官能化聚四氢呋喃-<italic style="font-style: italic">b</italic>-聚异丁烯-<italic style="font-style: italic">b</italic>-聚四氢呋喃三嵌段共聚物的合成与性能

张方; 张航天; 杨甜; 孔波; 郭安儒; 章琦; 吴一弦

doi:10.11777/j.issn1000-3304.2020.19151

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官能化聚四氢呋喃-b-聚异丁烯-b-聚四氢呋喃三嵌段共聚物的合成与性能

论文 | 更新时间：2021-04-27

- 官能化聚四氢呋喃-b-聚异丁烯-b-聚四氢呋喃三嵌段共聚物的合成与性能
- Synthesis and Property of Novel Functionalized Polytetrahydrofuran-b-polyisobutylene-b-polytetrahydrofuran Triblock Copolymers
- 高分子学报 2020年51卷第1期页码：98-116
- 作者机构：
  
  北京化工大学化工资源有效利用国家重点实验室生物医用材料北京实验室　北京 100029
- 作者简介：
  
  E-mail: wuyx@mail.buct.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 51521062，21574007)资助项目
- DOI：10.11777/j.issn1000-3304.2020.19151
  中图分类号：
- 纸质出版日期：2020-1，
  
  网络出版日期：2019-11-12，
  
  收稿日期：2019-8-10，
  
  修回日期：2019-9-9，
扫描看全文
张方, 张航天, 杨甜, 孔波, 郭安儒, 章琦, 吴一弦. 官能化聚四氢呋喃-b-聚异丁烯-b-聚四氢呋喃三嵌段共聚物的合成与性能[J]. 高分子学报, 2020,51(1):98-116.

Fang Zhang, Hang-tian Zhang, Tian Yang, Bo Kong, An-ru Guo, Qi Zhang, Yi-xian Wu. Synthesis and Property of Novel Functionalized Polytetrahydrofuran-b-polyisobutylene-b-polytetrahydrofuran Triblock Copolymers[J]. Acta Polymerica Sinica, 2020,51(1):98-116.
张方, 张航天, 杨甜, 孔波, 郭安儒, 章琦, 吴一弦. 官能化聚四氢呋喃-b-聚异丁烯-b-聚四氢呋喃三嵌段共聚物的合成与性能[J]. 高分子学报, 2020,51(1):98-116. DOI： 10.11777/j.issn1000-3304.2020.19151.

Fang Zhang, Hang-tian Zhang, Tian Yang, Bo Kong, An-ru Guo, Qi Zhang, Yi-xian Wu. Synthesis and Property of Novel Functionalized Polytetrahydrofuran-b-polyisobutylene-b-polytetrahydrofuran Triblock Copolymers[J]. Acta Polymerica Sinica, 2020,51(1):98-116. DOI： 10.11777/j.issn1000-3304.2020.19151.

摘要

采用2-氯-2

4-三甲基戊烷或对二枯基氯为引发剂和TiCl

或FeCl

为共引发剂，引发异丁烯(IB)可控/活性正离子聚合与官能端基转化，设计合成不同分子量及窄分子量分布的端基官能化聚异丁烯，如双端烯丙基溴官能化聚异丁烯(Br-PIB-Br)或双端烯丙基胺官能化聚异丁烯(H

