以噻吩［3,4-<italic style="font-style: italic">b</italic>］并噻吩为核的近红外电子受体及其高性能光探测器

潘幼文; 陶利婷; 高健; 何程亮; 刘智鑫; 方彦俊; 施敏敏; 陈红征

doi:10.11777/j.issn1000-3304.2021.21340

您当前的位置：

首页 >

文章列表页 >

以噻吩［3,4-b］并噻吩为核的近红外电子受体及其高性能光探测器

研究论文 | 更新时间：2024-10-08

- 以噻吩［3,4-b］并噻吩为核的近红外电子受体及其高性能光探测器
  增强出版
- A Near-infrared Electron Acceptor with Thieno[3,4-b]thiophene as the Core and the Related High-performance Photodetectors
- 高分子学报 2022年53卷第4期页码：424-432
- 作者机构：
  
  1.高分子合成与功能构造教育部重点实验室浙江大学高分子科学与工程学系杭州 310027
  2.硅材料国家重点实验室 3.浙江大学材料科学与工程学院杭州 310027
  3.School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027
- 作者简介：
  
  E-mail: jkfang@zju.edu.cn；
  E-mail:minminshi@zju.edu.cn；
- 基金信息：
  
  国家自然科学基金(基金号 ┣21875216);21734008┫;国家重点研发计划(2019YFA0705900)
- DOI：10.11777/j.issn1000-3304.2021.21340
  中图分类号：
- 纸质出版日期：2022-04-20，
  
  网络出版日期：2022-01-20，
  
  收稿日期：2021-11-04，
  
  修回日期：2021-12-09，
- 稿件说明：
移动端阅览
潘幼文,陶利婷,高健等.以噻吩［3,4-b］并噻吩为核的近红外电子受体及其高性能光探测器[J].高分子学报,2022,53(04):424-432.

Pan You-wen,Tao Li-ting,Gao Jian,et al.A Near-infrared Electron Acceptor with Thieno[3,4-b]thiophene as the Core and the Related High-performance Photodetectors[J].ACTA POLYMERICA SINICA,2022,53(04):424-432.
潘幼文,陶利婷,高健等.以噻吩［3,4-b］并噻吩为核的近红外电子受体及其高性能光探测器[J].高分子学报,2022,53(04):424-432. DOI： 10.11777/j.issn1000-3304.2021.21340.

Pan You-wen,Tao Li-ting,Gao Jian,et al.A Near-infrared Electron Acceptor with Thieno[3,4-b]thiophene as the Core and the Related High-performance Photodetectors[J].ACTA POLYMERICA SINICA,2022,53(04):424-432. DOI： 10.11777/j.issn1000-3304.2021.21340.

摘要

为了实现在近红外区的良好光电响应，设计合成了一种A-D-A型有机电子受体TCIC. 由于采用具有强醌式效应的噻吩[3

]

并噻吩单元为核，TCIC在780~1000 nm的近红外区具有强吸收以及合适的能级结构，可与常用的聚合物给体PCE10的吸收和能级相匹配. 于是，采用2种器件结构，制备了基于PCE10:TCIC共混膜的自供电式(0 V偏压下)有机光探测器，并发现，相比于正型器件，反型器件更有利于抑制暗电流与总噪声电流. 最终，反型器件在410~1000 nm的宽光谱范围内的比探测率均达到了10

Jones以上，而且，在940 nm波长下，器件表现出超宽的线性动态范围(~180 dB)以及极快的响应速度(~6.5 μs)，这些指标都处于目前有机光探测器的最优行列. 所以，本工作为高性能近红外受体的分子设计提供了重要指导.

Abstract

In order to obtain high photoelectric responses in the near-infrared (NIR) region

in this work

an A-D-A type organic electron acceptor

TCIC

is designed and synthesized. Due to the strong quinoid effect of the thieno[3

]

thiophene core

TCIC has strong absorptions in the NIR range of 780‒1000 nm and suitable energy levels

which match well with those of the commonly used polymer donor

PCE10. Thus

two device structures are adopted to fabricate the self-powered (at 0 V bias) organic photodetectors (OPDs) based on PCE10:TCIC blended films. Compared to the conventional device

the inverted device is beneficial to suppress dark current and total noise current. Finally

the inverted device achieves the specific detectivities of more than 10

Jones across the broad spectrum of 410‒1000 nm

and exhibits an ultra-wide linear dynamic range of ~180 dB and an extremely fast response speed of ~6.5 μs under illumination of lights at 940 nm

giving excellent figure-of-merits comparable to those of the best OPDs reported so far. Therefore

this work provides important guidance for the molecular design of high-performance NIR acceptors.

