四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性

窦青青; 李子成; 满涛; 许贝贝

doi:10.11777/j.issn1000-3304.2023.23240

您当前的位置：

首页 >

文章列表页 >

四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性

研究论文 | 更新时间：2024-02-08

- 四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性
- Opto-Electric-Magnetic Coupling Properties of Tetrathiafulvalene- Pyromelliticdiimide Organic Cocrystals
- 高分子学报 2024年55卷第3期页码：320-327
- 作者机构：
  
  1.包头稀土研究院白云鄂博稀土资源研究与综合利用全国重点实验室包头 014030
  2.浙江大学光电科学与工程学院极端光学技术与仪器全国重点实验室杭州 310027
- 作者简介：
  
  E-mail: bbxu2019@zju.edu.cn
- 基金信息：
  
  浙江省自然基金重大项目(LD22E010001);浙江省杰出青年基金(基金号 LR23E030002)
- DOI：10.11777/j.issn1000-3304.2023.23240
  中图分类号：
- 纸质出版日期：2024-03-20，
  
  网络出版日期：2024-01-16，
  
  收稿日期：2023-10-01，
  
  录用日期：2023-11-15
- 稿件说明：
移动端阅览
窦青青, 李子成, 满涛, 许贝贝. 四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性. 高分子学报, 2024, 55(3), 320-327

Dou, Q. Q.; Li, Z. C.; Man, T.; Xu, B. B. Opto-electric-magnetic coupling properties of tetrathiafulvalene-pyromelliticdiimide organic cocrystals. Acta Polymerica Sinica, 2024, 55(3), 320-327
窦青青, 李子成, 满涛, 许贝贝. 四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性. 高分子学报, 2024, 55(3), 320-327 DOI： 10.11777/j.issn1000-3304.2023.23240.

Dou, Q. Q.; Li, Z. C.; Man, T.; Xu, B. B. Opto-electric-magnetic coupling properties of tetrathiafulvalene-pyromelliticdiimide organic cocrystals. Acta Polymerica Sinica, 2024, 55(3), 320-327 DOI： 10.11777/j.issn1000-3304.2023.23240.

摘要

利用四硫富瓦烯(TTF)给体和苯均四酸二亚酰胺(PMDI)受体，发展了一种新型有机共晶TTF-PMDI. 该共晶给受体分子间具有强电荷转移作用，并表现出铁电性和磁电耦合效应，包括磁电容效应和磁场诱导铁电极化的变化，光刺激下，该共晶还表现出电容和铁电极化变化，详细讨论了这些效应产生的机制，并探讨了三线态电荷转移态对电容和铁电极化变化的影响. 本文的研究结果将促进多功能共晶的材料和器件的发展，为多场感知领域的应用提供了一种新的可能.

Abstract

The rapid development of intelligent robots raises increasing demand of multifunctional sensing materials and devices. However

most of currently developed materials only have two-field coupling effect. They lack multi-modal sensing ability. This article proposes a new strategy to develop multi-field coupling materials through the control of inter-molecular charge transfer interaction. Here

centimeter long organic co-crystal tetrathiafulvalene (TTF)-pyromelliticdiimide (PMDI) with opto-electric-magnetic coupling effect is developed by saturated precipitation method. It has room-temperature ferroelectric effect with a remnant polarization of 4 µC/cm

. It also shows room-temperature magneto-electric coupling effect

including magnetic field-induced capacitance change of 1.5×10

-3

%/Oe and ferroelectric polarization change with magneto-electric coupling coefficient of 1.18 nC/(cm

·Oe). Moreover

this effect can be controlled by light stimuli. It is demonstrated that the relatively weaker inter-molecular charge transfer interaction than that of intra-molecular interaction makes the co-crystal more vulnerable to external stimuli than single component crystal. In addition

the intersystem crossing between singlet and triplet charge transfer state also induces magnetic-field effect and influences the electric dipoles related capacitance and polarization. All these factors lead to the generation of multiple freedom to tune the opto-electric-magnetic properties of the co-crystal. The results of this study will promote the development of multifunctional cocrystal materials and devices

and promote their applications for multifunctional sensing.