N-PIB-NH

). 采用烯丙基溴/高氯酸银体系引发四氢呋喃(THF)开环聚合，合成聚四氢呋喃活性链(PTHF

). 进一步通过将IB可控/活性正离子聚合与THF可控/活性正离子开环聚合2种方法相结合，设计合成2种新型官能化聚四氢呋喃-

-聚异丁烯-

-聚四氢呋喃(PTHF-

-PIB-

-PTHF)三嵌段共聚物：(1)以上述Br-PIB-Br为大分子引发剂，在AgClO

作用下引发THF活性正离子开环聚合，采用水终止活性链端，设计合成双端为羟基的HO-PTHF-

-PIB-

-PTHF-OH三嵌段共聚物(简称：FIBF-OH)；(2)以上述合成的PTHF

活性链与H

N-PIB-NH

链端胺基发生高效亲核取代反应，设计合成中间链段连接点含―NH―官能基团的PTHF-

-HN-PIB-NH-

-PTHF三嵌段共聚物(简称：FIBF-NH). 在上述三嵌段共聚物中，极性PTHF链段与非极性PIB链段的热力学不相容，导致其呈现明显的微相分离，且微观形态与共聚组成相关. PTHF均聚物易结晶，在上述共聚物中由于PTHF链段单端受限致其结晶性减弱. 三嵌段共聚物分子链的中间连接点含―NH―官能基团，具有更强的氢键作用，促进PTHF链段重排并结晶，易形成更紧密的超分子网络结构，导致即使在PTHF链段相对分子量为0.7 kg·mol

−1

时仍具有较强的结晶性，且结晶熔融温度明显提高. 此外，由于FIBF-NH中形成超分子网络结构，使材料具有优异的自修复性能，材料表面的切痕在常温下10 min 后可以完全自愈合. 本文设计合成的新型官能化PTHF-

-PIB-

-PTHF三嵌段共聚物兼具有PTHF与PIB的优良性能，在生物医用、智能修复等功能材料领域具有潜在的应用前景.

Abstract

The functionalized polyisobutylenes (PIBs) carrying allyl-Br or allyl-NH

with different molecular weights and narrow molecular weight distribution

could be successfully synthesized

via

controlled/living cationic polymerization of isobutylene (IB) in

-hexane/CH

mixed solvents at −80 °C. Controlled/Living cationic ring-opening polymerization (ROP) of tetrahydrofuran (THF) was achieved with Allyl-Br/AgClO

initiating system at 0 °C. Two kinds of novel functionalized PTHF-

-PIB-

-PTHF triblock copolymers were designed and synthesized

via

combination with controlled/living cationic polymerization of IB and controlled/living cationic ROP of THF. Terminal hydroxyl functionalized HO-PTHF-

-PIB-

-PTHF-OH triblock copolymers (expressed as FIBF-OH) were successfully synthesized by using the PIBs with difunctional allyl-Br terminal groups (Br-PIB-Br) as macroinitiators to initiate living cationic ROP of THF in the presence of AgClO

to create living PTHF

-PIB-

-PTHF

chains and then terminating by H

O molecules. On the other hand

PTHF-

-HN-PIB-NH-

-PTHF triblock copolymers containing hydrogen bonds at the connection point of PTHF and PIB segments (expressed as FIBF-NH) were also successfully synthesized

via

efficient nucleophilic substitution reaction between living PTHF

chains and amine groups in H

N-PIB-NH

. Due to the dynamic incompatibility between polar PTHF segments and nonpolar PIB segments and the crystallization of PTHF segments

PTHF-

-PIB-

-PTHF triblock copolymers exhibit an obvious microphase separation micromorphology. It is recognized that the chemical structure in the PTHF-

-PIB-

-PTHF triblock copolymers makes a great contribution to the formation of hydrogen bonding and thus the supramolecular network. The crystallization of PTHF segments could be improved even in FIBF-NH with relatively short PTHF segments

e.g.

PTHF

= 0.7 kg·mol

−1

. FIBF-NH could be completely self-healing at 25 °C for 10 min after cutting on its surface. However

the cutting on FIBF-OH surface was difficult to heal even at 30 °C for 3 days. Moreover

the PTHF-

-PIB-

-PTHF triblock copolymers could be used as drug carrier by interactions between PTHF segment and drug. The drug carrier microspheres exhibit pH-sensitive drug-release rate in PBS with different pH values. The novel functionalized PTHF-

-PIB-

-PTHF triblock copolymers combined the respective good properties from PIB and PTHF segments would have their potential applications as biomedical and smart-healing functional materials.

