基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层

赵书瑞; 申婷; 李玉堂; 邓然; 杨皓程; 李伟华

doi:10.11777/j.issn1000-3304.2021.21116

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基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层

研究论文 | 更新时间：2023-05-22

- 基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层
- ‍ Epoxy-resin-based Slippery Liquid Infused Anti-icing Coating Based on Breath Figure
- 高分子学报 2021年52卷第12期页码：1622-1631
- 作者机构：
  
  中山大学化学工程与技术学院珠海 519000
- 作者简介：
  
  E-mail: yanghch8@mail.sysu.edu.cn
  liweihua3@mail.sysu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 ┣51909291;51525903);51879292┫;广东省基础与应用基础研究基金区域联合基金(基金号 2020A1515110678)
- DOI：10.11777/j.issn1000-3304.2021.21116
  中图分类号：
- 纸质出版日期：2021-12-20，
  
  网络出版日期：2021-08-26，
  
  收稿日期：2021-04-23，
  
  修回日期：2021-05-19，
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赵书瑞,申婷,李玉堂等.基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层[J].高分子学报,2021,52(12):1622-1631.

Zhao Shu-rui,Shen Ting,Li Yu-tang,et al.‍ Epoxy-resin-based Slippery Liquid Infused Anti-icing Coating Based on Breath Figure[J].ACTA POLYMERICA SINICA,2021,52(12):1622-1631.
赵书瑞,申婷,李玉堂等.基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层[J].高分子学报,2021,52(12):1622-1631. DOI： 10.11777/j.issn1000-3304.2021.21116.

Zhao Shu-rui,Shen Ting,Li Yu-tang,et al.‍ Epoxy-resin-based Slippery Liquid Infused Anti-icing Coating Based on Breath Figure[J].ACTA POLYMERICA SINICA,2021,52(12):1622-1631. DOI： 10.11777/j.issn1000-3304.2021.21116.

摘要

通过呼吸图法构筑了多孔环氧树脂基底，并在此基础上通过聚二甲基硅氧烷改性以及二甲基硅油润滑液灌注制备了具有优异润滑性的液体灌注涂层. 实验结果表明，基底表面孔径及孔隙率随着环境湿度增大而增大，且涂层在不同金属基底上都有良好的黏附性能. 基于上述基底所制备的液体灌注涂层具有较低的滚动角(2°)，且对多种液体具有良好的滑动性. 该涂层被用于冰黏附的防治，展现出较低的冰黏附强度(175 kPa)及较长的延迟结冰时间(>600 s)，表明其具有优异的防冰性能.

Abstract

Slippery liquid-infused porous surface (SLIPS) is an emerging low-adhesion material that has found wide uses in anti-icing and anti-fouling. However

the poor adhesion of SLIPSs by top-down methods restricts the practical applications of SLIPSs. In the current research

we fabricated an epoxy-based SLIPS with excellent liquid-repellent and anti-icing properties. The porous epoxy resin substrate was primarily constructed by breath figure and then modified with polydimethylsiloxane (PDMS). Silicone oil was infiltrated within the substrate

serving as the lubricant layer. The hygroscopic polyamine cross-linker plays a crucial role in inducing water droplet nucleation. The surface pore size of the epoxy substrate grows from 4.09 μm to 5.09 μm while the porosity increases from 4.73% to 46.67% when the environmental humidity is elevated from (65±5)% to (95±5)%. The porous epoxy coatings attach robustly to a variety of metal substrates with an adhesion strength of around 2.2 MPa. After grafting PDMS

the pores were filled with the polymer

which could reserve silicone oil through polymer swelling and capillary sorption. The SLIPS prepared based on the epoxy substrate exhibits an extremely low water sliding angle of 2°

as well as excellent repellence to a variety of liquids including coffee

Chinese ink

milk and even high-viscous honey. On the other hand

the dynamic lubricant layer endows the coating with excellent anti-icing property owing to its low freezing temperature. The coating performs a much longer delay in freezing time (632 s) than those of the glass (21 s) and epoxy coating (94 s)

as well as ultralow ice adhesion strength of 1.75 kPa in contrast to the glass substrate (166.9 kPa) and epoxy coating (50.7 kPa)

indicating excellent anti-icing performance. The ice adhesion strength on our SLIPS is much smaller than those on commercial and some reported anti-icing coatings. Moreover

no obvious increase in ice adhesion strength can be observed after 20 times tests

displaying outstanding long-term anti-icing property.

