高分子材料的生物降解性能表征

叶焱; 孟祥泽; 唐国烁; 金广轩; 杨睿; 谢续明

doi:10.11777/j.issn1000-3304.2023.23111

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高分子材料的生物降解性能表征

综述 (高分子表征技术专题) | 更新时间：2023-08-21

- 高分子材料的生物降解性能表征
- Characterization Techniques of Polymer Biodegradation Properties
- 高分子学报 2023年54卷第9期页码：1363-1384
- 作者机构：
  
  1.清华大学，化学工程系，北京 100084
  2.清华大学，探微书院，北京 100084
- 作者简介：
  
  [ "杨睿，女，1972年生，清华大学化工系教授、博士生导师. 1994、1996和2005年分别在清华大学化工系获得学士、硕士和博士学位，1996年至今在清华大学化工系任教. 主要研究方向为高分子材料的老化机理、稳定性评价和寿命预测." ]
- 基金信息：
  
  国家重点研发计划(2021YFC2103603;2021YFD1700700)
- DOI：10.11777/j.issn1000-3304.2023.23111
  中图分类号：
- 纸质出版日期：2023-09-20，
  
  网络出版日期：2023-07-19，
  
  收稿日期：2023-04-23，
  
  录用日期：2023-06-05
扫描看全文
叶焱,孟祥泽,唐国烁等.高分子材料的生物降解性能表征[J].高分子学报,2023,54(09):1363-1384.

Ye Yan,Meng Xiang-ze,Tang Guo-shuo,et al.Characterization Techniques of Polymer Biodegradation Properties[J].ACTA POLYMERICA SINICA,2023,54(09):1363-1384.
叶焱,孟祥泽,唐国烁等.高分子材料的生物降解性能表征[J].高分子学报,2023,54(09):1363-1384. DOI： 10.11777/j.issn1000-3304.2023.23111.

Ye Yan,Meng Xiang-ze,Tang Guo-shuo,et al.Characterization Techniques of Polymer Biodegradation Properties[J].ACTA POLYMERICA SINICA,2023,54(09):1363-1384. DOI： 10.11777/j.issn1000-3304.2023.23111.

摘要

生物降解能够使高分子材料回归自然界物质循环，被认为是解决塑料污染的一大重要途径. 高分子材料的生物降解性能表征对相关材料开发、改性和产业应用十分重要. 本文针对高分子材料的需氧生物降解，从降解产物和降解残留材料两个方面介绍常用表征方法. 降解产物的表征主要从CO

生成量、O

消耗量和小分子产物三方面开展，降解残留材料的表征围绕其组成结构变化和性能变化. 介绍了各表征方法的简单原理和典型案例，并对未来发展进行了展望.

Abstract

Biodegradation is an effective route for polymer materials to go back into the natural circumstance

and biodegradable polymers is regarded as an important solution to the plastic pollution problem. Characterization of biodegradability is therefore crucial for the development

modification

and application of degradable polymer materials. This review aims at the aerobic biodegradation of polymer materials and introduces typical characterization techniques

focusing on two aspects: degradation products and materials after degradation. For degradation products

the characterization are mainly carried out from three aspects: CO

generation

consumption

and determination of small molecular degradation products. In addition

the characterization of biomass can indicate the impacts of polymers on organisms and the environment during the biodegradation process. The characterization of materials after degradation involves composition changes

structure changes

and service performance changes such as weight loss and mechanical property deterioration. There may be a heterogeneous distribution of degradation in polymer materials. One reason is that the enzymatic decomposition starts from the surface and gradually develops into the matrix. In this paper

the principles of various characterization methods are introduced and typical examples are supplied. In the future

rapid biodegradation evaluation method is expected and comprehensive analysis of various characterization results is used to help the precise design and preparation of controllable biodegradability of polymers.

关键词

高分子材料生物降解降解产物材料表征性能变化

Keywords

Polymer materialBiodegradationDegradation productMaterial characterizationPerformance change

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