关键词

聚异丁烯聚四氢呋喃嵌段共聚物正离子聚合超分子网络

Keywords

PolyisobutylenePolytetrahydrofuranBlock copolymerLiving cationic polymerizationSupramolecular network

references

Campbell C G, Ummadisetty S, Storey R F. Macromolecules , 2016 . 49 7642 - 7652 . DOI:10.1021/acs.macromol.6b01754http://doi.org/10.1021/acs.macromol.6b01754 .

Wu Guanying(武冠英), Wu Yixian(吴一弦). Controlled Cationic Polymerization and its Application(控制阳离子聚合及其应用). Beijing(北京): Chemical Industry Press(化学工业出版社), 2005. 436

Kennedy J P, Macrechal E. Carbocationic polymerization. New York: John Wiley & Sons, 1982. 59

Faust R, Kennedy J P. Polym Bull , 1986 . 15 ( 4 ): 317 - 323.

Bahadur M, Shaffer T D, Ashbaugh J R. Macromolecules , 2000 . 33 ( 26 ): 9548 - 9552 . DOI:10.1021/ma000064uhttp://doi.org/10.1021/ma000064u .

Hadjikyriacou S, Acar M, Faust R. Macromolecules , 2004 . 37 ( 20 ): 7543 - 7547 . DOI:10.1021/ma049082shttp://doi.org/10.1021/ma049082s .

Qiu Y X, Wu Y X, Gu X L, Xu X, Wu G Y. Eur Polym J , 2005 . 41 349 - 358 . DOI:10.1016/j.eurpolymj.2004.10.003http://doi.org/10.1016/j.eurpolymj.2004.10.003 .

Xu X, Wu Y X, Qiu Y X, Dong C L, Wu G Y, Wang H. Eur Polym J , 2006 . 42 2791 - 2800 . DOI:10.1016/j.eurpolymj.2006.06.028http://doi.org/10.1016/j.eurpolymj.2006.06.028 .

Liu Xun(刘迅), Wu Yixian(吴一弦), Zhang Chenglong(张成龙), Zhang Bei(张蓓), Li Yan(李艳), Xu Xu(徐旭),Wu Guanying(武冠英). Acta Polymerica Sinica(高分子学报) , 2007 . ( 3 ): 255 - 261 . DOI:10.3321/j.issn:1000-3304.2007.03.009http://doi.org/10.3321/j.issn:1000-3304.2007.03.009 .

Li Y, Wu Y X, Xu X, Liang L H, Wu G Y. J Polym Sci, Part A: Polym Chem , 2007 . 45 ( 14 ): 3053 - 3061 . DOI:10.1002/pola.22061http://doi.org/10.1002/pola.22061 .

Qiu Yingxin(邱迎昕), Wu Yixian(吴一弦), Cui Yu(崔宇), Ye Xiaolin(叶晓林), Wu Guanying(武冠英). Acta Polymerica Sinica(高分子学报) , 2007 . ( 2 ): 190 - 197 . DOI:10.3321/j.issn:1000-3304.2007.02.017http://doi.org/10.3321/j.issn:1000-3304.2007.02.017 .

Zhang C L, Wu Y X, Xu X, Li Y, Feng L, Wu G Y. J Polym Sci, Part A: Polym Chem , 2008 . 46 936 - 946 . DOI:10.1002/pola.22437http://doi.org/10.1002/pola.22437 .

Lin Tao(林涛), Wu Yixian(吴一弦), Ye Xiaolin(叶晓林), Zhang Laibao(张来宝), Huang Qigu(黄启谷),Wu Guanying(武冠英). Acta Polymerica Sinica(高分子学报) , 2008 . ( 2 ): 129 - 135 . DOI:10.3321/j.issn:1000-3304.2008.02.006http://doi.org/10.3321/j.issn:1000-3304.2008.02.006 .

Liang Lihu(梁立虎), Wu Yixian(吴一弦), Li Yan(李艳), Xu Riwei(徐日炜), Yang Waitai(杨万泰), Wu Guanying(武冠英). Acta Polymerica Sinica(高分子学报) , 2008 . ( 12 ): 1166 - 1174 . DOI:10.3321/j.issn:1000-3304.2008.12.008http://doi.org/10.3321/j.issn:1000-3304.2008.12.008 .

