基于聚乙烯的阴离子交换隔膜的制备策略

陆祺然; 尤伟

doi:10.11777/j.issn1000-3304.2020.10123

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基于聚乙烯的阴离子交换隔膜的制备策略

专论 | 更新时间：2021-01-26

- 基于聚乙烯的阴离子交换隔膜的制备策略
- Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones
- 高分子学报 2020年51卷第10期页码：1140-1146
- 作者机构：
  
  1.中国科学院化学研究所北京分子科学国家研究中心中国科学院工程塑料重点实验室　北京 100190
  2.中国科学院大学　北京 100049
- 作者简介：
  
  [ "尤伟，男，1989年生. 2011年于清华大学获得理学学士学位；2016年于美国印第安纳大学布鲁明顿分校获得理学博士学位，导师为M. Kevin Brown教授. 2016 ~ 2019年于美国康奈尔大学从事博士后研究，导师为Geoffrey W. Coates教授. 2019年11月起，于中国科学院化学研究所工程塑料实验室任项目研究员、课题组长，主要从事新型碱性阴离子交换隔膜的设计与合成，对有机化学、高分子化学与电化学的前沿交叉领域进行探究" ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.10123
  中图分类号：
- 纸质出版日期：2020-9-1，
  
  网络出版日期：2020-7-27，
  
  收稿日期：2020-5-15，
  
  修回日期：2020-6-1，
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陆祺然, 尤伟. 基于聚乙烯的阴离子交换隔膜的制备策略[J]. 高分子学报, 2020,51(10):1140-1146.

Qi-ran Lu, Wei You. Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones[J]. Acta Polymerica Sinica, 2020,51(10):1140-1146.
陆祺然, 尤伟. 基于聚乙烯的阴离子交换隔膜的制备策略[J]. 高分子学报, 2020,51(10):1140-1146. DOI： 10.11777/j.issn1000-3304.2020.10123.

Qi-ran Lu, Wei You. Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones[J]. Acta Polymerica Sinica, 2020,51(10):1140-1146. DOI： 10.11777/j.issn1000-3304.2020.10123.

摘要

随着人们对生活环境的保护和对可持续发展的需求与日俱增，对于能够实现清洁、高效、廉价能源转化的电化学设备的研究也日益深入. 当这些设备在碱性环境下运行时，可以传输氢氧根的阴离子交换膜（AEM）就是核心部件之一，而AEM的离子导电性和碱性稳定性直接关系着设备的能量转化效率和耐久性. 具有聚乙烯骨架的阴离子交换膜(PE-AEM)由于其化学稳定性突出、阳离子兼容性好、机械性能柔韧等优点，近些年来受到了广泛的关注. 本专论归纳了PE-AEM的合成策略，包括聚合氢化法、直接共聚法和后修饰接枝法，在其中着重介绍环辛烯开环易位聚合(ROMP)后还原方法的发展历程，比较不同制备路线的优缺点，总结产物的化学结构和性能的关系，并且对PE-AEM的前景进行了展望.

Abstract

With the emerging demand of environmental protection and sustainable development

devices that can perform clean

efficient

and inexpensive energy conversion (

e.g.

alkaline fuel cells

water electrolysis

redox flow batteries

etc.

) have attracted increasing attention. Anion exchange membranes (AEMs) are a class of solid polyelectrolytes that are key components in the above-mentioned alkaline energy conversion devices to transport hydroxide anions. Two of the key properties of AEMs are ionic conductivity and alkaline stability

as they are directly related to the efficiency and durability of the devices

respectively. The AEMs bearing polyethylene backbones (PE-AEMs) have outstanding chemical stability

good compatibility with various cations

and strong mechanical properties

and thus they become promising candidates for high-performance AEMs. In this account

we summarize the synthetic strategies of PE-AEMs

which include ring-opening-metathesis polymerization (ROMP) followed by hydrogenation

derivatization of poly(ethylene-

-styrene)

direct copolymerization of functionalized terminal alkenes with ethylene

and radiation graft to modify polyethylene films. Among all these strategies

we specifically focus on the development of sequential cyclooctene ROMP and hydrogenation strategy

as it has the advantages of well-defined polymer structures

precise control of functionality distribution

and excellent tolerance to diverse functional groups. We also evaluate the structure-property relationship of the resultant PE-AEM membranes and discuss the future of these materials.

关键词

阴离子交换膜聚乙烯合成策略碱性稳定性

Keywords

Anion exchange membranePolyethyleneSynthetic strategyAlkaline stability

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