介电高分子及其纳米复合材料的电容储能应用

成桑; 李雨抒; 梁家杰; 李琦

doi:10.11777/j.issn1000-3304.2020.20001

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介电高分子及其纳米复合材料的电容储能应用

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- 介电高分子及其纳米复合材料的电容储能应用
- Polymer Dielectrics and Their Nanocomposites for Capacitive Energy Storage Applications
- 高分子学报 2020年51卷第5期页码：469-483
- 作者机构：
  
  清华大学电机工程与应用电子技术系电力系统国家重点实验室　北京 100084
- 作者简介：
  
  [ "李琦，男，1984年生. 清华大学电机系副教授，博士生导师. 2007年获武汉理工大学高分子材料与工程专业学士学位. 2010年、2013年分别获武汉理工大学材料学硕士、博士学位. 2013 ~ 2016年在美国宾夕法尼亚州立大学材料科学与工程系从事博士后研究. 2016年12月至今在清华大学电机系工作. 曾获美国材料学会优秀博士后奖(2016)、国际电气和电子工程师协会孙才新-斯坦·格博斯基青年学者成就奖(2018). 入选第十四批青年千人计划. 2019年获国家基金委优秀青年科学基金. 主要在介电高分子纳米复合材料及其储能和能量转换等领域开展关键基础及应用技术研究" ]
- 基金信息：
  
  国家自然科学基金(基金号 51777101, 51922056)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20001
  中图分类号：
- 纸质出版日期：2020-5，
  
  网络出版日期：2020-3-25，
  
  收稿日期：2020-1-20，
  
  修回日期：2020-1-30，
扫描看全文
成桑, 李雨抒, 梁家杰, 李琦. 介电高分子及其纳米复合材料的电容储能应用[J]. 高分子学报, 2020,51(5):469-483.

Sang Cheng, Yu-shu Li, Jia-jie Liang, Qi Li. Polymer Dielectrics and Their Nanocomposites for Capacitive Energy Storage Applications[J]. Acta Polymerica Sinica, 2020,51(5):469-483.
成桑, 李雨抒, 梁家杰, 李琦. 介电高分子及其纳米复合材料的电容储能应用[J]. 高分子学报, 2020,51(5):469-483. DOI： 10.11777/j.issn1000-3304.2020.20001.

Sang Cheng, Yu-shu Li, Jia-jie Liang, Qi Li. Polymer Dielectrics and Their Nanocomposites for Capacitive Energy Storage Applications[J]. Acta Polymerica Sinica, 2020,51(5):469-483. DOI： 10.11777/j.issn1000-3304.2020.20001.

摘要

静电电容器具有极快的放电速率和超高的功率密度，是先进电力与电子系统中的重要储能元件. 介电高分子凭借其高击穿、可自愈、低损耗、低成本等优势成为了广泛使用的电容器电介质材料. 然而，介电高分子能量密度偏低、热稳定性较差等问题制约了它们在大功率电力电子和紧凑型功率模块中的应用. 为了提高介电高分子的能量密度和满足其在高温环境下的应用需求，我们开展了一系列研究. 本文着重介绍了我们近年来在开发高性能聚合物基电介质材料及相关介电现象理论研究方面的进展. 主要内容涵盖基于聚偏氟乙烯的铁电聚合物、共聚物、纳米复合材料，以及聚合物基高温介电材料的制备与表征，还包括介电纳米复合材料界面微区特性的研究. 最后对介电高分子在电容储能应用领域仍存在的问题进行了总结，并展望了未来可能的研究方向.

Abstract

Electrostatic capacitors with extremely fast discharge speed and ultra-high power density

are an important class of energy storage element in advanced electrical and electronic systems. Polymer dielectrics are widely employed as capacitor dielectric materials because of their high breakdown strength

the ability to self-heal

low loss and low cost. However

polymer dielectrics usually show low energy density and poor thermal stability

which restrict their applications in high power electronics and compact power modules. In order to improve the energy density and temperature capability of polymer dielectrics

we have carried out a series of study. This review focuses on our recent progress in developing high-performance polymer-based dielectric materials and in understanding the corresponding dielectric phenomena. The main content includes the synthesis and characterization of PVDF-based ferroelectric polymers

copolymers and nanocomposites

and polymer-based high temperature dielectrics

as well as the investigation of interfacial property in the polymer matrix/inorganic nanoparticle composite system. At the end of this review

we summarize the existing challenges and propose the future directions in the field of polymer-based capacitor dielectrics.

关键词

介电高分子纳米复合材料储能密度界面

Keywords

Polymer dielectricsNanocompositesEnergy storage densityInterface

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