室温非均相可逆失活自由基聚合

林冬妮; 张力; 谭剑波

doi:10.11777/j.issn1000-3304.2022.22442

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室温非均相可逆失活自由基聚合

专论 | 更新时间：2023-05-31

- 室温非均相可逆失活自由基聚合
- Room-temperature Heterogeneous Reversible Deactivation Radical Polymerization
- 高分子学报 2023年54卷第6期页码：761-777
- 作者机构：
  
  广东工业大学高分子材料与工程系广东省功能软凝聚态物质重点实验室广州 510006
- 作者简介：
  
  [ "张力，女，1967年生. 广东工业大学高分子材料与工程系教授. 1988年获得哈尔滨工业大学学士学位，1991年获得黑龙江省科学院石油化学研究所硕士学位，1994年获得中山大学博士学位，1994~1996年在华南理工大学从事博士后研究工作，1996~2008年加入华南师范大学工作，2008年至今在广东工业大学高分子材料与工程系工作. 主要从事“活性”/可控自由基聚合，功能高分子纳米粒子和聚合物自组装等方面的研究内容. E-mail: lizhang@gdut.edu.cn" ]
  [ "谭剑波，男，1987年生. 广东工业大学高分子材料与工程系教授，博士生导师. 2009和2014年分别在中山大学获得学士和博士学位，2012~2014年在多伦多大学Mitchell Winnik课题组联合培养，2015年3月入职广东工业大学开展独立研究工作. 2017年入选广东省青年珠江学者，2021年获得广东省自然科学基金杰出青年项目资助，2022年获得国家自然科学基金优秀青年科学基金资助. 主要研究方向为高分子合成方法学和功能聚合物粒子. tanjianbo@gdut.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(基金号52222301;22171055;21971047)
- DOI：10.11777/j.issn1000-3304.2022.22442
  中图分类号：
- 纸质出版日期：2023-06-20，
  
  网络出版日期：2023-02-17，
  
  收稿日期：2022-12-24，
  
  录用日期：2023-01-18
扫描看全文
林冬妮,张力,谭剑波.室温非均相可逆失活自由基聚合[J].高分子学报,2023,54(06):761-777.

Lin Dong-ni,Zhang Li,Tan Jian-bo.Room-temperature Heterogeneous Reversible Deactivation Radical Polymerization[J].ACTA POLYMERICA SINICA,2023,54(06):761-777.
林冬妮,张力,谭剑波.室温非均相可逆失活自由基聚合[J].高分子学报,2023,54(06):761-777. DOI： 10.11777/j.issn1000-3304.2022.22442.

Lin Dong-ni,Zhang Li,Tan Jian-bo.Room-temperature Heterogeneous Reversible Deactivation Radical Polymerization[J].ACTA POLYMERICA SINICA,2023,54(06):761-777. DOI： 10.11777/j.issn1000-3304.2022.22442.

摘要

非均相可逆失活自由基聚合(RDRP)是高效可控制备结构与功能明确聚合物纳米材料的重要方法. 在室温下进行非均相RDRP从聚合技术层面上是一个很小的调整，但这为功能聚合物的可控合成、新非均相RDRP方法的发展及非均相RDRP的机理研究带来了巨大的机遇. 在本文中，我们将综述室温非均相RDRP的最新研究进展，这些研究进展难以通过传统的热引发非均相RDRP实现，包括聚合速率调控、耐氧非均相RDRP体系、新非均相RDRP方法的发展、聚合物纳米材料的形貌调控和功能聚合物纳米材料的合成，最后指出了室温非均相RDRP领域目前存在的关键问题和重要挑战.

Abstract

Reversible deactivation radical polymerization (RDRP) has become one of the most common methods for the synthesis of well-defined polymers with predetermined molar mass

narrow molar mass distribution

and precise end-group functionality. Depending on the solubility of monomer/polymer in the polymerization system

RDRP can be performed

via

either homogeneous polymerization or heterogeneous polymerization. Compared with homogeneous RDRP

heterogeneous RDRP exhibits significant advantages

such as low viscosity

high polymerization rate

and nanoconfinement effect. More importantly

heterogeneous RDRP enables efficient preparation of well-defined polymer nanomaterials that find applications in many areas. Currently

almost all heterogeneous RDRPs are conducted

via

thermal initiation at high temperatures (

e.g

. 70 ℃)

which is not beneficial for the preparation of many functional polymer nanomaterials. Performing heterogeneous RDRP at room temperature seems to be a minor change in the polymerization process

but this can lead to extensive opportunities for controlled synthesis of functional materials

the development of new heterogeneous RDRP methods

and mechanistic insights into heterogeneous RDRP. Many room-temperature initiations have been successfully introduced into heterogeneous RDRP

such as photoinitiation

enzyme initiation

redox initiation

and sonochemically initiation. In this feature article

we will summarize some recent developments of room-temperature heterogeneous RDRP that are difficult to be achieved

via

traditional heterogeneous RDRP

including the control of polymerization rate using room-temperature initiations

oxygen-tolerant heterogeneous RDRP

via

either enzymatic deoxygenation or photo-induced deoxygenation

the development of new heterogeneous RDRP methods (

e.g

. Z-RAFT mediated dispersion polymerization

wavelength-selective photo-induced heterogeneous RDRP)

morphological control of polymer nanomaterials

and the synthesis of functional polymer nanomaterials (bio-related polymer nanomaterials

epoxy-functionalized polymer nanomaterials

and thermo-responsive polymer nanomarterials). Finally

current challenges and further opportunities of room-temperature heterogeneous RDRP are discussed.

关键词

可逆失活自由基聚合非均相聚合室温聚合物纳米材料

Keywords

Reversible deactivation radical polymerization (RDRP)Heterogeneous polymerizationRoom-temperaturePolymer nanomaterials

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