光激发诱导组装策略在大分子组装中的应用

刘谋为; 朱亮亮

doi:10.11777/j.issn1000-3304.2023.23295

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光激发诱导组装策略在大分子组装中的应用

专论 | 更新时间：2024-09-25

- 光激发诱导组装策略在大分子组装中的应用
- Application of Photoexcitation-induced Assembly Strategies to Macromolecular Assembly
- 高分子学报 2024年55卷第7期页码：802-813
- 作者机构：
  
  聚合物分子工程国家重点实验室复旦大学高分子科学系上海 200438
- 作者简介：
  
  [ "朱亮亮，男，1982年生. 复旦大学高分子科学系研究员，博士生导师. 2005年获得浙江大学学士学位，2011年获得华东理工大学博士学位. 2011~2015年分别在新加坡南洋理工大学和美国哥伦比亚大学从事博士后研究工作. 2015年5月入职复旦大学开展独立研究工作. 入选国家高层次青年人才计划资助. 主要研究方向为有机高分子光功能材料." ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23295
  中图分类号：
- 纸质出版日期：2024-07-20，
  
  网络出版日期：2024-04-07，
  
  收稿日期：2023-12-25，
  
  录用日期：2024-02-06
- 稿件说明：
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刘谋为, 朱亮亮. 光激发诱导组装策略在大分子组装中的应用. 高分子学报, 2024, 55(7), 802-813

Liu, M. W.; Zhu, L. L. Application of photoex-induced assembly strategies to macromolecular assembly. Acta Polymerica Sinica, 2024, 55(7), 802-813
刘谋为, 朱亮亮. 光激发诱导组装策略在大分子组装中的应用. 高分子学报, 2024, 55(7), 802-813 DOI： 10.11777/j.issn1000-3304.2023.23295.

Liu, M. W.; Zhu, L. L. Application of photoex-induced assembly strategies to macromolecular assembly. Acta Polymerica Sinica, 2024, 55(7), 802-813 DOI： 10.11777/j.issn1000-3304.2023.23295.

摘要

在分子组装领域，光控自组装是调节分子有序性、多尺度结构和光电特性的一种智能策略. 然而，传统光控自组装是通过光化学反应诱导分子结构变化的光化学过程来实施. 由于副反应的存在和有限的转化率，光控自组装形成的纳米结构和形态往往难以预测. 相反，仅利用分子从基态到激发态的构象变化的光物理过程实现激发态组装则能够避免以上缺点，并能够进一步促进整个材料体系的协同组装或相变. 本文着重探讨了以多硫芳烃为基元的光激发诱导组装(photoexcitation-induced assembly

PEIA)策略. 多硫芳烃能够产生从基态到激发态的重大分子构象转变，这种转变有利于形成分子间相互作用，进而推动分子运动、聚集和组装. 系统介绍在分子水平上探索多硫芳烃的PEIA进展，进一步证明多硫芳烃的PEIA可以协同驱动聚合物体系中的分子运动和相变，并对PEIA未来发展所面临的关键问题和重要挑战进行了展望.

Abstract

In the field of molecular assembly

photocontrolled self-assembly is an intelligent strategy to regulate molecular ordering

multiscale structure and optoelectronic properties. However

conventional photocontrolled self-assembly is implemented through a photochemical process in which photochemical reactions induce structural changes in molecules. The nanostructures and morphologies formed by photocontrolled self-assembly are often unpredictable due to the presence of side reactions and limited conversion rates. On the contrary

assembly by photophysical processes that only utilize the conformational changes of molecules from the ground state to the excited state can avoid the above drawbacks and can further promote the synergistic assembly or phase transition of the whole material system. In this paper

we focus on the photoexcitation-induced assembly (PEIA) strategy using polysulfide aromatic hydrocarbons (PAHs) as the building blocks. PAHs are capable of generating significant molecular conformational transitions from the ground state to the excited state

which are favorable for the formation of intermolecular interactions that drive molecular motions

aggregation

and assembly. In this paper

we systematically introduce the progress of exploring PEIA of polysulfide aromatics at the molecular level

further demonstrate that PEIA of polysulfide aromatics can synergistically drive molecular motions and phase transitions in polymer systems

and provide an outlook on the key issues and important challenges for the future development of PEIA.

关键词

激发态构象多硫芳烃光诱导自组装磷光

Keywords

Excited-state conformationPersulfurated arenesPhotoinduced self-assemblyPhosphorescence

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