关键词

近红外电子受体噻吩[34-b]并噻吩有机光探测器比探测率

Keywords

Near-infrared electron acceptorsThieno[34-b]thiopheneOrganic photodetectorsSpecific detectivity

references

Zhan L, Li S, Xia X, Li Y, Lu X, Zuo L, Shi M, Chen H. Adv Mater, 2021, 33(12): 2007231. doi:10.1002/adma.202007231http://dx.doi.org/10.1002/adma.202007231

Xu Jingqi(许景琦), Fu Weifei(傅伟飞), Yang Shida(杨时达), Liu Tang(刘唐), Li Changzhi(李昌治), Chen Hongzheng(陈红征). Acta Polymerica Sinica(高分子学报), 2018, (2): 164-173. doi:10.11777/j.issn1000-3304.2018.17251http://dx.doi.org/10.11777/j.issn1000-3304.2018.17251

Liu X, Yin Q, Hu Z, Wang Z, Huang F, Cao Y. Chinese J Polym Sci, 2019, 37: 18-27. doi:10.1007/s10118-019-2188-1http://dx.doi.org/10.1007/s10118-019-2188-1

Zhang Z, Bai Y, Li Y. Chinese J Polym Sci, 2021, 39: 1-13. doi:10.1007/s10118-020-2496-5http://dx.doi.org/10.1007/s10118-020-2496-5

Lee J, Ko SJ, Lee H, Huang J, Zhu Z, Seifrid M, Vollbrecht J, Brus V V, Karki A, Wang H, Cho K, Nguyen T Q, Bazan G C. ACS Energy Lett, 2019, 4(6): 1401-1409. doi:10.1021/acsenergylett.9b00721http://dx.doi.org/10.1021/acsenergylett.9b00721

Wang X, Gao S, Han J, Zhang Y, Zhang S, Qiao W, Wang Z. Chinese J Polym Sci, 2021, 39: 831-837. doi:10.1186/s13020-021-00456-9http://dx.doi.org/10.1186/s13020-021-00456-9

Yang W, Qu W, Georgitzikis E, Simoen E, Serron J, Lee J, Lieberman I, Cheyns D, Malinowski P, Genoe J, Chen H, Heremans P. ACS Appl Mater Interfaces, 2021, 13(14): 16766-16774. doi:10.1021/acsami.1c02080http://dx.doi.org/10.1021/acsami.1c02080

Xie B, Xie R, Zhang K, Yin Q, Hu Z, Yu G, Huang F, Cao Y. Nat Commun, 2021, 11: 2871. doi:10.1039/c9py01781jhttp://dx.doi.org/10.1039/c9py01781j

Zhang Ming(‍张‍明), Zhu Lei(‍朱‍磊), Qiu Chaoqun(‍邱‍超‍群), Zhang Yongming(‍张‍永‍明), Liu Feng(‍刘‍烽). Acta Polymerica Sinica(高分子学报), 2019, 50(4): 352-358. doi:10.11777/j.issn1000-3304.2019.19010http://dx.doi.org/10.11777/j.issn1000-3304.2019.19010

Li Z, Zhong W, Ying L, Li N, Liu F, Huang F, Cao Y. Chinese J Polym Sci, 2020, 38: 323-331. doi:10.1007/s10118-020-2356-3http://dx.doi.org/10.1007/s10118-020-2356-3

Li Y, He C, Zuo L, Zhao F, Zhan L, Li X, Xia R, Yip H L, Li C Z, Liu X, Chen H. Adv Energy Mater, 2021, 11(11): 2003408. doi:10.1002/aenm.202003408http://dx.doi.org/10.1002/aenm.202003408

Chen Z, Ma S, Zhang K, Hu Z, Yin Q, Huang F, Cao Y. Chinese J Polym Sci, 2021, 39: 35-42. doi:10.1007/s10118-020-2440-8http://dx.doi.org/10.1007/s10118-020-2440-8