关键词

有机共晶光电磁耦合多场传感

Keywords

Organic cocrystalOpto-electric-magneto couplingMulti-field sensing

references

Fiebig M.; Lottermoser T.; Meier D.; Trassin M. The evolution of multiferroics. Nat. Rev. Mater., 2016, 1, 16046. doi:10.1038/natrevmats.2016.46http://dx.doi.org/10.1038/natrevmats.2016.46

Ryu J.; Kang J. E.; Zhou Y.; Choi S. Y.; Yoon W. H.; Park D. S.; Choi J. J.; Hahn B. D.; Ahn C. W.; Kim J. W.; Kim Y. D.; Priya S.; Lee S. Y.; Jeong S.; Jeong D. Y. Ubiquitous magneto-mechano-electric generator. Energy Environ. Sci., 2015, 8(8), 2402-2408. doi:10.1039/c5ee00414dhttp://dx.doi.org/10.1039/c5ee00414d

Zhu Q. X.; Yang M. M.; Zheng M.; Zheng R. K.; Guo L. J.; Wang Y.; Zhang J. X.; Li X. M.; Luo H. S.; Li X. G. Ultrahigh tunability of room temperature electronic transport and ferromagnetism in dilute magnetic semiconductor and PMN-PT single-crystal-based field effect transistors via electric charge mediation. Adv. Funct. Mater., 2015, 25(7), 1111-1119. doi:10.1002/adfm.201403763http://dx.doi.org/10.1002/adfm.201403763

Annapureddy V.; Palneedi H.; Yoon W. H.; Park D. S.; Choi J. J.; Hahn B. D.; Ahn C. W.; Kim J. W.; Jeong D. Y.; Ryu J. A pT/√Hz sensitivity ac magnetic field sensor based on magnetoelectric composites using low-loss piezoelectric single crystals. Sens. Actuat. A, 2017, 260, 206-211. doi:10.1016/j.sna.2017.04.017http://dx.doi.org/10.1016/j.sna.2017.04.017

Chen A. T.; Wen Y.; Fang B.; Zhao Y. L.; Zhang Q.; Chang Y. S.; Li P. S.; Wu H.; Huang H. L.; Lu Y. L.; Zeng Z. M.; Cai J. W.; Han X. F.; Wu T.; Zhang X. X.; Zhao Y. G. Giant nonvolatile manipulation of magnetoresistance in magnetic tunnel junctions by electric fields via magnetoelectric coupling. Nat. Commun., 2019, 10, 243. doi:10.1038/s41467-018-08061-5http://dx.doi.org/10.1038/s41467-018-08061-5

Kosub T.; Kopte M.; Hühne R.; Appel P.; Shields B.; Maletinsky P.; Hübner R.; Liedke M. O.; Fassbender J.; Schmidt O. G.; Makarov D. Purely antiferromagnetic magnetoelectric random access memory. Nat. Commun., 2017, 8, 13985. doi:10.1038/ncomms13985http://dx.doi.org/10.1038/ncomms13985

Yan Y. K.; Geng L. D.; Tan Y. H.; Ma J. H.; Zhang L. J.; Sanghadasa M.; Ngo K.; Ghosh A. W.; Wang Y. U.; Priya S. Colossal tunability in high frequency magnetoelectric voltage tunable inductors. Nat. Commun., 2018, 9, 4998. doi:10.1038/s41467-018-07371-yhttp://dx.doi.org/10.1038/s41467-018-07371-y

Fetisov Y. K.; Srinivasan G. Electric field tuning characteristics of a ferrite-piezoelectric microwave resonator. Appl. Phys. Lett., 2006, 88(14), 143503. doi:10.1063/1.2191950http://dx.doi.org/10.1063/1.2191950