Zhang C L, Wu Y X, Meng X Y, Huang Q, Wu G Y, Xu R W. Chinese J Polym Sci , 2009 . 27 ( 4 ): 551 - 559 . DOI:10.1142/S0256767909004230http://doi.org/10.1142/S0256767909004230 .

Zhang Bei(张蓓), Wu Yixian(吴一弦), Li Yan(李艳), Liu Xun(刘迅), Xu Xu(徐旭), Wu Guanying(武冠英). Acta Polymerica Sinica(高分子学报) , 2009 . ( 11 ): 1040 - 1046.

Li Y, Wu Y X, Liang L H, Li Y, Wu G Y. Chinese J Polym Sci , 2010 . 28 ( 1 ): 55 - 62 . DOI:10.1007/s10118-010-8216-9http://doi.org/10.1007/s10118-010-8216-9 .

Liu Q, Wu Y X, Zhang Y, Yan P F, Xu R W. Polymer , 2010 . 51 ( 25 ): 5960 - 5969 . DOI:10.1016/j.polymer.2010.10.012http://doi.org/10.1016/j.polymer.2010.10.012 .

Vasilenko I V, Frolov A N, Kostjuk S V. Macromolecules , 2010 . 43 ( 13 ): 5503 - 5507 . DOI:10.1021/ma1009275http://doi.org/10.1021/ma1009275 .

Zhang L B, Wu Y X, Zhou P, Wu G Y, Yang W T, Yu D S. Chinese J Polym Sci , 2011 . 29 ( 3 ): 360 - 367 . DOI:10.1007/s10118-011-1042-xhttp://doi.org/10.1007/s10118-011-1042-x .

Liu Q, Wu Y X, Yan P F, Zhang Y, Xu R W. Macromolecules , 2011 . 44 1866 - 1875 . DOI:10.1021/ma1027017http://doi.org/10.1021/ma1027017 .

Yan P F, Guo A R, Liu Q, Wu Y X. J Polym Sci, Part A: Polym Chem , 2012 . 50 3383 - 3392 . DOI:10.1002/pola.26126http://doi.org/10.1002/pola.26126 .

Zhang L B, Wu Y X, Zhou P, Xu R W. Polym Adv Technol , 2012 . 23 522 - 528 . DOI:10.1002/pat.1908http://doi.org/10.1002/pat.1908 .

Kumar R, Dimitrov P, Bartelson K J, Emert J, Faust R. Macromolecules , 2012 . 45 ( 21 ): 8598 - 8603 . DOI:10.1021/ma3017585http://doi.org/10.1021/ma3017585 .

Bartelson K J, De P, Kumar R, Emert J, Faust R. Polymer , 2013 . 54 ( 18 ): 4858 - 4863 . DOI:10.1016/j.polymer.2013.07.024http://doi.org/10.1016/j.polymer.2013.07.024 .

Guo A R, Yang X J, Yan P F, Wu Y X. J Polym Sci, Part A: Polym. Chem , 2013 . 51 4200 - 4212 . DOI:10.1002/pola.26834http://doi.org/10.1002/pola.26834 .

Kumar R, Zheng B, Huang, K W, Emert J, Faust R. Macromolecules , 2014 . 47 ( 6 ): 1959 - 1965 . DOI:10.1021/ma500042fhttp://doi.org/10.1021/ma500042f .

Yang X J, Guo A R, Xu H C, Wu Y X. J Appl Polym Sci , 2015 . 132 42232 - 42244.

Kostjuk S V, Vasilenko I V, Shiman D I, Frolov A N, Gaponik L V. Macromol Symp , 2015 . 349 ( 1 ): 94 - 103 . DOI:10.1002/masy.201400016http://doi.org/10.1002/masy.201400016 .