Xie C, Yan F. Small, 2017, 13(43): 1701822. doi:10.1002/smll.201701822http://dx.doi.org/10.1002/smll.201701822

Park S, Heo S W, Lee W, Inoue D, Jiang Z, Yu K, Jinno H, Hashizume D, Sekino M, Yokota T, Fukuda K, Tajima K,. doi:10.1038/s41586-018-0536-xhttp://dx.doi.org/10.1038/s41586-018-0536-x

Someya T. Nature, 2018, 561: 516-521. doi:10.1038/s41586-018-0536-xhttp://dx.doi.org/10.1038/s41586-018-0536-x

Liu Z X, Lau T K, Zhou G, Li S, Ren J, Das S K, Xia R, Wu G, Zhu H, Lu X, Yip H L, Chen H, Li C Z. Nano Energy, 2019, 63: 103807. doi:10.1016/j.nanoen.2019.06.003http://dx.doi.org/10.1016/j.nanoen.2019.06.003

Chow P C Y, Someya T. Adv Mater, 2020, 32(15): 1902045. doi:10.1002/adma.201902045http://dx.doi.org/10.1002/adma.201902045

Chen Y, Zheng Y, Jiang Y, Fan H, Zhu X. J Am Chem Soc, 2021, 143(11): 4281-4289. doi:10.1021/jacs.0c12818http://dx.doi.org/10.1021/jacs.0c12818

Lin Y, Wang J, Zhang Z, Bai H, Li Y, Zhu D, Zhan X. Adv Mater, 2015, 27(7): 1170-1174. doi:10.1002/adma.201404317http://dx.doi.org/10.1002/adma.201404317

Yuan J, Zhang Y, Zhou L, Zhang G, Yip H L, Lau T K, Lu X, Zhu C, Peng H, Johnson P A, Leclerc M, Cao Y, Ulanski J, Li Y, Zou Y. Joule, 2019, 3(4): 1140-1151. doi:10.1016/j.joule.2019.01.004http://dx.doi.org/10.1016/j.joule.2019.01.004

Zhang Z, Zhang S, Liu Z, Zhang Z, Li Y, Li C Z, Chen H. Acta Phys-Chim Sin, 2019, 35(4): 394-400

Li S, Zhan L, Jin Y, Zhou G, Lau T K, Qin R, Shi M, Li C Z, Zhu H, Lu X, Zhang F, Chen H. Adv Mater, 2020, 32(24): 2001160. doi:10.1002/adma.202001160http://dx.doi.org/10.1002/adma.202001160

Li W, Xu Y L, Meng X, Xiao Z, Li R, Jiang L, Cui L, Zheng M, Liu C, Ding L, Lin Q. Adv Funct Mater, 2019, 29(20): 1808948. doi:10.1002/adfm.201808948http://dx.doi.org/10.1002/adfm.201808948

Liu J, Jiang J, Wang S, Li T, Jing X, Liu Y, Wang Y, Wen H, Yao M, Zhan X, Shen L. Small, 2021, 17(43): 2101316. doi:10.1002/smll.202101316http://dx.doi.org/10.1002/smll.202101316

Wei Y, Chen H, Liu T, Wang S, Jiang Y, Song Y, Zhang J, Zhang X, Lu G, Huang F, Wei Z, Huang H. Adv Funct Mater, 2021, DOI: 10.1002/adfm.202106326http://dx.doi.org/10.1002/adfm.202106326

Wang J, Wang W, Wang X, Wu Y, Zhang Q, Yan C, Ma W, You W, Zhan X. Adv Mater, 2017, 29(35): 1702125. doi:10.1002/adma.201702125http://dx.doi.org/10.1002/adma.201702125

Yao H, Cui Y, Yu R, Gao B, Zhang H, Hou J. Angew Chem Int Ed, 2017, 56(11): 3045-3049. doi:10.1002/anie.201610944http://dx.doi.org/10.1002/anie.201610944

Li W, Xu Y, Meng X, Xiao Z, Li R, Jiang L, Cui L, Zheng M, Liu C, Ding L, Lin Q. Adv Funct Mater, 2019, 29(20): 1808948. doi:10.1002/adfm.201808948http://dx.doi.org/10.1002/adfm.201808948

