高性能锂离子电池正极黏合剂研究进展

王亚丽; 刘丙学; 田国峰; 齐胜利; 武德珍

doi:10.11777/j.issn1000-3304.2019.19215

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高性能锂离子电池正极黏合剂研究进展

综述 | 更新时间：2021-01-26

- 高性能锂离子电池正极黏合剂研究进展
- Research Progress of Cathode Binder for High Performance Lithium-ion Battery
- 高分子学报 2020年51卷第4期页码：326-337
- 作者机构：
  
  1.北京化工大学化工资源有效利用国家重点实验室　北京 100029
  2.北京化工大学常州先进材料研究院　常州 213164
  3.国联汽车动力电池研究院有限责任公司　北京 101407
- 作者简介：
  
  [ "齐胜利，男，1982年生，2008年于北京化工大学获博士学位，2009 ~ 2011年于日本名古屋大学从事JSPS博士后研究，现为北京化工大学材料科学与工程学院教授、博士生导师，曾获江苏省杰出青年基金(2014年)资助，以第一作者和通讯作者发表SCI论文50余篇，获授权专利20余项. 主要研究方向为高性能及功能聚酰亚胺材料的分子结构设计及其在柔性显示、信息存储及二次能源系统中的应用" ]
- 基金信息：
  
  国家自然基金(基金号 5167301)、国家重点基础研究发展计划(973计划，项目号 2014CB643604，2014CB643606)、中央高校基本科研业务费专项资金资(基金号 XK1802-2)、中国航空科学基金(基金号 201718S9001)和江苏省杰出青年基金(基金号 BK20140006)资助项目
- DOI：10.11777/j.issn1000-3304.2019.19215
  中图分类号：
- 纸质出版日期：2020-4，
  
  网络出版日期：2020-3-24，
  
  收稿日期：2019-12-23，
  
  修回日期：2020-1-17，
扫描看全文
王亚丽, 刘丙学, 田国峰, 齐胜利, 武德珍. 高性能锂离子电池正极黏合剂研究进展[J]. 高分子学报, 2020,51(4):326-337.

Ya-li Wang, Bing-xue Liu, Guo-feng Tian, Sheng-li Qi, De-zhen Wu. Research Progress of Cathode Binder for High Performance Lithium-ion Battery[J]. Acta Polymerica Sinica, 2020,51(4):326-337.
王亚丽, 刘丙学, 田国峰, 齐胜利, 武德珍. 高性能锂离子电池正极黏合剂研究进展[J]. 高分子学报, 2020,51(4):326-337. DOI： 10.11777/j.issn1000-3304.2019.19215.

Ya-li Wang, Bing-xue Liu, Guo-feng Tian, Sheng-li Qi, De-zhen Wu. Research Progress of Cathode Binder for High Performance Lithium-ion Battery[J]. Acta Polymerica Sinica, 2020,51(4):326-337. DOI： 10.11777/j.issn1000-3304.2019.19215.

摘要

正极黏合剂是维持锂离子电池正极结构稳定性的关键材料，对于锂离子电池的能量密度及安全性具有重要作用. 本文综述了锂离子电池正极黏合剂材料的研究及应用进展，重点介绍了锂离子电池正极黏合剂对于正极材料及锂离子电池电化学性能的影响，详细总结了以聚偏氟乙烯(PVDF)、聚酰亚胺(PI)、功能性聚合物黏合剂为代表的油溶性黏合剂和以聚丙烯酸(PAA)、羧甲基纤维素(CMC)为代表的水溶性黏合剂的特点：PVDF具备良好的化学稳定性，黏合效果较好，但耐高温性能差且在电解液中易溶胀；PI的耐高温性能优异，机械性能较好，但成本相对较高；功能性聚合物黏合剂具备良好的导电性，可有效抑制 Li-S 锂电池中多硫化物的穿梭效应，但制备工艺复杂；PAA的柔性较好，抗高压能力较强，但是力学性能较差；CMC具有良好的分散性，机械强度较大，因脆性较大需与丁苯橡胶(SBR)配合使用. 结合已有的研究报道，探讨了高性能锂离子电池先进正极黏合剂材料的未来发展方向及前景.

Abstract

Developing high-performance battery systems requires the collaborative optimization of every battery components

including electrodes

electrolyte

separators and binder systems. The strategies of synthesizing electrode materials and developing novel electrolyte system are widely investigated. Cathode binder

a crucial material to maintain structure stability of cathode

plays an essential role in efficiently enhancing energy density and ensuring safety of lithium ion battery. In recent years

designing advanced binder systems has attracted researchers’ attention. In this account

the research progress on material and structural design of cathode binder and application about cathode binder of lithium ion battery are reviewed comprehensively. The effects that cathode binders play on stabilizing cathode material

promoting reduction of battery internal impedance and regulating electrochemical performances of lithium ion battery are primarily introduced. Meanwhile

the characteristics of the oil-soluble binder represented by poly(vinylidene fluoride) (PVDF)

polyimide (PI)

functional polymer binder and the water-soluble binder represented by poly(acrylic acid) (PAA) and carboxymethyl cellulose (CMC) are concluded in detail. PVDF has good chemical stability and adhesion

but suffers from large swelling ratio; PI has excellent high temperature resistance and good mechanical properties

but the cost is relatively high; functional polymer binder has good electrical conductivity and can effectively suppress the shuttle effect of Li-S lithium batteries

but the preparation process is complicated; PAA is flexible

but mechanical properties are poor; CMC has good dispersibility and large mechanical strength

but it needs to be matched with styrene-butadiene rubber due to the large brittleness. Furthermore

combining with the existing research reports

methods of designing advanced cathode binder systems are concluded to provide valuable guidance for the performance optimization. The development prospects and application exploration are also discussed.

关键词

锂离子电池正极黏合剂聚偏氟乙烯聚酰亚胺功能性聚合物聚丙烯酸羧甲基纤维素

Keywords

Lithium-ion batteryCathode binderPoly(vinylidene fluoride)PolyimideFunctional polymer binderPoly(acrylic acid)Carboxymethyl cellulose

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