Vasilenko I V, Berezianko I A, Shiman D I, Shiman D I, Kostjuk S V. Polym Chem , 2016 . 7 ( 36 ): 5615 - 5619 . DOI:10.1039/C6PY01325Bhttp://doi.org/10.1039/C6PY01325B .

Wu Yixian(吴一弦), Zhou Qi(周琦), Du Jie(杜杰), Wang Nan(王楠). Acta Polymerica Sinica(高分子学报) , 2017 . ( 7 ): 1047 - 1057 . DOI:10.11777/j.issn1000-3304.2017.17045http://doi.org/10.11777/j.issn1000-3304.2017.17045 .

Yang S X, Fan Z Y, Zhang F Y, Li S H, Wu Y X. Chinese J Polym Sci , 2019 . 37 919 - 929 . DOI:10.1007/s10118-019-2329-6http://doi.org/10.1007/s10118-019-2329-6 .

De P, Faust R. Macromolecules , 2006 . 39 ( 22 ): 7527 - 7533 . DOI:10.1021/ma061463dhttp://doi.org/10.1021/ma061463d .

Ojha U, Rajkhowa R, Agnihotra S R, Faust R. Macromolecules , 2008 . 41 ( 11 ): 3832 - 3841 . DOI:10.1021/ma7027209http://doi.org/10.1021/ma7027209 .

Deodhar T J, Keszler B L, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2017 . 55 ( 10 ): 1784 - 1789 . DOI:10.1002/pola.28529http://doi.org/10.1002/pola.28529 .

Nugay T, Deodhar T, Nugay N, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2018 . 56 ( 11 ): 1140 - 1145 . DOI:10.1002/pola.28993http://doi.org/10.1002/pola.28993 .

Sipos L, Som A, Rudolf Faust R. Biomacromolecules , 2005 . 6 2570 - 2582 . DOI:10.1021/bm050299jhttp://doi.org/10.1021/bm050299j .

Bouchekif H, Som A, Sipos L, Faust R. J Macromol Sci, Part A: Pure Appl Chem , 2007 . 44 359 - 366 . DOI:10.1080/10601320601187986http://doi.org/10.1080/10601320601187986 .

Kleinedler J J, Foley J D, Alexander J S, Roerig S C, Hebert V Y, Dugas T R. J Biomed Mater Res B , 2011 . 99B ( 2 ): 266 - 275 . DOI:10.1002/jbm.b.31894http://doi.org/10.1002/jbm.b.31894 .

McDermott M K, Kim C S, Saylor D M, Patwardhan D V. J Biomed Mater Res B , 2013 . 101 1191 - 1199 . DOI:10.1002/jbm.b.32930http://doi.org/10.1002/jbm.b.32930 .

Fittipaldi M, Rodriguez L A, Damley-Strnad A, Grace L R. Mater Des , 2015 . 86 6 - 13 . DOI:10.1016/j.matdes.2015.07.070http://doi.org/10.1016/j.matdes.2015.07.070 .

Toth K, Nugay N, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2016 . 54 ( 15 ): 2361 - 2369 . DOI:10.1002/pola.28109http://doi.org/10.1002/pola.28109 .

Moralesa B, Kaskarb O, Grace L R. Mater Today Commun , 2018 . 17 278 - 288 . DOI:10.1016/j.mtcomm.2018.09.019http://doi.org/10.1016/j.mtcomm.2018.09.019 .

Wu Y B, Li K, Xiang D, Zhang M, Yang D, Zhang J H, Mao J, Wang H, Guo W L. Appl Surf Sci , 2018 . 445 8 - 15 . DOI:10.1016/j.apsusc.2018.03.048http://doi.org/10.1016/j.apsusc.2018.03.048 .

James G K, Robson F S, William L J, Kenneth A M. Polymer , 2008 . 49 5045 - 5052 . DOI:10.1016/j.polymer.2008.08.045http://doi.org/10.1016/j.polymer.2008.08.045 .