关键词

呼吸图法环氧树脂超滑液体灌注涂层防冰

Keywords

Breath figureEpoxy resinSlippery liquid infused porous surfaceAnti-icing

references

Jamil M I, Ali A, Haq F, Zhang Q, Zhan X, Chen F. Langmuir, 2018, 34(50): 15425-15444. doi:10.1021/acs.langmuir.8b03276http://dx.doi.org/10.1021/acs.langmuir.8b03276

Ignatyev D I, Khrabrov A N, Bazhenov S G. Aerosp Sci Technol, 2020, 104: 105914. doi:10.1016/j.ast.2020.105914http://dx.doi.org/10.1016/j.ast.2020.105914

Lv Jianyong(吕健勇), He Zhiyuan(贺志远), Wang Jianjun(王健君). Acta Polymerica Sinica(高分子学报), 2017, (12): 1870-1882. doi:10.11777/j.issn1000-3304.2017.17216http://dx.doi.org/10.11777/j.issn1000-3304.2017.17216

Cheng Shuman(程舒曼), Guo Pu(郭璞), Heng Liping(衡利苹). Acta Polymerica Sinica(高分子学报), 2020, 51(5):. doi:10.11777/j.issn1000-3304.2020.19226http://dx.doi.org/10.11777/j.issn1000-3304.2020.19226

530-547. doi:10.11777/j.issn1000-3304.2020.19226http://dx.doi.org/10.11777/j.issn1000-3304.2020.19226

Wong T S, Kang S H, Tang S K, Smythe E J, Aizenberg J. Nature, 2011, 477(7365): 443-447. doi:10.1038/nature10447http://dx.doi.org/10.1038/nature10447

Deng R, Shen T, Chen H, Lu J, Yang H C, Li W. J Mater Chem A, 2020, 8(16): 7536-7547. doi:10.1039/d0ta02000ahttp://dx.doi.org/10.1039/d0ta02000a

Solomon B R, Khalil K S, Varanasi K K. Langmuir, 2014, 30(36): 10970-10976. doi:10.1021/la5021143http://dx.doi.org/10.1021/la5021143

Bartolo D, Bouamrirene F, Verneuil É, Moulinet S. Europhys Lett, 2006, 74(2): 299-305. doi:10.1209/epl/i2005-10522-3http://dx.doi.org/10.1209/epl/i2005-10522-3

Yuan S, Li Z, Song L, Shi H, Luan S, Yin J. ACS Appl Mater Interfaces, 2016, 8(33): 21214-21220. doi:10.1021/acsami.6b06407http://dx.doi.org/10.1021/acsami.6b06407

Xu Y, Liu M. Surf Coat Technol, 2016, 307: 332-344. doi:10.1016/j.surfcoat.2016.08.091http://dx.doi.org/10.1016/j.surfcoat.2016.08.091

Sett S, Yan X, Barac G, Bolton L W, Miljkovic N. ACS Appl Mater Interfaces, 2017, 9(41): 36400-36408. doi:10.1021/acsami.7b10756http://dx.doi.org/10.1021/acsami.7b10756

Denq B, Hu Y, Chen L. J Appl Polym Sci, 1999, 74(1): 229-237. doi:10.1002/(sici)1097-4628(19991003)74:1<229::aid-app28>3.0.co;2-chttp://dx.doi.org/10.1002/(sici)1097-4628(19991003)74:1<229::aid-app28>3.0.co;2-c

Zhang A, Bai H, Li L. Chem Rev, 2015, 115(18): 9801-9868. doi:10.1021/acs.chemrev.5b00069http://dx.doi.org/10.1021/acs.chemrev.5b00069

