基于离子偶极相互作用的高分子材料

张玉成; 陈滔; 王朝

doi:10.11777/j.issn1000-3304.2022.22262

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基于离子偶极相互作用的高分子材料

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- 基于离子偶极相互作用的高分子材料
- Polymeric Materials Based on Ion-dipole Interactions
- 高分子学报 2023年54卷第3期页码：303-313
- 作者机构：
  
  清华大学化学系北京 100084
- 作者简介：
  
  [ "王朝，男，1984年生. 2007年本科毕业于清华大学化学工程系，同年进入清华大学化学系张希院士研究组攻读博士学位，2011年博士毕业，现任清华大学化学系副教授. 课题组主要研究方向为超分子电学材料、柔性电学器件和高性能储能器件，近5年在《Nature Electronics》《Nature Communications》《Angewandte Chemie》《Advanced Materials》等杂志发表多篇论文. 曾获得全国百篇优秀博士论文，求是青年科学家奖等荣誉." ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22262
  中图分类号：
- 纸质出版日期：2023-03-20，
  
  网络出版日期：2022-10-14，
  
  收稿日期：2022-08-01，
  
  录用日期：2022-09-16
扫描看全文
张玉成,陈滔,王朝.基于离子偶极相互作用的高分子材料[J].高分子学报,2023,54(03):303-313.

Zhang Yu-cheng,Chen Tao,Wang Chao.Polymeric Materials Based on Ion-dipole Interactions[J].ACTA POLYMERICA SINICA,2023,54(03):303-313.
张玉成,陈滔,王朝.基于离子偶极相互作用的高分子材料[J].高分子学报,2023,54(03):303-313. DOI： 10.11777/j.issn1000-3304.2022.22262.

Zhang Yu-cheng,Chen Tao,Wang Chao.Polymeric Materials Based on Ion-dipole Interactions[J].ACTA POLYMERICA SINICA,2023,54(03):303-313. DOI： 10.11777/j.issn1000-3304.2022.22262.

摘要

离子偶极相互作用是一种超分子相互作用，作用基元为带相反电荷的偶极和离子. 离子偶极相互作用具有许多特性，如没有方向性和饱和性、自愈性以及动态性. 该作用可以同时赋予高分子材料优异的电学性能和力学性能，进而赋予了含有该作用的高分子材料在柔性电子、储能等领域巨大的应用潜力，同时吸引了科学家对该类材料的探索与开发. 本文主要总结了我们课题组在基于离子偶极相互作用的高分子材料方面的研究工作，从一系列不同的离子偶极基元出发，构筑具有不同力学以及电学性能的高分子材料，随后介绍了它们的应用. 例如人造肌肉、人造皮肤、离子电致发光、触摸板等，可用于可穿戴设备以及人机交互界面.

Abstract

Ion-dipole interactions are supramolecular interactions in which oppositely charged dipoles and ions act as the substrate. The ion-dipole interaction has many properties

such as non-directional

non-saturation

self-healing and dynamic properties

which can give polymers excellent electrical and mechanical properties at the same time. These properties have given polymeric materials containing these interactions great potential for applications in flexible electronics and battery energy storage

and have attracted scientists to explore and develop these materials. The aim of this paper is to summarize the features and advantages of ionic-dipole interactions

while indicating the shortcomings in the field and attracting more scientists to the relevant research. We started from the types of materials containing ion-dipole interactions

introduces the possible acting substrates that can be used to build the materials

and explores how the different materials behave in terms of mechanical and electrical properties. It also combines our group's work on polymeric materials based on ionic dipole interactions

and concludes with a description of suitable application scenarios for such materials. For example

we discovered and exploited the ion-dipole interactions between fluorine-containing groups and imidazole cations to construct a self-healing ionic conductor. Applications include artificial muscles

artificial skin

ionic electroluminescence

and touch panels for wearable devices and human-machine interaction interfaces. Although there are currently a wide range of application scenarios for polymeric materials based on ion-dipole interactions

the development of related materials needs to be supported by fundamental science. For example

the regulation of electrical conductivity and mechanical properties can only be attempted by extensive experiments and not by more rational design.

关键词

非共价键作用超分子化学离子偶极相互作用

Keywords

Noncovalent interactionSupramolecular chemistryIon-dipole interaction

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