Cheng Y. X.; Peng B.; Hu Z. Q.; Zhou Z. Y.; Liu M. Recent development and status of magnetoelectric materials and devices. Phys. Lett. A, 2018, 382(41), 3018-3025. doi:10.1016/j.physleta.2018.07.014http://dx.doi.org/10.1016/j.physleta.2018.07.014

Nan T. X.; Lin H.; Gao Y.; Matyushov A.; Yu G. L.; Chen H. H.; Sun N.; Wei S. J.; Wang Z. G.; Li M. H.; Wang X. J.; Belkessam A.; Guo R. D.; Chen B.; Zhou J.; Qian Z. Y.; Hui Y.; Rinaldi M.; McConney M. E.; Howe B. M.; Hu Z. Q.; Jones J. G.; Brown G. J.; Sun N. X. Acoustically actuated ultra-compact NEMS magnetoelectric antennas. Nat. Commun., 2017, 8(1), 296. doi:10.1038/s41467-017-00343-8http://dx.doi.org/10.1038/s41467-017-00343-8

Shen J. X.; Shang D. S.; Chai Y. S.; Wang S. G.; Shen B. G.; Sun Y. Mimicking synaptic plasticity and neural network using memtranstors. Adv. Mater., 2018, 30(12), 1706717. doi:10.1002/adma.201706717http://dx.doi.org/10.1002/adma.201706717

Yue K.; Guduru R.; Hong J.; Liang P.; Nair M.; Khizroev S. Magneto-electric nano-particles for non-invasive brain stimulation. PLoS One, 2012, 7(9), e44040. doi:10.1371/journal.pone.0044040http://dx.doi.org/10.1371/journal.pone.0044040

Wu Y. Z.; Liu Y. W.; Zhou Y. L.; Man Q. K.; Hu C.; Asghar W.; Li F. L.; Yu Z.; Shang J. E.; Liu G.; Liao M. Y.; Li R. W. A skin-inspired tactile sensor for smart prosthetics. Sci. Robot., 2018, 3(22), eaat0429. doi:10.1126/scirobotics.aat0429http://dx.doi.org/10.1126/scirobotics.aat0429

Huang Y. J.; Wang Z. R.; Chen Z.; Zhang Q. C. Organic cocrystals: beyond electrical conductivities and field-effect transistors (FETs). Angew. Chem. Int. Ed., 2019, 58(29), 9696-9711. doi:10.1002/anie.201900501http://dx.doi.org/10.1002/anie.201900501

Goetz K. P.; Vermeulen D.; Payne M. E.; Kloc C.; McNeil L. E.; Jurchescu O. D. Charge-transfer complexes: new perspectives on an old class of compounds. J. Mater. Chem. C, 2014, 2(17), 3065-3076. doi:10.1039/c3tc32062fhttp://dx.doi.org/10.1039/c3tc32062f

Xu B. B.; Chakraborty H.; Yadav V. K.; Zhang Z. L.; Klein M. L.; Ren S. Q. Tunable two-dimensional interfacial coupling in molecular heterostructures. Nat. Commun., 2017, 8, 312. doi:10.1038/s41467-017-00390-1http://dx.doi.org/10.1038/s41467-017-00390-1

Xu B. B.; Li H. S.; Hall A.; Gao W. X.; Gong M. G.; Yuan G. L.; Grossman J.; Ren S. Q. All-polymeric control of nanoferronics. Sci. Adv., 2015, 1(11), e1501264. doi:10.1126/sciadv.1501264http://dx.doi.org/10.1126/sciadv.1501264

Lunkenheimer P.; Müller J.; Krohns S.; Schrettle F.; Loidl A.; Hartmann B.; Rommel R.; de Souza M.; Hotta C.; Schlueter J. A.; Lang M. Multiferroicity in an organic charge-transfer salt that is suggestive of electric-dipole-driven magnetism. Nat. Mater., 2012, 11(9), 755-758. doi:10.1038/nmat3400http://dx.doi.org/10.1038/nmat3400