Sun Wei(孙巍), Zhou Yuchen(周雨辰), Chen Zhongren(陈忠仁). Acta Polymerica Sinica(高分子学报), 2012, (12): 1459-1464. doi:10.3724/SP.J.1105.2012.12130http://dx.doi.org/10.3724/SP.J.1105.2012.12130

Ferrari E, Fabbri P, Pilati F. Langmuir, 2011, 27(5): 1874-1881. doi:10.1021/la104500jhttp://dx.doi.org/10.1021/la104500j

Zhu L W, Ou Y, Wan L S, Xu Z K. J Phys Chem B, 2014, 118(3): 845-854. doi:10.1021/jp4114392http://dx.doi.org/10.1021/jp4114392

Peng J, Han Y, Yang Y, Li B. Polymer, 2004, 45(2): 447-452. doi:10.1016/j.polymer.2003.11.019http://dx.doi.org/10.1016/j.polymer.2003.11.019

Bui V T, Ko S H, Choi H S. Chem Commun, 2014, 50(29): 3817-3819. doi:10.1039/c3cc48654khttp://dx.doi.org/10.1039/c3cc48654k

Liu X, Zhang X, Chen Q, Pan Y, Liu C, Shen C. Chem Eng J, 2021, 406: 126532. doi:10.1016/j.cej.2020.126532http://dx.doi.org/10.1016/j.cej.2020.126532

Sohbatzadeh F, Shabannejad A, Ghasemi M, Mahmoudsani Z. Prog Org Coat, 2021, 151: 106070. doi:10.1016/j.porgcoat.2020.106070http://dx.doi.org/10.1016/j.porgcoat.2020.106070

Liu K, Yao X, Jiang L. Chem Soc Rev, 2010, 39(8): 3240-3255. doi:10.1039/b917112fhttp://dx.doi.org/10.1039/b917112f

Li Jingye(李景烨), Wang Ziqiang(王自强), Yu Ming(虞鸣). Acta Polymerica Sinica(高分子学报), 2017, (2): 315-320. doi:10.11777/j.issn1000-3304.2017.16273http://dx.doi.org/10.11777/j.issn1000-3304.2017.16273

Liu Zhu(刘珠), Hong Peng(洪鹏), Xiang Hongping(向洪平), Huang Ziying(黄梓英), Luo Qinghong(罗青宏), Yang Xianjun(杨先君) and Liu Xiaoxuan(刘晓暄). Acta Polymerica Sinica(高分子学报), 2020, 51(6): 656-669. doi:10.11777/j.issn1000-3304.2019.19207http://dx.doi.org/10.11777/j.issn1000-3304.2019.19207

Golovin K, Kobaku S P R, Lee D. Sci Adv, 2016, 2(3): 2375-2548. doi:10.1126/sciadv.1501496http://dx.doi.org/10.1126/sciadv.1501496

Aghdam A S, Cebeci F C. Langmuir, 2020, 36(46): 14145-14154. doi:10.1021/acs.langmuir.0c02873http://dx.doi.org/10.1021/acs.langmuir.0c02873

Wang F, Ding W, He J. Chem Eng J, 2019, 360: 243-249. doi:10.1016/j.cej.2018.11.224http://dx.doi.org/10.1016/j.cej.2018.11.224

Zhang L, Guo Z, Sarma J. ACS Appl Mater Interfaces, 2020, 12(17): 20084-20095. doi:10.1021/acsami.0c02014http://dx.doi.org/10.1021/acsami.0c02014

Liu C, Li Y, Lu C. ACS Appl Mater Interfaces, 2020, 12(22): 25471-25477. doi:10.1021/acsami.0c05954http://dx.doi.org/10.1021/acsami.0c05954

Han G, Nguyen T B, Park S. ACS Nano, 2020, 14(8): 10198-10209. doi:10.1021/acsnano.0c03463http://dx.doi.org/10.1021/acsnano.0c03463

Wei C, Zhang G, Zhang Q. ACS Appl Mater Interfaces, 2016, 8(50): 34810-34819. doi:10.1021/acsami.6b09879http://dx.doi.org/10.1021/acsami.6b09879

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