Bonduelle C V, Karamdoust S, Gillies E R. Macromolecules , 2011 . 44 6405 - 6415 . DOI:10.1021/ma2009996http://doi.org/10.1021/ma2009996 .

Li S, He J L, Zhang M Z, Wang H R, Ni P H. Polym Chem , 2016 . 7 1773 - 1781 . DOI:10.1039/C5PY02017Dhttp://doi.org/10.1039/C5PY02017D .

Malins E L, Waterson C, Becer C R. RSC Adv , 2016 . 6 71773 - 71780 . DOI:10.1039/C6RA15346Ahttp://doi.org/10.1039/C6RA15346A .

Castano M, Alvarez1 A, Becker M L, Puskas J E. Express Polym Lett , 2016 . 10 ( 8 ): 693 - 700 . DOI:10.3144/expresspolymlett.2016.62http://doi.org/10.3144/expresspolymlett.2016.62 .

Zhang H F, Banerjee S, Faust R, Hadjichristidis N. Polym Chem , 2016 . 7 1217 - 1220 . DOI:10.1039/C5PY01892Ghttp://doi.org/10.1039/C5PY01892G .

Askes S H C, Pomp W, Hopkins S L, Kros A, Wu S, Schmidt T, Bonnet S. Small , 2016 . 12 ( 40 ): 5579 - 5590 . DOI:10.1002/smll.201601708http://doi.org/10.1002/smll.201601708 .

Askes S H C, Bossert N, Bussmann J, Talens V S, Meijer M S, Kieltyka R E, Kros A, Bonnet S, Heinrich D. Biomaterials , 2018 . 168 54 - 63 . DOI:10.1016/j.biomaterials.2018.03.037http://doi.org/10.1016/j.biomaterials.2018.03.037 .

Campbell C G, Storey R F. Macromolecules , 2018 . 51 6430 - 6439 . DOI:10.1021/acs.macromol.8b01258http://doi.org/10.1021/acs.macromol.8b01258 .

Fu Y H, Madrahimov S T, Bergbreiter D E. J Polym Sci, Part A: Polym Chem , 2018 . 56 1860 - 1867 . DOI:10.1002/pola.29069http://doi.org/10.1002/pola.29069 .

Kerscher B, Trötschler T M, Pásztói B, Gröer S, Szabó A, Iván B, Mülhaupt R. Macromolecules , 2019 . 52 3306 - 3318 . DOI:10.1021/acs.macromol.9b00296http://doi.org/10.1021/acs.macromol.9b00296 .

Yang B, Abel B A, McCormick C L, Storey R F. Macromolecules , 2017 . 50 7458 - 7467 . DOI:10.1021/acs.macromol.7b01655http://doi.org/10.1021/acs.macromol.7b01655 .

Du Y Q, Li C M, Jin J, Li C, Jiang W. Colloids Surf B , 2018 . 161 73 - 82 . DOI:10.1016/j.colsurfb.2017.10.035http://doi.org/10.1016/j.colsurfb.2017.10.035 .

Wei Mengjuan(魏梦娟), Guo Anru(郭安儒), Wu Yixian(吴一弦). Acta Polymerica Sinica(高分子学报) , 2017 . ( 3 ): 118 - 127.

Wei Mengjuan(魏梦娟), Zhang Qi(章琦), Zhang Hangtian(张航天), Wu Yixian(吴一弦). Acta Polymerica Sinica(高分子学报) , 2018 . ( 4 ): 464 - 474 . DOI:10.11777/j.issn1000-3304.2017.17130http://doi.org/10.11777/j.issn1000-3304.2017.17130 .

Gao Y Z, Chang T X, Wu Y X. Carbohyd Polym , 2019 . 219 201 - 209 . DOI:10.1016/j.carbpol.2019.04.087http://doi.org/10.1016/j.carbpol.2019.04.087 .

Theiler S, Diamantouros S E, Jockenhoevel S, Keul H, Moeller M. Polym Chem , 2011 . 2 ( 10 ): 2273 - 2283 . DOI:10.1039/c1py00262ghttp://doi.org/10.1039/c1py00262g .