Xu B. B.; Chakraborty H.; Remsing R. C.; Klein M. L.; Ren S. Q. A free-standing molecular spin-charge converter for ubiquitous magnetic-energy harvesting and sensing. Adv. Mater., 2017, 29(8), 1605150. doi:10.1002/adma.201605150http://dx.doi.org/10.1002/adma.201605150

Wei M. M.; Song K. P.; Yang Y. Y.; Huang Q. K.; Tian Y. F.; Hao X. T.; Qin W. Organic multiferroic magnetoelastic complexes. Adv. Mater., 2020, 32(40), 2003293. doi:10.1002/adma.202003293http://dx.doi.org/10.1002/adma.202003293

Suda M.; Kawasugi Y.; Minari T.; Tsukagoshi K.; Kato R.; Yamamoto H. M. Strain-tunable superconducting field-effect transistor with an organic strongly-correlated electron system. Adv. Mater., 2014, 26(21), 3490-3495. doi:10.1002/adma.201305797http://dx.doi.org/10.1002/adma.201305797

Xu B. B.; Li H. S.; Li H. Q.; Wilson A. J.; Zhang L.; Chen K.; Willets K. A.; Ren F.; Grossman J. C.; Ren S. Q. Chemically driven interfacial coupling in charge-transfer mediated functional superstructures. Nano Lett., 2016, 16(4), 2851-2859. doi:10.1021/acs.nanolett.6b00712http://dx.doi.org/10.1021/acs.nanolett.6b00712

Qin Z. S.; Gao C.; Dong H. L.; Hu W. P. Organic semiconductor single-crystal light-emitting transistors. Adv. Opt. Mater., 2023, 11(13), 2201644. doi:10.1002/adom.202201644http://dx.doi.org/10.1002/adom.202201644

Chen S. A.; Zeng X. C. Design of ferroelectric organic molecular crystals with ultrahigh polarization. J. Am. Chem. Soc., 2014, 136(17), 6428-6436. doi:10.1021/ja5017393http://dx.doi.org/10.1021/ja5017393

Qin W.; Jasion D.; Chen X. M.; Wuttig M.; Ren S. Q. Charge-transfer magnetoelectrics of polymeric multiferroics. ACS Nano, 2014, 8(4), 3671-3677. doi:10.1021/nn500323jhttp://dx.doi.org/10.1021/nn500323j

Xu B. B.; Li Z.; Chang S. Q.; Li C. N.; Ren S. Q. Crystallization-mediated magnetoelectric response in two-dimensional molecular charge transfer crystals. ACS Appl. Electron. Mater., 2019, 1(9), 1735-1739. doi:10.1021/acsaelm.9b00337http://dx.doi.org/10.1021/acsaelm.9b00337

Xu B. B.; Luo Z. P.; Wilson A. J.; Chen K.; Gao W. X.; Yuan G. L.; Chopra H. D.; Chen X.; Willets K. A.; Dauter Z.; Ren S. Q. Multifunctional charge-transfer single crystals through supramolecular assembly. Adv. Mater., 2016, 28(26), 5322-5329. doi:10.1002/adma.201600383http://dx.doi.org/10.1002/adma.201600383

Hu B.; Yan L. A.; Shao M. Magnetic-field effects in organic semiconducting materials and devices. Adv. Mater., 2009, 21(14-15), 1500-1516. doi:10.1002/adma.200802386http://dx.doi.org/10.1002/adma.200802386

He L.; Li M. X.; Urbas A.; Hu B. Optically tunable magneto-capacitance phenomenon in organic semiconducting materials developed by electrical polarization of intermolecular charge-transfer states. Adv. Mater., 2014, 26(23), 3956-3961. doi:10.1002/adma.201305965http://dx.doi.org/10.1002/adma.201305965

浏览量

297

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据