有机电化学晶体管分子材料与功能器件研究进展

项兰义; 张凤娇; 狄重安

doi:10.11777/j.issn1000-3304.2024.24066

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有机电化学晶体管分子材料与功能器件研究进展

综述 | 更新时间：2024-11-26

- 有机电化学晶体管分子材料与功能器件研究进展
- Advancements in Semiconductor Materials and Functional Devices of Organic Electrochemical Transistors
- 高分子学报 2024年55卷第9期页码：1111-1133
- 作者机构：
  
  1.中国科学院大学化学科学学院北京 100049
  2.中国科学院有机固体重点实验室中国科学院化学研究所北京 100190
- 作者简介：
  
  [ "张凤娇，女，1989年生. 中国科学院大学化学科学学院副教授，博士生导师. 2010年于福州大学获得学士学位，2015年于中国科学院化学研究所获博士学位，后赴美国伊利诺伊大学香槟分校化学与生物工程学院从事博士后工作，于2019年1月入职中国科学院大学化学科学学院. 曾获得唐敖庆化学奖(2014年)、中国科学院BHPB (2013年)和朱李月华奖学金(2013年)，作为博士生代表参加第65届林岛诺贝尔奖获得者大会等. 2022年获中国分析测试协会科学技术奖一等奖. 现担任SmartMat和Chin. Chem. Lett.期刊青年编委. 主要研究方向为新型传感功能器件设计、开发与应用研究." ]
  [ "狄重安，男，1981年生. 中国科学院化学研究所研究员，博士生导师. 2003年于曲阜师范大学获得学士学位，2008年于中国科学院化学研究所获得博士学位，后入职中国科学院化学研究所；先后在剑桥大学(2011年)和斯坦福大学(2013年)从事访问学者研究. 曾获中国化学会青年化学奖(2011年度)、中国分析测试协会科学技术奖一等奖(2022年度)和中国化学会-英国皇家化学会青年化学奖(2022年度). 先后于2014年和2018年获得基金委优秀青年基金和中组部青年拔尖项目资助，2021年获得国家杰出青年基金资助；入选2022爱思唯尔“中国高被引学者”；担任Chin. Chem. Lett.副主编，Adv. Mater. Tech.和J. Energ. Chem.期刊的顾问编委，中国化学会高级会员，International Thin-film Transistor Conference (ITC)技术委员，中国化学会有机固体专业委员会委员. 研究领域为有机半导体材料与器件." ]
- 基金信息：
  
  中国科学院先导专项(XDB0520200);中央高校基本科研业务费专项资金(E2E40305X2);中国博士后科学基金(基金号 119103S395)
- DOI：10.11777/j.issn1000-3304.2024.24066
  中图分类号：
- 纸质出版日期：2024-09-20，
  
  网络出版日期：2024-06-06，
  
  收稿日期：2024-03-02，
  
  录用日期：2024-04-18
- 稿件说明：
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项兰义, 张凤娇, 狄重安. 有机电化学晶体管分子材料与功能器件研究进展. 高分子学报, 2024, 55(9), 1111-1133

Xiang, L. Y.; Zhang, F. J.; Di, C. A. Advancements in semiconductor materials and functional devices of organic electrochemical transistors. Acta Polymerica Sinica, 2024, 55(9), 1111-1133
项兰义, 张凤娇, 狄重安. 有机电化学晶体管分子材料与功能器件研究进展. 高分子学报, 2024, 55(9), 1111-1133 DOI： 10.11777/j.issn1000-3304.2024.24066.

Xiang, L. Y.; Zhang, F. J.; Di, C. A. Advancements in semiconductor materials and functional devices of organic electrochemical transistors. Acta Polymerica Sinica, 2024, 55(9), 1111-1133 DOI： 10.11777/j.issn1000-3304.2024.24066.

摘要

有机电化学晶体管通过离子-电子耦合调控共轭分子的电子结构和导电能力，被认为是下一代柔性智能电子的理想载体. 本文结合电化学掺杂工作原理，总结了有机电化学晶体管分子材料在离子-电子耦合性能以及在可拉伸性、机械顺应性和生物黏性等力学特征的研究进展，并介绍了器件在互补逻辑电路、生物传感和仿生神经突触等方面的功能应用. 此外，从有机共轭分子设计、界面修饰、离子动力学调控和器件结构开发等方面入手，分析了提升器件性能和推动器件多功能化的研究策略，展示了有机电化学晶体管在智能电子方面的重要研究价值. 最后，详细探讨了有机电化学晶体管在面向传感-适应-反馈-处理的一体化智能感知器件和低成本商业化制备等方面的关键挑战与机遇.

Abstract

Organic electrochemical transistors play a crucial role in modulating the electronic structure and conductivity of conjugated films through ion-electron coupling

making them highly promising for the advancement of flexible smart electronics. This article provides a comprehensive overview of the organic electrochemical transistors by integrating electrochemical doping principle. It discusses the recent advancements in ion-electron coupling performance and mechanical characteristics such as stretchability

mechanical conformability

and bioviscosity. In addition

it summarizes the multifunctional applications of the organic electrochemical transistors

including their role in complementary logic circuits

biosensing

and bionic neural synapses. Furthermore

special emphasis is placed on research strategies

aimed at enhancing device performance and enabling multifunctionality through approaches like organic conjugated molecule design

interface modification

ion dynamics control

and device structure optimization

underscoring the versatility of OECTs in smart electronics. Finally

the key challenges and opportunities of organic electrochemical transistors are discussed in detail concerning integrated intelligent sensing devices for sensing-adaptation-feedback-processing and low-cost commercial preparation.

关键词

有机电化学晶体管共轭分子电学性能力学特征多功能应用

Keywords

Organic electrochemical transistorConjugated moleculesElectric performanceMechanical propertiesMultifunctional application

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