聚合物纳米杂化高性能光功能材料

刘朋远; 刘崇铭; 杨柏

doi:10.11777/j.issn1000-3304.2022.22162

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聚合物纳米杂化高性能光功能材料

综述 | 更新时间：2023-05-22

- 聚合物纳米杂化高性能光功能材料
- High Performance Polymer Nano-hybrid Optical Function Materials
- 高分子学报 2023年54卷第1期页码：37-64
- 作者机构：
  
  超分子结构与材料国家重点实验室吉林大学化学学院长春 130012
- 作者简介：
  
  [ "杨柏，男，1962年生. 1984年毕业于吉林大学化学系，1991年获吉林大学高分子化学与物理专业博士学位；1987年起在吉林大学化学系任教，1994年至今任吉林大学教授，1999年聘为教育部长江学者特聘教授并获国家杰出青年科学基金支持，2009年作为负责人获“创新研究群体”基金支持. 迄今已发表SCI论文600余篇，论文被SCI引用41000余次；2014年以来连续入选爱思唯尔中国高被引学者榜单，2018年以来连续入选科睿唯安交叉学科全球高被引学者榜单；作为第一完成人，2009年获吉林省高等教育省级教学成果一等奖，2007和2021年2次获得吉林省科学技术进步一等奖，2010年获国家自然科学奖二等奖. 研究领域包括高性能聚合物光学材料、聚合物纳米杂化与光功能材料、碳化聚合物点设计合成与应用等. E-mail: byangchem@jlu.edu.cn" ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22162
  中图分类号：
- 纸质出版日期：2023-01-20，
  
  网络出版日期：2022-10-08，
  
  收稿日期：2022-05-01，
  
  录用日期：2022-06-30
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刘朋远,刘崇铭,杨柏.聚合物纳米杂化高性能光功能材料[J].高分子学报,2023,54(01):37-64.

Liu Peng-yuan,Liu Chong-ming,Yang Bai.High Performance Polymer Nano-hybrid Optical Function Materials[J].ACTA POLYMERICA SINICA,2023,54(01):37-64.
刘朋远,刘崇铭,杨柏.聚合物纳米杂化高性能光功能材料[J].高分子学报,2023,54(01):37-64. DOI： 10.11777/j.issn1000-3304.2022.22162.

Liu Peng-yuan,Liu Chong-ming,Yang Bai.High Performance Polymer Nano-hybrid Optical Function Materials[J].ACTA POLYMERICA SINICA,2023,54(01):37-64. DOI： 10.11777/j.issn1000-3304.2022.22162.

摘要

近年来材料科学与技术的不断发展，对光学材料提出了高性能化和多功能化的需求，为此，研究者们结合传统有机聚合物光学材料和无机光学材料的优势，提出了备受关注的聚合物纳米粒子杂化的策略.本文首先概述了针对杂化材料透光性进行控制的杂化方法，指出杂化方法的选择很大程度上与材料性质尤其是纳米相的性质相关，而杂化方法的目的则在于实现纳米杂化材料的透光性控制，纳米杂化光功能材料实现功能的前提即为透光性. 随后，分别介绍了聚合物纳米杂化策略在高折射率材料与发光材料中的应用.对于高折射率材料，总结了提升材料折射率的不同策略.对于发光材料，总结了基于聚合物相和纳米相之间不同的相互作用而采用各种杂化方式以及相关的性能提升.接下来，讨论了聚合物纳米杂化光功能材料在光学和机械、热学、表面性能方面的调控手段和性能提升的策略.最后，提出了下一代光学杂化材料所面临的困难与挑战，以进一步推动这一领域的发展.

Abstract

In recent years

with the demands of materials science and high technologies

of optical materials with high performance and multi-functionalization are required. In order to combine the advantages of traditional organic polymer optical materials and inorganic optical materials

many researchers pay much attention to the fabrication and properties of the polymer/nanoparticle composites. In this paper

the methods for controlling the light transmittance of hybrid materials are summarized

focusing on the importance of hybrid materials' transparency

and then it is worth noting that the selection of hybrid methods is largely related to the properties of materials

especially the properties of inorganic nanoparticles. Subsequently

we introduce the applications of polymer/nanoparticle composites

including high refractive index materials and luminescent materials. For high refractive index materials

we summarized different strategies about the improvement of refractive index. For luminescent materials

various fabrication methods based on different interactions between polymer phase and inorganic nano-phase and the improvements of performance are summarized. Next

the performance improvement and adjustment of polymer/nanoparticle composites for other optical properties

mechanical

thermal and surface properties are discussed. Finally

we propose the challenges of the next generation polymer/nanoparticle composites to further push forward the development in this field.

关键词

聚合物纳米杂化材料光功能材料杂化方法高折射率材料发光材料

Keywords

Polymer nanocompositesOptical function materialsHybrid methodsHigh refractive index materialsLuminescent materials

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