流变技术在高分子表征中的应用：拉伸流变测试

刘双; 黄茜; 陈全; 黄险波

doi:10.11777/j.issn1000-3304.2022.22245

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流变技术在高分子表征中的应用：拉伸流变测试

综述 (高分子表征技术专题) | 更新时间：2023-05-22

- 流变技术在高分子表征中的应用：拉伸流变测试
- Application of Extensional Rheology in Polymer Characterization
- 高分子学报 2023年54卷第2期页码：286-302
- 作者机构：
  
  1.四川大学高分子材料工程国家重点实验室高分子研究所成都 610065
  2.金发科技股份有限公司企业技术中心广州 510000
  3.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室长春 130022
- 作者简介：
  
  [ "黄茜，女，1982年生. 四川大学高分子研究所特聘研究员. 2004年本科毕业于浙江大学高分子材料与工程专业，2006年硕士毕业于丹麦技术大学(DTU)高分子工程专业. 2007~2009年在上海从事化工工艺设计工作；2010年获欧盟玛丽居里ITN项目博士奖学金资助，于2013年在DTU化工系取得博士学位；之后在DTU工作至2020年，期间进行博士后深造，后任研究员；2021年3月加入四川大学高分子研究所，并成立独立课题组；主要研究方向包括高分子熔体和溶液的拉伸流变行为与分子结构的关系、缠结高分子液体的断裂机理以及分子链取向对聚合物机械性能的影响等." ]
  [ "陈全，男，1981年8月生. 中国科学院长春应用化学研究所研究员. 大学本科和硕士毕业于上海交通大学，2011年在日本京都大学取得工学博士学位，之后赴美国宾州州立大学继续博士后深造. 于2015年回国成立独立课题组，同年当选中国流变学学会专业委员会委员；于2016年获美国TA公司授予的Distinguished Young Rheologist Award (2~3人/年)，2017年获国家自然科学基金优秀青年基金资助；2019年入选中国化学会高分子学科委员会委员，同年获得日本流变学会奖励赏(1~2人/年)；2021年获美国流变学会梅茨纳奖(Metzner Award)；目前担任美国流变学学会会刊《Journal of Rheology》，日本流变学会志《Nihon Reoroji Gakkaishi》和《高分子学报》编委. 主要研究方向为包括缔合高分子体系在内的多个复杂高分子体系的线性及非线性流变行为." ]
- 基金信息：
  
  国家自然科学基金(基金号 52173022┫资助项目‍)
- DOI：10.11777/j.issn1000-3304.2022.22245
  中图分类号：
- 纸质出版日期：2023-02-20，
  
  网络出版日期：2022-10-14，
  
  收稿日期：2022-07-15，
  
  录用日期：2022-09-09
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刘双,黄茜,陈全等.流变技术在高分子表征中的应用：拉伸流变测试[J].高分子学报,2023,54(02):286-302.

Liu Shuang,Huang Qian,Chen Quan,et al.Application of Extensional Rheology in Polymer Characterization[J].ACTA POLYMERICA SINICA,2023,54(02):286-302.
刘双,黄茜,陈全等.流变技术在高分子表征中的应用：拉伸流变测试[J].高分子学报,2023,54(02):286-302. DOI： 10.11777/j.issn1000-3304.2022.22245.

Liu Shuang,Huang Qian,Chen Quan,et al.Application of Extensional Rheology in Polymer Characterization[J].ACTA POLYMERICA SINICA,2023,54(02):286-302. DOI： 10.11777/j.issn1000-3304.2022.22245.

摘要

流变测试是与高分子加工和应用相关的重要表征手段. 尤其在纺丝、发泡、吹膜、吹塑等以拉伸流场占主导的高分子加工工艺中，高分子的拉伸流变行为对材料聚集态结构的形成起了决定性的作用，进而影响了产品最终的使役性能. 本综述第一部分介绍了拉伸流场的定义、拉伸流场的分类以及各自的特征；第二部分概述了目前商业拉伸流变仪的种类，并围绕其基本原理、测试技巧以及优缺点等内容展开讲解；第三部分介绍了拉伸流变的测试模式，并举例说明了各个模式的优势；第四部分列出了在拉伸测试中存在的常见问题，并给出了相应的解决方案和建议；最后对拉伸流变与其他表征联用技术的发展趋势进行了总结和展望.

