稀土催化极性单体配位均聚及与非极性单体共聚合的研究

崔冬梅

doi:10.11777/j.issn1000-3304.2020.19142

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稀土催化极性单体配位均聚及与非极性单体共聚合的研究

综述 | 更新时间：2021-04-27

- 稀土催化极性单体配位均聚及与非极性单体共聚合的研究
- Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts
- 高分子学报 2020年51卷第1期页码：12-29
- 作者机构：
  
  中国科学院长春应用化学研究所　长春 130022
- 作者简介：
  
  [ "崔冬梅，女，1963年生. 1981 ~ 1988年就读于大连理工大学，获得学士和硕士学位；1998 ~ 2001年，中科学院长春应用化学研究所获得博士学位. 1988 ~ 1992年，沈阳药科大学，讲师；1992 ~ 2002年，长春工业大学，讲师，副教授，教授(2002年)；2002年5 ~ 8月，香港浸会大学，访问学者；2002 ~ 2004年，日本理化学研究所(Riken)，JSPS博士后；2013年9 ~ 11月，美国科罗拉多州立大学，访问教授；2004年11月至今，中国科学院长春应用化学研究所，研究员. 研究方向是金属有机合成与可控聚合. 主要针对通用单体的立体选择性聚合，制备高立构规整度、功能性、高附加值的聚烯烃材料. 发表论文160余篇，申请及获授权专利40件，其中国际专利5件" ]
- 基金信息：
  
  国家自然科学基金(基金号 21634007)资助项目
- DOI：10.11777/j.issn1000-3304.2020.19142
  中图分类号：
- 纸质出版日期：2020-1，
  
  网络出版日期：2019-10-23，
  
  收稿日期：2019-7-31，
  
  修回日期：2019-8-28，
扫描看全文
崔冬梅. 稀土催化极性单体配位均聚及与非极性单体共聚合的研究[J]. 高分子学报, 2020,51(1):12-29.

Dong-mei Cui. Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts[J]. Acta Polymerica Sinica, 2020,51(1):12-29.
崔冬梅. 稀土催化极性单体配位均聚及与非极性单体共聚合的研究[J]. 高分子学报, 2020,51(1):12-29. DOI： 10.11777/j.issn1000-3304.2020.19142.

Dong-mei Cui. Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts[J]. Acta Polymerica Sinica, 2020,51(1):12-29. DOI： 10.11777/j.issn1000-3304.2020.19142.

摘要

将极性基团引入大分子链中可改善非极性聚烯烃材料的表面性能，扩展其应用范围甚至带来不可预见的新功能，是市场需求并由企业驱动. 与聚合后功能化改性和物理共混方法相比，极性与非极性单体配位共聚合是最直接和简便的方法，适用范围广，并可保持聚烯烃的立构规整度，一直以来，相关研究备受企业和科研工作者瞩目. 然而，极性基团通常具有Lewis碱性，容易与Lewis酸性的聚合催化剂强烈螯合而致其毒化，因此，这又是极具挑战性的课题. 目前，该领域的研究取得了很大的进展，已经实现了乙烯与很多极性单体的共聚合. 今后，将集中解决如何实现极性单体均聚合，提高共聚合活性，特别是极性单体插入率和分布可调节性，保持立体选择性，以及获得高分子量、具有实际应用意义的共聚产物等问题. 本文旨在将课题组近年来在极性功能化苯乙烯和共轭双烯烃单体的均聚合及与苯乙烯、乙烯和共轭双烯烃等非极性单体共聚合方面的最新研究成果以及国内外该领域的相关报道进行综合阐述，为读者提供解决上述关键问题采用的研究路线、实施方法和创新性思维.

Abstract

The homo- and co-polymerizations of polar and non-polar monomers

since they can remain the stereo-regularity of the non-polyolefin precursors and meanwhile introduce polar groups into the non-polar polyolefins to improve their surface properties or bring unpredicted new functionalities

have attracted great attention of both academia and industries. However

polar groups are Lewis-basic while the catalysts employed in the polymerizations are usually Lewis acidic

which are prone to interact with the catalytic metal center to poison the catalysts

thus the study on homo- and co-polymerizations has been a challenging project. To date

many achievements have been obtained

and the following research should focus on realizing the homopolymerizations of polar monomers

increasing the activity and insertion ratio of the polar monomer in the copolymers

regulating the polar monomer composition and distribution along the copolymer macromolecular chains and isolating high molecular weight and practically available products. In this review

we summarized the recent developments of our group on the homo- and co-polymerizations of polar monomers

in particular polar styrenes and conjugated dienes with styrene

ethylene

butadien

isoprene and other popular nonpolar olefins

aiming to provide the readers novel strategies for designing new catalysts and polar monomers

as well as the unprecedented mechanisms.

关键词

稀土催化剂配位聚合极性单体共轭烯烃聚烯烃

Keywords

Rare-earth metal catalystCoordination polymerizationPolar monomerConjugated dienesPolyolefin

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