基于窄带系DPP类聚合物的高性能近红外有机光探测器件

秦铭聪; 李清源; 张帆; 匡俊华; 刘凯; 刘彦伟; 朱明亮; 赵志远; 潘志超; 边洋爽; 郭云龙; 刘云圻

doi:10.11777/j.issn1000-3304.2021.21334

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基于窄带系DPP类聚合物的高性能近红外有机光探测器件

研究论文 | 更新时间：2024-10-08

- 基于窄带系DPP类聚合物的高性能近红外有机光探测器件
  增强出版
- High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer
- 高分子学报 2022年53卷第4期页码：405-413
- 作者机构：
  
  1.北京分子科学国家研究中心中国科学院化学研究所有机固体院重点实验室北京 100190
  2.中国科学院大学北京 100049
- 作者简介：
  
  E-mail: guoyunlong@iccas.ac.cn
- 基金信息：
  
  国家重点基础研究发展计划(2018YFA0703200);国家自然科学基金(基金号 ┣61890940;21922511);91833306, 91833304┫;中国科学院前沿重点项目和先导专项(QYZDY-SSW-SLH029;XDB30000000)
- DOI：10.11777/j.issn1000-3304.2021.21334
  中图分类号：
- 纸质出版日期：2022-04-20，
  
  网络出版日期：2022-01-19，
  
  收稿日期：2021-11-01，
  
  修回日期：2021-12-17，
- 稿件说明：
移动端阅览
秦铭聪,李清源,张帆等.基于窄带系DPP类聚合物的高性能近红外有机光探测器件[J].高分子学报,2022,53(04):405-413.

Qin Ming-cong,Li Qing-yuan,Zhang Fan,et al.High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer[J].ACTA POLYMERICA SINICA,2022,53(04):405-413.
秦铭聪,李清源,张帆等.基于窄带系DPP类聚合物的高性能近红外有机光探测器件[J].高分子学报,2022,53(04):405-413. DOI： 10.11777/j.issn1000-3304.2021.21334.

Qin Ming-cong,Li Qing-yuan,Zhang Fan,et al.High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer[J].ACTA POLYMERICA SINICA,2022,53(04):405-413. DOI： 10.11777/j.issn1000-3304.2021.21334.

摘要

采用窄带隙给体材料DPPDTT和富勒烯衍生物受体PCBM共混作为活性层，制备了具有高激子分离和电荷传输效率的近红外有机光探测器件，并进一步采用窄带隙受体Y6代替PCBM制备一种“双窄带隙吸收”的异质结结构，在近红外区域的吸收叠加有效地增强了器件光响应能力. 最后，通过采用厚活性层、插入阻挡层以及制备倒置结构等方法，将器件的暗电流进一步降低1个数量级. 在850 nm，0.53 μW·cm

-2

的近红外光照射下，比探测率提升至8.28×10

Jones. 同时，随着测量频率的提升，器件响应的速度和强度几乎没有发生变化，在120帧/秒的条件下仍表现出很好的循环稳定性. 研究结果表明该类器件在光电通信、近红外成像以及医疗生理检测等方向具有良好的应用前景.

Abstract

High-performance near-infrared (NIR) organic photodetectors (OPDs) have widespread application prospects in artificial vision

biological imaging

flexible wearable electronic devices. Ascribed to high absorption coefficient and charge-carrier mobility

the narrow-bandgap polymer DPPDTT displayed a great potential for NIR OPDs. However

due to the nature of narrow bandgap and strong intermolecular interactions

the DPPDTT-based OPDs exhibit a low detectivity (

(

)). Here

we introduced PCBM as the acceptor material to construct bulk-heterojunction photodiodes

which improved the efficiency of exciton separation and charge transfer

so that the

(

) can be simultaneously enhanced. Moreover

when the narrow-bandgap acceptor Y6 is utilized instead of PCBM to afford a "double narrow-bandgap absorption" heterojunction structure

the superposition of absorption in the near-infrared region could effectively enhance the light response capability of devices. Finally

by adopting the inverted structure and inserting barrier layers

the dark current is further reduced by one order of magnitude

and the

(λ)

is increased to 8.28×10

Jones under 850 nm at a light irradiation of 0.53 μW·cm

-2

. With the increase of the measurement frequency

the response spe

ed and the

(

) of the device were kept at same value

and it still showed good cycle stability under the condition of 120 frames per second. Thus

the above results confirm that this type of device will show promising applications in photoelectric communication

NIR imaging

physiological testing

and so forth.

关键词

窄带系DPP类聚合物高性能二极管近红外有机光探测器

Keywords

Narrow-bandgap DPP-based polymerHigh performanceDiodeNear-infrared organic photodetectors

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