . DOI:10.1002/marc.200800713http://doi.org/10.1002/marc.200800713 .

Yang S Y, Yang J A, Kim E S, Jeon G, Choi K Y, Hahn S K. ACS Nano , 2010 . 4 ( 7 ): 3817 - 3822 . DOI:10.1021/nn100464uhttp://doi.org/10.1021/nn100464u .

Jackson E A, Hillmyer M A. ACS Nano , 2010 . 4 ( 7 ): 3548 - 3553 . DOI:10.1021/nn1014006http://doi.org/10.1021/nn1014006 .

Kazunori K, Glenn S K, Masayuki Y, Teruo O, Yasuhisa S. J Control Release , 1993 . 24 ( 1-3 ): 119 - 132 . DOI:10.1016/0168-3659(93)90172-2http://doi.org/10.1016/0168-3659(93)90172-2 .

Gaucher G, Dufresne M H, Sant V P, Kang N, Maysinger D, Leroux J C. J Control Release , 2005 . 109 ( 1-3 ): 169 - 188 . DOI:10.1016/j.jconrel.2005.09.034http://doi.org/10.1016/j.jconrel.2005.09.034 .

Allen C, Maysinger D, Eisenberg A. Colloid Surface B , 1999 . 16 ( 1-4 ): 3 - 27 . DOI:10.1016/S0927-7765(99)00058-2http://doi.org/10.1016/S0927-7765(99)00058-2 .

Lu A, O’Reilly R K. Curr Opin Biotech , 2013 . 24 ( 4 ): 639 - 645 . DOI:10.1016/j.copbio.2012.11.013http://doi.org/10.1016/j.copbio.2012.11.013 .

Kim K T, Cornelissen J J L M, Nolte R J M, Nolte R J M. Adv Mater , 2009 . 21 ( 27 ): 2787 - 2791 . DOI:10.1002/adma.200900300http://doi.org/10.1002/adma.200900300 .

Zhao B, Brittain W J. Prog Polym Sci , 2000 . 25 ( 5 ): 677 - 710 . DOI:10.1016/S0079-6700(00)00012-5http://doi.org/10.1016/S0079-6700(00)00012-5 .

Chen W L, Cordero R, Tran H, Ober C K. Macromolecules , 2017 . 50 ( 11 ): 4089 - 4113 . DOI:10.1021/acs.macromol.7b00450http://doi.org/10.1021/acs.macromol.7b00450 .

Keating J J, Imbrogno J, Belfort G. ACS Appl Mater Interfaces , 2016 . 8 ( 42 ): 28383 - 28399 . DOI:10.1021/acsami.6b09068http://doi.org/10.1021/acsami.6b09068 .

Senaratne W, Andruzzi L, Ober C K. Biomacromolecules , 2005 . 6 ( 5 ): 2427 - 2448 . DOI:10.1021/bm050180ahttp://doi.org/10.1021/bm050180a .

Xu J, Yin Y, Wang Z, Jiang R, Li B, Shi A C. J Chem Phys , 2013 . 138 ( 11 ): 114905 DOI:10.1063/1.4795578http://doi.org/10.1063/1.4795578 .

Cui Baobao(崔宝宝), Pan Junxing(潘俊星), Zhang Jinjun(张进军), Sun Minna(孙敏娜), Guo Yuqi(郭宇琦),Cen Jianyong(岑建勇), Wu Haishun(武海顺). Acta Polymerica Sinica(高分子学报) , 2017 . ( 6 ): 959 - 966 . DOI:10.11777/j.issn1000-3304.2017.16285http://doi.org/10.11777/j.issn1000-3304.2017.16285 .

Cao Xuguang(曹旭光), Jiang Tao(蒋涛), Wang Liquan(王立权), Zhang Liangshun(张良顺), Lin Jiaping(林嘉平),Cai Chunhua(蔡春华). Acta Polymerica Sinica(高分子学报) , 2015 . ( 4 ): 475 - 483 . DOI:10.11777/j.issn1000-3304.2015.14339http://doi.org/10.11777/j.issn1000-3304.2015.14339 .

Yin Y, Sun P, Li B, Chen T, Jin Q, Ding D, Shi A C. Macromolecules , 2007 . 40 ( 14 ): 5161 - 5170 . DOI:10.1021/ma070393nhttp://doi.org/10.1021/ma070393n .

Guskova O A, Seidel C. Macromolecules , 2011 . 44 ( 3 ): 671 - 682 . DOI:10.1021/ma102349khttp://doi.org/10.1021/ma102349k .

Xu C, Wu T, Drain C M, Batteas J D, Fasolka M J, Beers K L. Macromolecules , 2006 . 39 ( 9 ): 3359 - 3364 . DOI:10.1021/ma051405chttp://doi.org/10.1021/ma051405c .

