层状MoS<sub>2</sub>复合膜的制备及其纳滤与光热抗菌性能研究

俞炯弛; 马梦琪; 朱城业; 胡登峰; 计剑; 徐志康

doi:10.11777/j.issn1000-3304.2020.20264

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层状MoS₂复合膜的制备及其纳滤与光热抗菌性能研究

研究论文 | 更新时间：2021-05-07

- 层状MoS₂复合膜的制备及其纳滤与光热抗菌性能研究
  增强出版
- MoS₂ Membranes with Photothermal Conversion Property for Nanofiltration and Antibacterial Activity
- 高分子学报 2021年52卷第5期页码：505-513
- 作者机构：
  
  浙江省吸附分离材料与应用技术重点实验室浙江大学高分子科学与工程学系　杭州 310027
- 作者简介：
  
  E-mail: xuzk@zju.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 21534009)资助项目()
- DOI：10.11777/j.issn1000-3304.2020.20264
  中图分类号：
- 纸质出版日期：2021-5-3，
  
  网络出版日期：2021-2-4，
  
  收稿日期：2020-12-4，
  
  修回日期：2021-1-6，
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俞炯弛, 马梦琪, 朱城业, 胡登峰, 计剑, 徐志康. 层状MoS₂复合膜的制备及其纳滤与光热抗菌性能研究[J]. 高分子学报, 2021,52(5):505-513.

Jiong-chi Yu, Meng-qi Ma, Cheng-ye Zhu, Deng-feng Hu, Jian Ji, Zhi-kang Xu. MoS₂ Membranes with Photothermal Conversion Property for Nanofiltration and Antibacterial Activity[J]. Acta Polymerica Sinica, 2021,52(5):505-513.
俞炯弛, 马梦琪, 朱城业, 胡登峰, 计剑, 徐志康. 层状MoS₂复合膜的制备及其纳滤与光热抗菌性能研究[J]. 高分子学报, 2021,52(5):505-513. DOI： 10.11777/j.issn1000-3304.2020.20264.

Jiong-chi Yu, Meng-qi Ma, Cheng-ye Zhu, Deng-feng Hu, Jian Ji, Zhi-kang Xu. MoS₂ Membranes with Photothermal Conversion Property for Nanofiltration and Antibacterial Activity[J]. Acta Polymerica Sinica, 2021,52(5):505-513. DOI： 10.11777/j.issn1000-3304.2020.20264.

摘要

二维纳米片构建的层状纳滤膜在工业染料和含盐废水的净化处理中显示出广泛的应用前景，但纳米片间松散的层状结构会影响过滤通道的稳定性，导致对盐类的截留效果不理想. 本文以均苯三甲酰氯(TMC)交联单宁酸(TA)官能化的二硫化钼(MoS

)纳米片构建薄层复合纳滤膜，以解决二维材料构建层状纳滤膜的常见问题. 所制备的纳滤膜不仅对荷负电染料(伊文思蓝，分子量960.8)有很高的截留率(

98.5%)，也能很好地选择性分离染料-盐混合溶液(NaCl截留率

15%). 同时，该膜还能在严苛环境中保持优秀的稳定性. 此外，在近红外光照射下，MoS

纳米片显著的光热转换效应赋予薄层复合纳滤膜一定的抗菌能力，使得该膜在实际应用中具有巨大潜力.

Abstract

Assembly of two-dimensional nanosheets has been demonstrated as one of the promising strategies to construct laminar membranes for efficient nanofiltration of dyed wastewater and even brackish water. However

these membranes are usually confined by poor stability and inferior salt rejection imposed by their loose laminar structure. Large majority of them also have complex preparation procedures and excessive feedstock consumption. Herein

new laminar nanofiltration membranes are designed to fundamentally overcome the conventional limitations. The membranes are prepared by leveraging trimesoyl chloride (TMC) dissolved in

-hexane

on the assembly of tannic acid-functionalized molybdenum disulfide (MoS

) nanosheets aqueous solution (TAT-MoS

). The interfacial polymerization reaction between TMC and TAT-MoS

takes place on polyacrylonitrile (PAN) substrate with its pH of 12. As-prepared laminar nanofiltration membranes display extraordinary stability in diverse harsh environments. The dense cross-linking network formed by acyl chloride group and MoS

nanosheets contributes to appropriate membrane pore size. Therefore

the laminar nanofiltration membranes promoted rejections against Na

(≈85%) and negatively charged dyes (

98.5%). In the meanwhile

the membranes possess high selectivity for dyes from saline solutions

which shows huge potential in industrial production (NaCl

15%). Furthermore

MoS

nanosheets endows the laminar nanofiltration membranes with remarkable photothermal effect under near infrared light irradiation. As the membrane surface temperature rose

the bacteria

one of the membrane fouling culprits

would find it harsh to survive. As dead bacteria are more easier to be rinsed over membrane surface

the laminar nanofiltration membranes retain self-cleaning function. Antibacterial capability provides a fresh solution for designing membranes which work in bacteria-rich workspaces

holding significant potentials in practical applications.

关键词

二硫化钼薄层复合膜纳滤光热转换效应抗菌

Keywords

Two-dimensional nanosheetsLaminar membraneNanofiltrationPhotothermal effectAntibacterial activity

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DOI：10.11777/j.issn1000-3304.2020.20264

摘要

Abstract

关键词

Keywords

references

层状MoS₂复合膜的制备及其纳滤与光热抗菌性能研究

MoS₂ Membranes with Photothermal Conversion Property for Nanofiltration and Antibacterial Activity