Abstract

Knowledge of elongational properties of polymeric materials is important in different polymer processing techniques

particularly the fiber-spinning

foaming

and blow-molding techniques where the extensional flow is dominant. In this review

we summarize the methods of measuring extensional rheology for polymer melts and solutions. We start with explaining the definition and classification of different extensional flow fields in Section 1. In Section 2 we introduce different types of extensional rheometers

including Goettfert Rheotens

Münstedt Tensile Rheometer

Rheometrics Melt Extensometer

Sentmanat Extensional Rheometer

Filament Stretching Rheometer

and Capillary Breakup Extensional Rheometer. Their designing principles

operation methods

and advantages/disadvantages are described. In Section 3

we briefly introduce the different modes of extensional measurements

such as constant extensional rate

constant stress

stress relaxation and large amplitude oscillation modes. Some examples are included to elucidate the advantages of each mode. In Section 4

we give some suggestions and solutions for minimizing experimental errors and pushing the experimental limits. Finally

we highlight the importance of combining extensional rheology with other techniques in revealing more dynamic features of polymeric materials under extensional flow.

关键词

流变学拉伸流场拉伸流变仪拉伸测试

Keywords

RheologyExtensional flow fieldExtensional rheometerExtensional rheology measurement

references

Tadmor Z.; Gogos C. G. Principles of polymer processing. 2nd ed. Hoboken, JerseyNew: John Wiley & Sons 2013.

Kaneda, I. Rheology control agents for cosmetics. In: Rheology of Biological Soft Matter. Tokyo: Springer, 2017. 295-321. doi:10.1007/978-4-431-56080-7_11http://dx.doi.org/10.1007/978-4-431-56080-7_11

Eley R. R. Applied rheology and architectural coating performance. J. Coat. Technol. Res., 2019, 16(2), 263-305. doi:10.1007/s11998-019-00187-5http://dx.doi.org/10.1007/s11998-019-00187-5

刘双, 曹晓, 张嘉琪, 韩迎春, 赵欣悦, 陈全. 流变技术在高分子表征中的应用：如何正确地进行剪切流变测试. 高分子学报, 2021, 52(4): 406-422. doi:10.11777/j.issn1000-3304.2020.20230http://dx.doi.org/10.11777/j.issn1000-3304.2020.20230

Bird R. B.; Armstrong R. C.; Hassager O. Dynamics of Polymeric Liquids. Vol. 1, 2nd: Fluid Mechanics. New York: John Wiley and Sons, 1987.

Román Marín J. M.; Huusom J. K.; Alvarez N. J.; Huang Q.; Rasmussen H. K.; Bach A.; Skov A. L.; Hassager O. A control scheme for filament stretching rheometers with application to polymer melts. J. Non Newton. Fluid Mech., 2013, 194, 14-22. doi:10.1016/j.jnnfm.2012.10.007http://dx.doi.org/10.1016/j.jnnfm.2012.10.007

Watanabe H.; Matsumiya Y.; Inoue T. Dielectric and viscoelastic relaxation of highly entangled star polyisoprene: Quantitative test of tube dilation model. Macromolecules, 2002, 35(6), 2339-2357. doi:10.1021/ma011782zhttp://dx.doi.org/10.1021/ma011782z

Yoshida H.; Adachi K.; Watanabe H.; Kotaka T. Dielectric normal mode process of star-shaped polyisoprenes. Polym. J., 1989, 21(11), 863-872. doi:10.1295/polymj.21.863http://dx.doi.org/10.1295/polymj.21.863

Trouton F. T. On the coefficient of viscous traction and its relation to that of viscosity. Proc. Royal Soc. A Math. Phys. Eng. Sci., 1906, 77, 426-440. doi:10.1098/rspa.1906.0038http://dx.doi.org/10.1098/rspa.1906.0038

Huang Q. When polymer chains are highly aligned: a perspective on extensional rheology. Macromolecules, 2022, 55(3), 715-727. doi:10.1021/acs.macromol.1c02262http://dx.doi.org/10.1021/acs.macromol.1c02262

Costanzo S.; Huang Q.; Ianniruberto G.; Marrucci G.; Hassager O.; Vlassopoulos D. Shear and extensional rheology of polystyrene melts and solutions with the same number of entanglements. Macromolecules, 2016, 49(10), 3925-3935. doi:10.1021/acs.macromol.6b00409http://dx.doi.org/10.1021/acs.macromol.6b00409

Meiβner J. Dehnungsverhalten von polyäthylen-schmelzen. Rheol. Acta, 1971, 10(2), 230-242. doi:10.1007/bf02040447http://dx.doi.org/10.1007/bf02040447