Zhang R, Zhou T, Peng H, Li M, Zhu X, Yao Y. J Membr Sci , 2019 . 580 117 - 124 . DOI:10.1016/j.memsci.2019.03.020http://doi.org/10.1016/j.memsci.2019.03.020 .

Marschelke C, Puretskiy N, Raguzin I, Melnyk I, Lonov L, Syntska A. Macromol Chem Phys , 2019 . 220 ( 10 ): 1900030 DOI:10.1002/macp.201900030http://doi.org/10.1002/macp.201900030 .

Zhang Shuo(张朔), Cai Chunhua(蔡春华), Huang Qijing(黄琦婧), Lin Jiaping(林嘉平), Xu Zhanwen(许占文). Acta Polymerica Sinica(高分子学报) , 2018 . ( 1 ): 109 - 118 . DOI:10.11777/j.issn1000-3304.2018.17223http://doi.org/10.11777/j.issn1000-3304.2018.17223 .

Xu Jihua(徐纪华), Jiang Run(蒋润), Yin Yuhua(尹玉华), WangZheng(王铮), Li Baohui(李宝会). Acta Polymerica Sinica(高分子学报) , 2013 . ( 10 ): 1277 - 1284 . DOI:10.3724/SP.J.1105.2013.13028http://doi.org/10.3724/SP.J.1105.2013.13028 .

Wischerhoff E, Badi N, Lutz J F, Laschewsky A. Soft Matter , 2010 . 6 ( 4 ): 705 - 713 . DOI:10.1039/B913594Dhttp://doi.org/10.1039/B913594D .

Cabane E, Zhang X, Langowska K, Palivan C G, Meier W. Biointerphases , 2012 . 7 ( 9 ): 1 - 7.

Glinel K, Jonas A M, Jouenne T, Leprince J, Huck W T S. Bioconjugate Chem , 2009 . 20 ( 1 ): 71 - 77 . DOI:10.1021/bc800280uhttp://doi.org/10.1021/bc800280u .

Cheng G, Xue H, Zhang Z, Chen S, Jiang S. Angew Chem Int Ed , 2008 . 47 ( 46 ): 8831 - 8834 . DOI:10.1002/anie.200803570http://doi.org/10.1002/anie.200803570 .

Raviv U, Giasson S, Kampf N, Gohy J F, Klein R J J. Nature , 2003 . 425 ( 6954 ): 163 DOI:10.1038/nature01970http://doi.org/10.1038/nature01970 .

Kobayashi M, Terada M, Takahara A. Faraday Discuss , 2012 . 156 ( 1 ): 403 - 412.

Léger L, Raphaël E, Hervet H. Polymers in Confined Environments. Berlin: Heidelberg, 1999. 185−225

Landherr L J T, Cohen C, Agarwal P, Archer L A. Langmuir , 2011 . 27 ( 15 ): 9387 - 9395 . DOI:10.1021/la201396mhttp://doi.org/10.1021/la201396m .

Mansky P, Liu Y, Huang E, Russell T P, Hawker C. Science , 1997 . 275 ( 5305 ): 1458 - 1460 . DOI:10.1126/science.275.5305.1458http://doi.org/10.1126/science.275.5305.1458 .

Boyes S G, Brittain W J, Weng X, Russell T P, Hawker C. Macromolecules , 2002 . 35 ( 13 ): 4960 - 4967 . DOI:10.1021/ma020109mhttp://doi.org/10.1021/ma020109m .

Boyes S G, Granville A M, Baum M, Akgun B, Mirous B K, Brittain W J. Surf Sci , 2004 . 570 ( 1-2 ): 1 - 12 . DOI:10.1016/j.susc.2004.06.193http://doi.org/10.1016/j.susc.2004.06.193 .

Price A D, Hur S M, Fredrickson G H, Frischknecht A L, Huber D L. Macromolecules , 2011 . 45 ( 1 ): 510 - 524.

Yin Y, Jiang R, Wang Z, Li B, Shi A C. Langmuir , 2016 . 32 ( 30 ): 7467 - 7475 . DOI:10.1021/acs.langmuir.6b01448http://doi.org/10.1021/acs.langmuir.6b01448 .

Carmesin I, Kremer K. Macromolecules , 1988 . 21 ( 9 ): 2819 - 2823 . DOI:10.1021/ma00187a030http://doi.org/10.1021/ma00187a030 .

Larson R G. J Chem Phys , 1992 . 96 ( 11 ): 7904 - 7918 . DOI:10.1063/1.462343http://doi.org/10.1063/1.462343 .

Yin Y, Sun P, Chen T, Chen T, Li B, Jin Q, Ding D, Shi A. ChemPhysChem , 2004 . 5 ( 4 ): 540 - 548 . DOI:10.1002/cphc.200300999http://doi.org/10.1002/cphc.200300999 .

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