基于聚合物复合物的自修复与可修复聚合物材料

李懿轩; 孙俊奇

doi:10.11777/j.issn1000-3304.2020.20062

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基于聚合物复合物的自修复与可修复聚合物材料

专论 | 更新时间：2021-01-26

- 基于聚合物复合物的自修复与可修复聚合物材料
- Self-healing and Healable Polymeric Materials Based on Polymer Complexes
- 高分子学报 2020年51卷第8期页码：791-803
- 作者机构：
  
  超分子结构与材料国家重点实验室吉林大学化学学院　长春 130012
- 作者简介：
  
  [ "孙俊奇，1975年生，现任吉林大学超分子结构与材料国家重点实验室、化学学院教授. 分别于1996和2001年在吉林大学获得工学学士和理学博士学位，2002年1月 ~ 2003年8月在日本理化学研究所从事博士后研究，2003年9月受聘吉林大学教授，2010年受聘吉林大学“唐敖庆特聘教授”. 于2003年获得全国优秀博士论文，获得2007年度中国化学会青年化学奖和第十届中国化学会-巴斯夫公司青年知识创新奖(2019年). 现在担任Langmuir杂志副主编. 主要从事功能性聚合物膜、自/可修复和循环利用聚合物材料方面的研究" ]
- 基金信息：
  
  国家自然科学基金(基金号 21935004)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20062
  中图分类号：
- 纸质出版日期：2020-8，
  
  网络出版日期：2020-7-8，
  
  收稿日期：2020-3-10，
  
  修回日期：2020-5-7，
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李懿轩, 孙俊奇. 基于聚合物复合物的自修复与可修复聚合物材料[J]. 高分子学报, 2020,51(8):791-803.

Yi-xuan Li, Jun-qi Sun. Self-healing and Healable Polymeric Materials Based on Polymer Complexes[J]. Acta Polymerica Sinica, 2020,51(8):791-803.
李懿轩, 孙俊奇. 基于聚合物复合物的自修复与可修复聚合物材料[J]. 高分子学报, 2020,51(8):791-803. DOI： 10.11777/j.issn1000-3304.2020.20062.

Yi-xuan Li, Jun-qi Sun. Self-healing and Healable Polymeric Materials Based on Polymer Complexes[J]. Acta Polymerica Sinica, 2020,51(8):791-803. DOI： 10.11777/j.issn1000-3304.2020.20062.

摘要

聚合物材料在使用过程中受到损伤，就会丧失原有的力学强度和功能. 修复功能能够延长聚合物材料的使用寿命、减少原料浪费并提高材料性能的可靠性. 赋予聚合物材料修复性能是可持续发展社会对聚合物材料设计的重要需求. 本文系统地介绍了本研究组发展的基于溶液中复合的聚合物复合物构筑自/可修复聚合物材料的方法，以及基于高密度的超分子可逆作用力及聚合物复合原位生成的纳米粒子的协同，解决聚合物复合材料的良好修复性能与高力学强度之间矛盾的策略. 基于聚合物复合的方法，我们成功制备了聚合物凝胶、弹性体及高强度聚合物复合材料，并实现了上述修复材料在防雾、质子传导和传感等方面的功能. 聚合物复合的方法为制备具有优异力学性能和功能的自/可修复聚合物材料提供了新思路.

Abstract

When polymer materials are damaged during usage

they will lose their original mechanical strength and function. Polymer materials with healability can have an extended service life

reduce raw material consumption and improve reliability. Endowing polymer materials with self-healing/healable capacity is an important requirement for the development of sustainable society. Polymeric complexes can be produced by directly mixing polymers with complementary interactions or copolymerization/sequential homopolymerization of two kinds of monomers with complementary interactions in bulk solutions. Polymer complexation provides a flexible method for the fabrication of polymer composite materials crosslinked by noncovalent supramolecular interactions or dynamic covalent bonds. Meanwhile

the mechanical properties of the polymeric composite materials derived from polymeric complexes can be conveniently tailored. This paper gives a comprehensive summary of the solution-based polymeric complexation method for the fabrication of self-healing/healable polymer materials developed in our research group. Based on the polymeric complexation method

we have successfully fabricated polymeric hydrogels

elastomers and high-strength polymer composites with excellent healing capacity. We also demonstrate that the contradiction between the satisfactory healability and high mechanical strength of polymer composites can be solved by integrating a high density of reversible supramolecular interactions and

in situ

-formed rigid polymeric complex nanoparticles in the targeted polymer composites. The polymeric complex nanoparticles can serve as nanofillers and cross-linkers to significantly improve the mechanical strength of the polymer composites. Meanwhile

the reversibility of supramolecular interactions facilitates the mobility of polymer chains and enables highly efficient healing of damaged composites to restore their original mechanical properties. Moreover

we also fabricated self-healing/healable polymer composite materials with functions such as antifogging

proton conduction and sensing. These polymer composite materials can heal mechanical damage as well as restore their original functions. We believe that the polymeric complexation method provides new avenue for the fabrication of self-healing/healable polymer materials with excellent mechanical properties and functions.

关键词

聚合物复合物超分子化学自修复材料非共价键作用力超分子材料

Keywords

Polymer complexesSupramolecular chemistrySelf-healing materialsNon-covalent bondsSupramolecular materials

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