Guo A R, Yang W X, Yang F, Yu R, Wu Y X. Macromolecules , 2014 . 47 ( 16 ): 5450 - 5461 . DOI:10.1021/ma501060yhttp://doi.org/10.1021/ma501060y .

Jikei M, Aikawa Y, Matsumoto K. High Perform Polym , 2016 . 28 ( 9 ): 1015 - 1023 . DOI:10.1177/0954008315613423http://doi.org/10.1177/0954008315613423 .

Meyer W, Engelhardt S, Novosel E, Elling B, Wegener M, Krüger H. J Funct Biomater , 2012 . 3 ( 2 ): 257 - 268 . DOI:10.3390/jfb3020257http://doi.org/10.3390/jfb3020257 .

Cheng Liang(程亮), Li Jianda(李健达), Ma Jun(马骏), Su Junping(苏军平), Wei Shifeng(卫世锋), Liu Xu(刘旭). Guangzhou Chemical Industry(广州化工) , 2018 . 46 ( 19 ): 114 - 115.

Hourston D J, Williams G D, Satguru R, Padget J C, Pears D. J Appl Polym Sci , 1999 . 74 556 - 566 . DOI:10.1002/(SICI)1097-4628(19991017)74:3<556::AID-APP10>3.0.CO;2-Dhttp://doi.org/10.1002/(SICI)1097-4628(19991017)74:3<556::AID-APP10>3.0.CO;2-D .

Rasolonjatovo B, Gomez J P, William M, Gonçalves C, Huin C, Bennevault-Celton V, Gall T L, Montier T, Lehn P, Cheradame H, Midoux P, Guégan P. Biomacromolecules , 2015 . 16 748 - 756 . DOI:10.1021/bm5016656http://doi.org/10.1021/bm5016656 .

Zhang Qi(章琦), Wei Mengjuan(魏梦娟), Deng Jinrui(邓金睿), Wu Yixian(吴一弦). Acta Polymerica Sinica(高分子学报) , 2018 . ( 9 ): 70 - 79.

Almeida A D, Nébouy M, Baeza G P. Macromolecules , 2019 . 52 ( 3 ): 1227 - 1240 . DOI:10.1021/acs.macromol.8b01689http://doi.org/10.1021/acs.macromol.8b01689 .

Jewrajka S K, Yilgor E, Yilgor I, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2009 . 47 ( 1 ): 38 - 48 . DOI:10.1002/pola.23118http://doi.org/10.1002/pola.23118 .

Jewrajka S K, Kang J, Erdodi G, Kennedy J P, Yilgor E, Yilgor I. J Polym Sci, Part A: Polym Chem , 2009 . 47 ( 11 ): 2787 - 2797 . DOI:10.1002/pola.23361http://doi.org/10.1002/pola.23361 .

Erdodi G, Kang J, Kennedy J P, Yilgor E, Yilgor I. J Polym Sci, Part A: Polym Chem , 2009 . 47 ( 20 ): 5278 - 5290 . DOI:10.1002/pola.23577http://doi.org/10.1002/pola.23577 .

Kang J, Erdodi G, Kennedy J P, Yilgor E, Yilgor I. J Polym Sci, Part A: Polym Chem , 2009 . 47 ( 22 ): 6180 - 6190 . DOI:10.1002/pola.23661http://doi.org/10.1002/pola.23661 .

Ojha U, Kulkarni P, Faust R. Polymer , 2009 . 50 ( 15 ): 3448 - 3457 . DOI:10.1016/j.polymer.2009.05.025http://doi.org/10.1016/j.polymer.2009.05.025 .

Erdodi G, Kang J, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2010 . 48 ( 11 ): 2361 - 2371 . DOI:10.1002/pola.24003http://doi.org/10.1002/pola.24003 .

