可热塑加工的纤维素材料研究进展

尹春春; 许如梦; 张金明; 宋广杰; 张军

doi:10.11777/j.issn1000-3304.2022.22183

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可热塑加工的纤维素材料研究进展

综述 | 更新时间：2024-10-08

- 可热塑加工的纤维素材料研究进展
- Research Progress on Thermoplastic Cellulose Materials
- 高分子学报 2022年53卷第9期页码：1072-1082
- 作者机构：
  
  1.中国科学院化学研究所中国科学院工程塑料重点实验室北京 100190
  2.中国科学院大学化学科学学院北京 100049
- 作者简介：
  
  [ "张金明，男，1983年生. 中国科学院化学研究所副研究员. 2004年，河北师范大学化学系大学本科，2010年，中国科学院化学研究所博士(导师：张军研究员). 获2013 年度北京市科学技术一等奖，2018 年入选中国科学院青年促进会. 主要研究兴趣包括：纤维素功能材料、功能性环境友好材料、绿色合成与制备新方法、天然生物质资源的高值化利用." ]
  [ "张军，男，1969年生. 中国科学院化学研究所研究员，中国科学院大学岗位教授，中国科学院工程塑料重点实验室主任. 1993年，安徽师范大学化学系大学本科，1996年，哈尔滨工程大学应用化学系硕士(导师：赵书兰教授)，1999年，大连理工大学高分子材料系博士(导师：蹇锡高教授). 2014年获得国家杰出青年基金资助，2015年山东省首届泰山产业领军人才. 获2013年度北京市科学技术一等奖和2009年度北京市科学技术二等奖. 目前担任中国纤维素行业协会(CCIA)技术委员会副主任，中国科学院分子科学中心学术委员会委员，《Polymer International》(Wiley)和《高分子学报》编委. 主要研究兴趣包括：天然高分子的加工与功能化改性、纤维素化学与物理、离子液体在高分子材料中的应用、功能化聚合物复合材料、新型聚合物纤维等." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣52173292);U2004211┫
- DOI：10.11777/j.issn1000-3304.2022.22183
  中图分类号：
- 纸质出版日期：2022-09-20，
  
  网络出版日期：2022-07-14，
  
  收稿日期：2022-05-13，
  
  录用日期：2022-06-20
- 稿件说明：
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尹春春,许如梦,张金明等.可热塑加工的纤维素材料研究进展[J].高分子学报,2022,53(09):1072-1082.

Yin Chun-chun,Xu Ru-meng,Zhang Jin-ming,et al.Research Progress on Thermoplastic Cellulose Materials[J].ACTA POLYMERICA SINICA,2022,53(09):1072-1082.
尹春春,许如梦,张金明等.可热塑加工的纤维素材料研究进展[J].高分子学报,2022,53(09):1072-1082. DOI： 10.11777/j.issn1000-3304.2022.22183.

Yin Chun-chun,Xu Ru-meng,Zhang Jin-ming,et al.Research Progress on Thermoplastic Cellulose Materials[J].ACTA POLYMERICA SINICA,2022,53(09):1072-1082. DOI： 10.11777/j.issn1000-3304.2022.22183.

摘要

天然高分子纤维素由于具有强氢键网络，不能熔融，难于加工. 在苛刻加工条件或加入大量增塑剂的情况下，才可实现纤维素的热塑加工，但是所得材料存在诸多缺陷. 为此，通过化学修饰引入新的衍生化基团的内增塑方法受到了人们的广泛关注，但是内增塑方法会导致纤维素材料降解性能显著下降. 如何制备兼具热塑性和降解性的纤维素材料仍然是纤维素领域的挑战. 本文回顾了纤维素材料热塑加工领域的相关进展，分析对比了纤维素热塑加工的各种策略，希望促进构建兼具热塑性和降解性的材料，解决热封涂层、热封薄膜等轻薄材料对环境的危害，对于促进环境保护和可持续发展具有重要意义.

Abstract

Natural cellulose cannot be melted and is difficult to process due to its strong hydrogen bonding network. Thermoplastic processing of cellulose is achieved only under harsh processing conditions or with the addition of large amounts of plasticizers

but the resulting material suffers from numerous drawbacks. So the internal plasticization method of introducing new derivatized groups has received extensive attention

but the internal plasticization method will lead to a significant decrease in the degradation performance of cellulose materials. How to prepare cellulosic materials with both thermoplasticity and degradability remains a challenge. This paper summarizes the relevant progress in the field of thermoplastic processing of cellulose materials

promoting the construction of materials with both thermoplasticity and degradability to solve the environmental hazards of thin and light materials such as heat-sealing coatings and films.

关键词

纤维素热塑加工纤维素衍生物增塑剂衍生化

Keywords

CelluloseThermoplastic processingCellulose derivativesPlasticizerDerivatization

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