植物细胞壁纳米结构与纳米纤维素的化学纯化处理结合机械解纤法制备

王梦竹; 方颖; 李勍; 白璐璐; 于海鹏; 刘守新; 李坚; 陈文帅

doi:10.11777/j.issn1000-3304.2020.20037

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植物细胞壁纳米结构与纳米纤维素的化学纯化处理结合机械解纤法制备

专论 | 更新时间：2021-01-26

- 植物细胞壁纳米结构与纳米纤维素的化学纯化处理结合机械解纤法制备
- Nanostructures of Plant Cell Walls and Individualization Methodology of Nanofibrillated Cellulose
- 高分子学报 2020年51卷第6期页码：586-597
- 作者机构：
  
  东北林业大学生物质材料科学与技术教育部重点实验室　哈尔滨 150040
- 作者简介：
  
  [ "陈文帅，男，1987年生，博士，教授，博士生导师. 国家自然科学基金优秀青年科学基金项目获得者. 2008年、2013年分别于东北林业大学木材科学与技术学科获得学士、博士学位(硕博连读). 主要从事木材物理学研究，研究工作专注于木材基纳米材料的机械法制备、自聚集组装及其衍生材料在环境、能源等相关领域的应用" ]
- 基金信息：
  
  国家自然科学基金(基金号31922056，31770594，31800487)、黑龙江省自然科学基金面上项目(基金号 C2017006)和霍英东教育基金会高等院校青年教师基金(基金号 161025)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20037
  中图分类号：
- 纸质出版日期：2020-6，
  
  网络出版日期：2020-5-28，
  
  收稿日期：2020-2-17，
  
  修回日期：2020-4-1，
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王梦竹, 方颖, 李勍, 白璐璐, 于海鹏, 刘守新, 李坚, 陈文帅. 植物细胞壁纳米结构与纳米纤维素的化学纯化处理结合机械解纤法制备[J]. 高分子学报, 2020,51(6):586-597.

Meng-zhu Wang, Ying Fang, Qing Li, Lu-lu Bai, Hai-peng Yu, Shou-xin Liu, Jian Li, Wen-shuai Chen. Nanostructures of Plant Cell Walls and Individualization Methodology of Nanofibrillated Cellulose[J]. Acta Polymerica Sinica, 2020,51(6):586-597.
王梦竹, 方颖, 李勍, 白璐璐, 于海鹏, 刘守新, 李坚, 陈文帅. 植物细胞壁纳米结构与纳米纤维素的化学纯化处理结合机械解纤法制备[J]. 高分子学报, 2020,51(6):586-597. DOI： 10.11777/j.issn1000-3304.2020.20037.

Meng-zhu Wang, Ying Fang, Qing Li, Lu-lu Bai, Hai-peng Yu, Shou-xin Liu, Jian Li, Wen-shuai Chen. Nanostructures of Plant Cell Walls and Individualization Methodology of Nanofibrillated Cellulose[J]. Acta Polymerica Sinica, 2020,51(6):586-597. DOI： 10.11777/j.issn1000-3304.2020.20037.

摘要

植物中含有自然界中储量最为丰富的天然高分子—纤维素. 植物具有多层级结构，在微观层面由细胞构成. 细胞的主体物质存在于细胞壁中，主要以纤维素纳米纤丝—基体复合结构形式存在，这种结构对植物的性能和功能起到了至关重要的作用. 采用化学纯化处理结合机械解纤策略，可以将细胞壁内部起支撑作用的纳米纤维素解离出来. 纳米纤维素展现出一维纳米纤维结构、高结晶度以及优异的力学性能和热性能，在许多领域均展现出巨大的应用潜力. 本文主要介绍我们课题组近几年对植物多层级结构、细胞特征、细胞壁生物合成以及细胞壁纳米结构的研究和思考，总结了在植物纳米纤维素化学纯化处理结合机械解纤法制备方面的研究进展，并对其存在的问题以及今后重点研究方向进行了总结和展望.

Abstract

Cellulose

the most abundant and sustainable natural polymer material in nature

is mainly contained in plants. The structures of plants are quite complex and all the plants exhibit multiple hierarchical structures. In micro-scale

plants are organized by various types of cells. The main matters of the cells exist at cell walls. For most plants

composite structures with cellulose nanofibrils and matrix such as hemicellulose and lignin were formed during the cell synthesis and growth

which play a critical role on the performance and function of plants. Nanofibrils in the plant cell walls can be individualized through chemical purification combined with nanofibrillation strategy. The as-extracted nanofibrillated cellulose exhibits one-dimensional nanofiber structure

high relative crystallinity

and excellent mechanical and thermal properties. Nanofibrillated cellulose is recognized as a promising novel polymer nanomaterial

which has been widely exploited for applications in catalysis

adsorbents

elastic conductors

optoelectronic devices

energy storage

conversion and harvest

as well as desalination. Herein

the recent progress of our group is introduced

with specific focuses on the multiple hierarchical structures of plants

cells

the biosynthesis of cell walls

nanostructures of cell walls

and the research advances of the isolation of nanofibrillated cellulose by chemical purification treatment combined with mechanical nanofibrillation strategy. The nanofibrilaltion of the cellulose pulps using a high-intensity ultrasonicator

high-speed blender and high-pressure homogenizer is discussed in detail. The main challenges and future research directions are summarized and prospected.

关键词

植物细胞壁纳米结构纳米纤维素机械解纤法

Keywords

PlantCell wallNanostructureNanocelluloseNanofibrillation

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