Meissner J.; Hostettler J. A new elongational rheometer for polymer melts and other highly viscoelastic liquids. Rheol. Acta, 1994, 33(1), 1-21. doi:10.1007/bf00453459http://dx.doi.org/10.1007/bf00453459

Münstedt H. New universal extensional rheometer for polymer melts. measurements on a polystyrene sample. J. Rheol., 1979, 23(4), 421-436. doi:10.1122/1.549544http://dx.doi.org/10.1122/1.549544

Sentmanat M. L. Miniature universal testing platform: from extensional melt rheology to solid-state deformation behavior. Rheol Acta, 2004, 43(6), 657-669. doi:10.1007/s00397-004-0405-4http://dx.doi.org/10.1007/s00397-004-0405-4

Hodder P.; Franck A. A new tool for measuring extensional viscosity. J. Ann. Trans. Nord. Rheol. Soc, 2005, 13, 227-232.

Li B. K.; Yu W.; Cao X.; Chen Q. Horizontal extensional rheometry (HER) for low viscosity polymer melts. J. Rheol., 2020, 64(1), 177-190. doi:10.1122/1.5134532http://dx.doi.org/10.1122/1.5134532

Matta J.; Tytus R. Liquid stretching using a falling cylinder. J. Non Newton. Fluid Mech., 1990, 35(2-3), 215-229. doi:10.1016/0377-0257(90)85050-9http://dx.doi.org/10.1016/0377-0257(90)85050-9

Tirtaatmadja V.; Sridhar T. A filament stretching device for measurement of extensional viscosity. J. Rheol., 1993, 37(6), 1081-1102. doi:10.1122/1.550372http://dx.doi.org/10.1122/1.550372

Auhl D.; Hoyle D. M.; Hassell D.; Lord T. D.; Harlen O. G.; Mackley M. R.; McLeish T. C. B. Cross-slot extensional rheometry and the steady-state extensional response of long chain branched polymer melts. J. Rheol., 2011, 55(4), 875-900. doi:10.1122/1.3589972http://dx.doi.org/10.1122/1.3589972

Miller E.; Clasen C.; Rothstein J. P. The effect of step-stretch parameters on capillary breakup extensional rheology (CaBER) measurements. Rheol. Acta, 2009, 48, 625-639. doi:10.1007/s00397-009-0357-9http://dx.doi.org/10.1007/s00397-009-0357-9

Zhang D. Y.; Calabrese M. A. Temperature-controlled dripping-onto-substrate (DoS) extensional rheometry of polymer micelle solutions. Soft Matter., 2022, 18(20), 3993-4008. doi:10.1039/d2sm00377ehttp://dx.doi.org/10.1039/d2sm00377e

Wagner M. H.; Bernnat A.; Schulze V. The rheology of the rheotens test. J. Rheol., 1998, 42(4), 917-928. doi:10.1122/1.550907http://dx.doi.org/10.1122/1.550907

Münstedt H.; Schwarzl F. R. Deformation and Flow of Polymeric Materials. Berlin, Heidelberg: Springer, 2014. doi:10.1007/978-3-642-55409-4http://dx.doi.org/10.1007/978-3-642-55409-4

Aho J.; Boetker J. P.; Baldursdottir S.; Rantanen J. Rheology as a tool for evaluation of melt processability of innovative dosage forms. Int. J. Pharm., 2015, 494(2), 623-642. doi:10.1016/j.ijpharm.2015.02.009http://dx.doi.org/10.1016/j.ijpharm.2015.02.009

Huang Q.; Mangnus M.; Alvarez N. J.; Koopmans R.; Hassager O. A new look at extensional rheology of low-density polyethylene. Rheol Acta, 2016, 55(5), 343-350. doi:10.1007/s00397-016-0921-zhttp://dx.doi.org/10.1007/s00397-016-0921-z

Nielsen J. K.; Rasmussen H. K.; Hassager O. Stress relaxation of narrow molar mass distribution polystyrene following uniaxial extension. J. Rheol., 2008, 52(4), 885-899. doi:10.1122/1.2930872http://dx.doi.org/10.1122/1.2930872

Robertson B. P.; Calabrese M. A. Evaporation-controlled dripping-onto-substrate (DoS) extensional rheology of viscoelastic polymer solutions. Sci. Rep., 2022, 12, 4697. doi:10.1038/s41598-022-08448-xhttp://dx.doi.org/10.1038/s41598-022-08448-x