He C, Li Y, Liu Y, Li Y, Zhou G, Li S, Zhu H, Lu X, Zhang F, Li C Z, Chen H. J Mater Chem A, 2020, 8(35): 18154-18161. doi:10.1039/d0ta06907hhttp://dx.doi.org/10.1039/d0ta06907h

Chen H Y, Hou J, Zhang S, Liang Y, Yang G, Yang Y, Yu L, Wu Y, Li G. Nat Photon, 2009, 3(11): 649-653. doi:10.1038/nphoton.2009.192http://dx.doi.org/10.1038/nphoton.2009.192

Hou J, Chen H, Zhang S, Chen R, Yang Y, Wu Y, Li G. J Am Chem Soc, 2009, 131(43): 15586-15587. doi:10.1021/ja9064975http://dx.doi.org/10.1021/ja9064975

Huo L, Zhang S, Guo X, Xu F, Li Y, Hou J. Angew Chem Int Ed, 2011, 50(41): 9697-9702. doi:10.1002/anie.201103313http://dx.doi.org/10.1002/anie.201103313

Li S, Zhan L, Liu F, Ren J, Shi M, Li C Z, Russell T P, Chen H. Adv Mater, 2018, 30(6): 1705208. doi:10.1002/adma.201705208http://dx.doi.org/10.1002/adma.201705208

Geng S, Yang W, Gao J, Li S, Shi M, Lau T K, Lu X, Li C Z, Chen H. Chinese J Polym Sci, 2019, 37: 1005-1014. doi:10.1007/s10118-019-2309-xhttp://dx.doi.org/10.1007/s10118-019-2309-x

Huang H, Guo Q, Feng S, Zhang C, Bi Z, Xue W, Yang J, Song J, Li C, Xu X, Tang Z, Ma W, Bo Z. Nat Commun, 2019, 10(1): 3038. doi:10.1038/s41467-019-11001-6http://dx.doi.org/10.1038/s41467-019-11001-6

He C, Li Y, Li S, Yu Z P, Li Y, Lu X, Shi M, Li C Z, Chen H. ACS Appl Mater Interfaces, 2020, 12(14): 16700-16706. doi:10.1021/acsami.0c00837http://dx.doi.org/10.1021/acsami.0c00837

Pang S, Zhou X, Zhang S, Tang H, Dhakal S, Gu X, Duan C, Huang F, Cao Y. ACS Appl Mater Interfaces, 2020, 12(14): 16531-16540. doi:10.1021/acsami.0c01850http://dx.doi.org/10.1021/acsami.0c01850

Gao J, Li Y, Li S, Xia X, Lu X, Shi M, Chen H. Sol Energy Mater Sol Cells, 2021, 225: 111046. doi:10.1016/j.solmat.2021.111046http://dx.doi.org/10.1016/j.solmat.2021.111046

Ye S, Chen S, Li S, Pan Y, Xia X, Fu W, Zuo L, Lu X, Shi M, Chen H. ChemSusChem, 2021, 14(17): 3599-3606. doi:10.1002/cssc.202100689http://dx.doi.org/10.1002/cssc.202100689

Yao Z, Li Y, Li S, Xiang J, Xia X, Lu X, Shi M, Chen H. ACS Appl Energy Mater, 2020, 4(1): 819-827. doi:10.1021/acsaem.0c02719http://dx.doi.org/10.1021/acsaem.0c02719

Huang J, Lee J, Vollbrecht J, Brus V V, Dixon A L, Cao D X, Zhu Z, Du Z, Wang H, Cho K, Bazan G C, Nguyen T Q. Adv Mater, 2020, 32(1): 1906027. doi:10.1002/adma.201906027http://dx.doi.org/10.1002/adma.201906027

Wen T J, Wang D, Tao L, Xiao Y, Tao Y D, Li Y, Lu X, Fang Y, Li C Z, Chen H, Yang D. ACS Appl Mater Interfaces, 2020, 12(35): 39515-39523. doi:10.1021/acsami.0c12100http://dx.doi.org/10.1021/acsami.0c12100

浏览量

165

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

可拉伸高分子光电器件的研究进展

以噻吩［3,4-b］并噻吩为核的近红外电子受体及其高性能光探测器

A Near-infrared Electron Acceptor with Thieno[3,4-b]thiophene as the Core and the Related High-performance Photodetectors

DOI：10.11777/j.issn1000-3304.2021.21340

摘要

Abstract

关键词

Keywords

references