超声辅助制备超疏水聚丙烯表面花瓣状微纳结构

邢清松; 陈旭龙; 陶嘉宇; 陈安伏; 张艳梅; 雷彩红

doi:10.11777/j.issn1000-3304.2021.21403

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超声辅助制备超疏水聚丙烯表面花瓣状微纳结构

研究论文 | 更新时间：2024-10-08

- 超声辅助制备超疏水聚丙烯表面花瓣状微纳结构
- Ultrasonic Assisted Preparation of Superhydrophobic Polypropylene with Flower-like Micro-/Nanostructure on Surfaces
- 高分子学报 2022年53卷第6期页码：645-652
- 作者机构：
  
  1.广东工业大学材料与能源学院广东省功能软凝聚态物质重点实验室广州 510006
  2.深圳市鹏准模具有限公司深圳 518108
- 作者简介：
  
  E-mail: anfuchen@gdut.edu.cn;
  E-mail:zhyanmei@gdut.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 52003057)
- DOI：10.11777/j.issn1000-3304.2021.21403
  中图分类号：
- 纸质出版日期：2022-06-20，
  
  网络出版日期：2022-04-26，
  
  收稿日期：2021-12-30，
  
  录用日期：2022-03-24
- 稿件说明：
移动端阅览
邢清松,陈旭龙,陶嘉宇等.超声辅助制备超疏水聚丙烯表面花瓣状微纳结构[J].高分子学报,2022,53(06):645-652.

Xing Qing-song,Chen Xu-long,Tao Jia-yu,et al.Ultrasonic Assisted Preparation of Superhydrophobic Polypropylene with Flower-like Micro-/Nanostructure on Surfaces[J].ACTA POLYMERICA SINICA,2022,53(06):645-652.
邢清松,陈旭龙,陶嘉宇等.超声辅助制备超疏水聚丙烯表面花瓣状微纳结构[J].高分子学报,2022,53(06):645-652. DOI： 10.11777/j.issn1000-3304.2021.21403.

Xing Qing-song,Chen Xu-long,Tao Jia-yu,et al.Ultrasonic Assisted Preparation of Superhydrophobic Polypropylene with Flower-like Micro-/Nanostructure on Surfaces[J].ACTA POLYMERICA SINICA,2022,53(06):645-652. DOI： 10.11777/j.issn1000-3304.2021.21403.

摘要

超疏水微纳结构表面广泛应用于自清洁、防冰、抗菌、柔性传感等领域，但其制备工艺仍面临一定的挑战. 以阳极氧化铝(AAO)膜为模板，采用热压印在聚丙烯(PP)表面成型了规整的纳米结构阵列. 对纳米结构阵列进行超声处理，在超声空化作用下，PP表面纳米结构转变为类花瓣状微纳结构. 结果表明，经超声处理后的微纳结构PP表面的接触角从152.3°上升至160.0°，滚动角从11.5°降低至1.8°，表面黏附力从75 μN降低至38 μN，呈现典型的超疏水低黏附特性且其自清洁效应明显. 采用模板法与超声辅助相结合的方法制备超疏水微纳表面具有方便快捷、成本低廉、效果显著的优点，有望应用于工业生产领域.

Abstract

Superhydrophobic micro-/nanostructured surfaces are widely used in the fields of self-cleaning

anti-icing

anti-bacterial and flexible sensor

but there are still some challenges in the preparation methods of these surfaces. In this work

the polypropylene (PP) surfaces with nanostructure arrays were prepared using the hot compression molding with anodic aluminum oxide (AAO) templates. With the ultrasonic-assisted treatment

the nanostructure was transformed onto micro-/nanostructure due to the ultrasonic cavitation effect. The superhydrophobic property of micro-/nanostructured surface was improved after ultrasonic treatment

the contact angle increased from 152.3° to 160.0°

the rolling angle decreased from 11.5° to 1.8°

and the surface adhesion decreased from 75 μN to 38 μN. Moreover

the self-cleaning performance of the micro-/nanostructured PP surface was also better than that of the nanostructured PP surface. The template method combining with the ultrasonic-assisted treatment is convenient

cheap

and effective in the preparation of superhydrophobic micro-/nanostructured surfaces

expecting promising applications in industrial production.

关键词

压缩模塑阳极氧化铝超声处理微纳结构超疏水

Keywords

Compression moldingAnodic aluminum oxideUltrasonic-assisted treatmentMicro-/nanostructureSuperhydrophobic

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