高性能双极性聚合物半导体材料与晶体管器件

郭云龙

doi:10.11777/j.issn1000-3304.2020.19221

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高性能双极性聚合物半导体材料与晶体管器件

专论 | 更新时间：2021-01-26

- 高性能双极性聚合物半导体材料与晶体管器件
- High Performance Ambipolar Polymer Semiconductors and Transistors
- 高分子学报 2020年51卷第5期页码：448-456
- 作者机构：
  
  中国科学院化学研究所北京分子科学国家研究中心　北京 100190
- 作者简介：
  
  [ "郭云龙，男，1982年生. 2005年本科毕业于河北师范大学化学学院，2010年博士毕业于中国科学院化学研究所，2010 ~ 2013年历任中国科学院化学研究所助理研究员和副研究员，2013 ~ 2016年日本东京大学博士后，2016年日本东京大学特任副教授，2016年至今中国科学院化学研究所研究员，博士生导师. 2019年获得国家自然基金委优秀青年基金资助，主要研究方向为有机聚合物半导体分子与晶体管器件；有机-无机杂化材料分子与光电器件" ]
- 基金信息：
  
  国家自然科学基金(基金号 21922511，51873216，61890943，91833306)和国家重点研发计划(项目号 2018YFA0703202)资助项目
- DOI：10.11777/j.issn1000-3304.2020.19221
  中图分类号：
- 纸质出版日期：2020-5，
  
  网络出版日期：2020-4-2，
  
  收稿日期：2019-12-26，
  
  修回日期：2020-2-8，
扫描看全文
郭云龙. 高性能双极性聚合物半导体材料与晶体管器件[J]. 高分子学报, 2020,51(5):448-456.

Yun-long Guo. High Performance Ambipolar Polymer Semiconductors and Transistors[J]. Acta Polymerica Sinica, 2020,51(5):448-456.
郭云龙. 高性能双极性聚合物半导体材料与晶体管器件[J]. 高分子学报, 2020,51(5):448-456. DOI： 10.11777/j.issn1000-3304.2020.19221.

Yun-long Guo. High Performance Ambipolar Polymer Semiconductors and Transistors[J]. Acta Polymerica Sinica, 2020,51(5):448-456. DOI： 10.11777/j.issn1000-3304.2020.19221.

摘要

有机聚合物半导体材料与晶体管器件是融合了化学、材料、半导体以及微电子等学科的前沿交叉研究方向. 聚合物半导体材料分子是该领域研究的重要内容，其中双极性聚合物分子半导体材料，兼具了电子和空穴的双重载流子输运能力而受到学术界的广泛关注. 本文总结了双极性聚合物半导体材料与器件的研究进展，重点介绍了我们在D-A型双极性聚合物分子半导体材料设计、加工技术与器件制备以及功能应用方面的研究工作，并论述了双极性聚合物分子半导体材料与器件研究过程中存在的科学问题及发展方向.

Abstract

Organic polymer semiconductors and field-effect transistors (OFET) are the frontier interdisciplinary research directions of chemistry

materials

semiconductors and microelectronics. Polymer semiconductors are the important research contents in this field

among which ambipolar semiconducting polymer materials

which have the double carrier transport ability

have received extensive attention in the academic field. This unique property gives ambipolar semiconducting polymers many applications

such as low-cost logic circuit

organic light-emitting transistors (OLETs)

low-energy cost memory device

and near infrared detectors. In this feature article

the research progress of ambipolar polymer semiconductors and transistors is summarized. First

we give brief introduction of the configuration of OFETs and its related parameters. And then

our research work in designing new ambipolar polymers based on bis-acceptors or enhancing acceptor ability with withdraw group are introduced. In fact

except designing of polymer structures

solution-process methods are also very important for low-cost and large-area organic devices. Therefore

different solution-processing technologies

such as spin-coating

sheer-coating

bar-coating

inkjet printing

screen printing

and slot-die

are discussed for achieving high performance OFETs. Further

functional application of D-A ambipolar polymer semiconductors in inverter circuit

OLETs

and memory devices are mainly described in this paper. Finally

the scientific problems and development direction in the research process of ambipolar polymer semiconductors and devices are also discussed.

关键词

高性能双极性聚合物半导体材料晶体管器件

Keywords

High performanceAmbipolarPolymer semiconductorsTransistors

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