高分子单链-胶体杂化纳米颗粒的合成进展与挑战

叶一兰; 孙大吟; 杨振忠

doi:10.11777/j.issn1000-3304.2022.22177

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高分子单链-胶体杂化纳米颗粒的合成进展与挑战

综述 | 更新时间：2024-10-08

- 高分子单链-胶体杂化纳米颗粒的合成进展与挑战
- Development and Challenges of the Synthesis of Polymeric Single Chain-colloid Hybrid Nanoparticles
- 高分子学报 2022年53卷第12期页码：1429-1444
- 作者机构：
  
  清华大学化学工程系北京 100084
- 作者简介：
  
  E-mail: yangzhenzhong@tsinghua.edu.cn
- 基金信息：
  
  国家重点研发计划(2021YFC2102800);国家自然科学基金(基金号 ┣51833005;51233007);52003138┫;清华大学人才引进启动项目(53330100120)
- DOI：10.11777/j.issn1000-3304.2022.22177
  中图分类号：
- 纸质出版日期：2022-12-20，
  
  网络出版日期：2022-09-09，
  
  收稿日期：2022-05-09，
  
  录用日期：2022-06-14
- 稿件说明：
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叶一兰,孙大吟,杨振忠.高分子单链-胶体杂化纳米颗粒的合成进展与挑战[J].高分子学报,2022,53(12):1429-1444.

Ye Yi-lan,Sun Da-yin,Yang Zhen-zhong.Development and Challenges of the Synthesis of Polymeric Single Chain-colloid Hybrid Nanoparticles[J].ACTA POLYMERICA SINICA,2022,53(12):1429-1444.
叶一兰,孙大吟,杨振忠.高分子单链-胶体杂化纳米颗粒的合成进展与挑战[J].高分子学报,2022,53(12):1429-1444. DOI： 10.11777/j.issn1000-3304.2022.22177.

Ye Yi-lan,Sun Da-yin,Yang Zhen-zhong.Development and Challenges of the Synthesis of Polymeric Single Chain-colloid Hybrid Nanoparticles[J].ACTA POLYMERICA SINICA,2022,53(12):1429-1444. DOI： 10.11777/j.issn1000-3304.2022.22177.

摘要

高分子单链-胶体杂化纳米颗粒是以高分子单链/单胶体为特征尺度、集成高分子单链与胶体特性的功能材料，为创制亚10 nm超精细结构与单链器件奠定物质基础. 高分子单链-胶体杂化纳米颗粒的精准构筑与规模制备是合成方法学核心，有助于深入揭示构效关系和获得新奇特性，其规模制备为新材料交叉应用提供必要条件. 本文总结了3类高分子单链-胶体杂化纳米颗粒的合成进展：(1) 高分子单链分子内交联；(2) 单体边聚合边交联；(3) 高分子单链键接纳米颗粒(单链@纳米颗粒)；展望了高分子单链-胶体杂化纳米颗粒合成方法发展趋势.

Abstract

Polymeric single chain-colloid hybrid nanoparticles are functional building blocks with the characteristic lengths of single chains. These hybrid nanoparticles integrate the characteristics of polymers and colloids and lay the foundation for the construction of sub-10 nm superstructures and single chain devices. Central to the synthetic methodology

the precise architecture and scalable fabrication of polymeric single chain-colloid hybrid nanoparticles are fundamental to the discovery of novel structure-property relationships and are essential for materials applications. In this review

we summarize recent progress in t

he synthesis of polymeric single-colloid hybrid nanoparticles

including (1) intramolecular crosslinking of polymeric single chains

(2) intramolecular cyclization through polymerization

and (3) chemical bonding between single chains and colloidal surfaces. For intramolecular crosslinking

precursor chains with diverse topologies (

e.g.

rings

bottlebrushes

and dendrimers) contribute to unique conformational and structural characteristics for single chain nanoparticles (SCNPs). More precise regulation of the precursor sequences

the tertiary structures of SCNPs

and the responsive intramolecular crosslinking are expected in future study. To address the challenge of scalable synthesis of SCNPs

electrostatic-mediated intramolecular crosslinking has been an efficient method. By utilizing electrostatic repulsion

intramolecular crosslinking can be achieved at relatively high solid contents. For intramolecular cyclization through polymerization

polymer networks constructed through cyclization of single living species is the key. This method has been underestimated; in fact

it has the potential to sequentially generate topologies like "chain-crosslinked sphere-chain"

in analogy to the polymerization of block copolymers. The scalable synthesis of SCNPs through intramolecular cyclization is still challenging since gelation occurs at low reaction conversion. Theoretical and experimental research are expected to collaborate to generate new understanding in regulating single species cyclization during polymerization and the SCNP network construction. For chemical bonding between single chains and colloidal surfaces

single chain@colloids can be achieved in a fast and scalable manner. The types of colloids should be largely expanded to cover a wide range of functional nanoparticles. In addition

precise regulation of the composition

number

and spatial arrangement of single chains at colloidal surfaces are critical to develop functional polymeric single chain-colloid hybrid nanoparticles.

关键词

单链纳米颗粒分子内交联功能胶体空间分区

Keywords

Single chain nanoparticlesIntramolecular crosslinkingFunctional colloidsSpatial compartment

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