基于天然高分子的导电材料制备及其在柔性传感器件中的应用

董点点; 张静雯; 唐杰; 王军; 杨宽; 马忠雷; 张文博; 陈咏梅; 马建中

doi:10.11777/j.issn1000-3304.2020.20114

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基于天然高分子的导电材料制备及其在柔性传感器件中的应用

综述 | 更新时间：2021-01-26

- 基于天然高分子的导电材料制备及其在柔性传感器件中的应用
- Fabrication of Conductive Materials Based on Natural Polymers and Their Application in Flexible Sensors
- 高分子学报 2020年51卷第8期页码：864-879
- 作者机构：
  
  1.陕西科技大学轻工科学与工程学院
  2. 化学与化工学院
  3.Shaanxi University of Science & Technology, Xi’an 710021 Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry & Technology
- 作者简介：
  
  [ "陈咏梅，女，1968年生. 陕西科技大学特聘教授，博士生导师. 2004年于日本北海道大学生物科学专业获博士学位. 2008年9月 ~ 2018年12月为西安交通大学教授. 2017年入选英国皇家化学会综合化学领域Top1%高被引中国作者榜单. 2020年以第一完成人获陕西高等学校科学技术奖一等奖1项. 主要从事新型功能高分子材料的基础研究以及在生物材料和柔性器件等方向的应用研究" ]
  [ "马建中，男，1960年生. 陕西科技大学二级教授，博士生导师. 1998年于浙江大学高分子化学与物理专业获得博士学位. 2017年8月任陕西科技大学校长、党委副书记，兼任中国皮革协会技术委员会名誉主任、国务院学位委员会轻工技术与工程学科评议组召集人. 以第一完成人获国家技术发明二等奖1项；国家科技进步二等奖1项；国家级教学成果奖二等奖1项；省部级科技一等奖4项；陕西省教学成果特等奖1项；何梁何利基金产业创新奖1项. 主要从事水性高分子的设计与合成、有机/无机纳米复合材料的关键技术、轻纺化学产品的技术与应用等方向的研究" ]
- 基金信息：
  
  国家自然科学基金(项目号 11674263)、陕西省重点研发计划国际科技合作计划项目(项目号 2020KWZ-006)、西安市未央区科技计划(项目号 201927)、军队后勤开放科研项目(项目号 BLB18J014)和国家重点研发计划“政府间国际科技创新合作/港澳台科技创新合作”重点专项项目(项目号 2018YFE0114200)资助
- DOI：10.11777/j.issn1000-3304.2020.20114
  中图分类号：
- 纸质出版日期：2020-8，
  
  网络出版日期：2020-7-22，
  
  收稿日期：2020-5-6，
  
  修回日期：2020-5-31，
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董点点, 张静雯, 唐杰, 王军, 杨宽, 马忠雷, 张文博, 陈咏梅, 马建中. 基于天然高分子的导电材料制备及其在柔性传感器件中的应用[J]. 高分子学报, 2020,51(8):864-879.

Dian-dian Dong, Jing-wen Zhang, Jie Tang, Jun Wang, Kuan Yang, Zhong-lei Ma, Wen-bo Zhang, Yong-mei Chen, Jian-zhong Ma. Fabrication of Conductive Materials Based on Natural Polymers and Their Application in Flexible Sensors[J]. Acta Polymerica Sinica, 2020,51(8):864-879.
董点点, 张静雯, 唐杰, 王军, 杨宽, 马忠雷, 张文博, 陈咏梅, 马建中. 基于天然高分子的导电材料制备及其在柔性传感器件中的应用[J]. 高分子学报, 2020,51(8):864-879. DOI： 10.11777/j.issn1000-3304.2020.20114.

Dian-dian Dong, Jing-wen Zhang, Jie Tang, Jun Wang, Kuan Yang, Zhong-lei Ma, Wen-bo Zhang, Yong-mei Chen, Jian-zhong Ma. Fabrication of Conductive Materials Based on Natural Polymers and Their Application in Flexible Sensors[J]. Acta Polymerica Sinica, 2020,51(8):864-879. DOI： 10.11777/j.issn1000-3304.2020.20114.

摘要

天然高分子材料具有来源广泛、化学成分多样、生物相容性和生物降解性良好等优势，是一类绿色可持续再生资源. 近年来，基于天然高分子的绿色柔性传感器件研究受到了国内外学者的广泛关注，并取得了长足的进展. 本文以天然高分子导电材料为主线，总结了基于天然高分子制备导电材料的模板法和掺杂法. 模板法直接以天然高分子材料的天然骨架结构作为基质，而掺杂法以天然高分子材料处理后的产物或衍生物作为基质. 归纳了基于天然高分子的柔性导电材料在湿度、温度、应变、气流/气体、光、生物传感器件中应用的研究进展，最后展望了基于天然高分子的柔性导电材料在设计和组装柔性传感器方面的前景，为高效发展绿色柔性电子和天然高分子材料的高值化利用提供新思路.

Abstract

Natural polymers are environmentally friendly and sustainable renewable raw materials with many advantages

such as variety of sources

different chemical components

excellent biocompatibility and biodegradability. The controllable production of conductive materials derived from natural polymers with excellent properties is critical for the design and manufacture of new conductive materials

and the assembly of unique functional flexible sensors. Recently

the research of green flexible sensors based on natural polymers has been widely concerned by scientists at home and abroad

and great progress has been made. The review summarizes the preparation approaches of conductive materials based on natural polymers

which can be divided into template method and doping method. The template method takes the micro-nano skeleton structures of the natural polymers as matrix

while the doping method takes the products or derivatives of the natural polymers as matrix. The research progresses of flexible sensors based on natural polymers are summarized

including the flexible sensors of humidity

temperature

strain

airflow

gas

light and biomedicine. Finally

the prospects of flexible conductive materials based on natural polymers in the design and assembly of flexible sensors are prospected

and novel ideas to efficient utilization of natural polymer materials for developing green flexible electronics have been proposed.

关键词

天然高分子导电材料柔性传感器

Keywords

Natural polymersConductive materialsFlexible sensors

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