Huang Q.; Ahn J.; Parisi D.; Chang T.; Hassager O.; Panyukov S.; Rubinstein M.; Vlassopoulos D. Unexpected stretching of entangled ring macromolecules. Phys. Rev. Lett., 2019, 122(20), 208001. doi:10.1103/physrevlett.122.208001http://dx.doi.org/10.1103/physrevlett.122.208001

Alvarez N. J.; Marín J. M. R.; Huang Q.; Michelsen M. L.; Hassager O. Creep measurements confirm steady flow after stress maximum in extension of branched polymer melts. Phys. Rev. Lett., 2013, 110(16), 168301. doi:10.1103/physrevlett.110.168301http://dx.doi.org/10.1103/physrevlett.110.168301

Huang Q.; Agostini S.; Hengeller L.; Shivokhin M.; Alvarez N. J.; Hutchings L. R.; Hassager O. Dynamics of star polymers in fast extensional flow and stress relaxation. Macromolecules, 2016, 49(17), 6694-6699. doi:10.1021/acs.macromol.6b01348http://dx.doi.org/10.1021/acs.macromol.6b01348

Bejenariu A. G.; Rasmussen H. K.; Skov A. L.; Hassager O.; Frankaer S. M. Large amplitude oscillatory extension of soft polymeric networks. Rheol. Acta, 2010, 49(8), 807-814. doi:10.1007/s00397-010-0464-7http://dx.doi.org/10.1007/s00397-010-0464-7

Yu, K. J.; Marín, J. M. R.; Rasmussen, H. K.; Hassager, O. 3D modeling of dual wind-up extensional rheometers. J. Non. Newton. Fluid. Mech., 2010, 165(1-2), 14-23. doi:10.1016/j.jnnfm.2009.08.006http://dx.doi.org/10.1016/j.jnnfm.2009.08.006

Lentzakis H.; Vlassopoulos D.; Read D. J.; Lee H.; Chang T.; Driva P.; Hadjichristidis N. Uniaxial extensional rheology of well-characterized comb polymers. J. Rheol., 2013, 57(2), 605-625. doi:10.1122/1.4789443http://dx.doi.org/10.1122/1.4789443

Wang Y. Y.; Wang S. Q. Rupture in rapid uniaxial extension of linear entangled melts. Rheol Acta, 2010, 49(11), 1179-1185. doi:10.1007/s00397-010-0491-4http://dx.doi.org/10.1007/s00397-010-0491-4

Wingstrand S. L.; Imperiali L.; Stepanyan R.; Hassager O. Extension induced phase separation and crystallization in semidilute solutions of ultra high molecular weight polyethylene. Polymer, 2018, 136, 215-223. doi:10.1016/j.polymer.2017.12.042http://dx.doi.org/10.1016/j.polymer.2017.12.042

Zhu X. Y.; Wang S. Q. Mechanisms for different failure modes in startup uniaxial extension: tensile (rupture-like) failure and necking. J. Rheol., 2013, 57(1), 223-248. doi:10.1122/1.4764081http://dx.doi.org/10.1122/1.4764081

Hoyle D. M.; Huang Q.; Auhl D.; Hassell D.; Rasmussen H. K.; Skov A. L.; Harlen O. G.; Hassager O.; McLeish T. C. B. Transient overshoot extensional rheology of long-chain branched polyethylenes: Experimental and numerical comparisons between filament stretching and cross-slot flow. J. Rheol., 2013, 57(1), 293-313. doi:10.1122/1.4767982http://dx.doi.org/10.1122/1.4767982

Liu D.; Tian N.; Cui K. P.; Zhou W. Q.; Li X. Y.; Li L. B. Correlation between flow-induced nucleation morphologies and strain in polyethylene: from uncorrelated oriented point-nuclei, scaffold-network, and microshish to shish. Macromolecules, 2013, 46(9), 3435-3443. doi:10.1021/ma400024mhttp://dx.doi.org/10.1021/ma400024m

Huang Q.; Madsen J.; Yu L. Y.; Borger A.; Johannsen S. R.; Mortensen K.; Hassager O. Highly anisotropic glassy polystyrenes are flexible. ACS Macro. Lett., 2018, 7(9), 1126-1130. doi:10.1021/acsmacrolett.8b00485http://dx.doi.org/10.1021/acsmacrolett.8b00485

Tabuteau H.; Mora S.; Porte G.; Abkarian M.; Ligoure C. Microscopic mechanisms of the brittleness of viscoelastic fluids. Phys. Rev. Lett., 2009, 102(15), 155501. doi:10.1103/physrevlett.102.155501http://dx.doi.org/10.1103/physrevlett.102.155501

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