Cozzens D, Ojha U, KulkarniP, Faust R, Desai S. J Biomed Mater Res A , 2010 . 95 ( 3 ): 774 - 782 . DOI:10.1002/jbm.a.32897http://doi.org/10.1002/jbm.a.32897 .

Ojha U, Faust R. J Biomed Mater Res A , 2010 . 47 ( 3 ): 186 - 191.

Cozzens D, Ojha U, Kulkarni P, Faust R, Desai S. Abstr Papers Am Chem Soc , 2010 . 51 ( 2 ): 31 - 32.

Kang J, Erdodi G, Brendel C M, Ely D, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2010 . 48 ( 10 ): 2194 - 2203 . DOI:10.1002/pola.23989http://doi.org/10.1002/pola.23989 .

Cozzens D, Luk A, Ojha U, Ruths M, Faust R. Langmuir , 2011 . 27 ( 23 ): 14160 - 14168 . DOI:10.1021/la202586jhttp://doi.org/10.1021/la202586j .

Wei X Y, Bagdi K, Ren L, Shah P, Seethamraju K, Faust R. Polymer , 2013 . 54 ( 6 ): 1647 - 1655 . DOI:10.1016/j.polymer.2013.01.029http://doi.org/10.1016/j.polymer.2013.01.029 .

Kulkarni P, Ojha U, Wei X Y, Gurung N, Seethamraju K, Faust R. J Appl Polym Sci , 2013 . 130 ( 2 ): 891 - 897 . DOI:10.1002/app.39236http://doi.org/10.1002/app.39236 .

Wei X Y, Shah P N, Bagdi K, Seethamraju K, Faust R. J Macromol Sci Part A: Pure Appl Chem , 2014 . 51 ( 1 ): 6 - 15 . DOI:10.1080/10601325.2014.850617http://doi.org/10.1080/10601325.2014.850617 .

Kang J, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2015 . 53 ( 1 ): 1 - 4 . DOI:10.1002/pola.27447http://doi.org/10.1002/pola.27447 .

Mishra A, Seethamraju K, Delaney J, Willoughby P, Faust R. J Biomed Mater Res A , 2015 . 103 ( 12 ): 3798 - 3806 . DOI:10.1002/jbm.a.35523http://doi.org/10.1002/jbm.a.35523 .

Banerjee S, Shah P N, Jeong Y, Chang T, Seethamraju K, Faust R. J Chromatogr A , 2015 . 1376 98 - 104 . DOI:10.1016/j.chroma.2014.12.022http://doi.org/10.1016/j.chroma.2014.12.022 .

Nugay N, Toth K, Kekec N C, Nugay T, Kennedy J P. J Polym Sci, Part A: Polym Chem , 2016 . 54 ( 17 ): 2760 - 2765 . DOI:10.1002/pola.28158http://doi.org/10.1002/pola.28158 .

Storey R F, Chisholm B J, Brister L B. Macromolecules , 1995 . 28 ( 12 ): 4055 - 4061 . DOI:10.1021/ma00116a002http://doi.org/10.1021/ma00116a002 .

Feldman K E, Kade M J, Meijer E W, Hawker C J, Kramer E J. Macromolecules , 2011 . 42 9072 - 9081.

Liu Xiao(刘晓), Li Shengran(李晟冉), Wu Yixian(吴一弦). Acta Polymerica Sinica(高分子学报) , 2017 . ( 11 ): 84 - 92.

Chang Tianxiao(常添笑), Zhang Hangtian(张航天), Lu Congjie(卢聪杰), Wu Yixian(吴一弦). Acta Polymerica Sinica(高分子学报) , 2018 . ( 6 ): 700 - 711 . DOI:10.11777/j.issn1000-3304.2017.17290http://doi.org/10.11777/j.issn1000-3304.2017.17290 .

Gao Y Z, Chang T X, Wu Y X. Appl Surf Sci , 2019 . 483 1027 - 1036 . DOI:10.1016/j.apsusc.2019.03.103http://doi.org/10.1016/j.apsusc.2019.03.103 .

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