马来酰胺酸-醋酸乙烯酯交替共聚物的光致发光性能及荧光水凝胶的制备

郭照琰; 高易; 茹越; 刘振杰; 张晓红; 乔金樑

doi:10.11777/j.issn1000-3304.2024.24111

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马来酰胺酸-醋酸乙烯酯交替共聚物的光致发光性能及荧光水凝胶的制备

研究论文 | 更新时间：2024-11-26

- 马来酰胺酸-醋酸乙烯酯交替共聚物的光致发光性能及荧光水凝胶的制备
- The Photoluminescent Properties of Poly(maleamic acid-alt-vinyl acetate) and Construction of Fluorescent Hydrogel
- 高分子学报 2024年55卷第9期页码：1155-1164
- 作者机构：
  
  中石化(北京)化工研究院有限公司北京 100013
- 作者简介：
  
  E-mail: qiaojl.bjhy@sinopec.com
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24111
  中图分类号：
- 纸质出版日期：2024-09-20，
  
  网络出版日期：2024-07-15，
  
  收稿日期：2024-04-11，
  
  录用日期：2024-05-11
- 稿件说明：
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郭照琰, 高易, 茹越, 刘振杰, 张晓红, 乔金樑. 马来酰胺酸-醋酸乙烯酯交替共聚物的光致发光性能及荧光水凝胶的制备. 高分子学报, 2024, 55(9), 1155-1164

Guo, Z. Y.; Gao, Y; Ru, Y; Liu, Z. J.; Zhang, X. H.; Qiao, J. L. The photoluminescent properties of poly-(maleamic acid-alt-vinyl acetate) and construction of fluorescent hydrogel. Acta Polymerica Sinica, 2024, 55(9), 1155-1164
郭照琰, 高易, 茹越, 刘振杰, 张晓红, 乔金樑. 马来酰胺酸-醋酸乙烯酯交替共聚物的光致发光性能及荧光水凝胶的制备. 高分子学报, 2024, 55(9), 1155-1164 DOI： 10.11777/j.issn1000-3304.2024.24111.

Guo, Z. Y.; Gao, Y; Ru, Y; Liu, Z. J.; Zhang, X. H.; Qiao, J. L. The photoluminescent properties of poly-(maleamic acid-alt-vinyl acetate) and construction of fluorescent hydrogel. Acta Polymerica Sinica, 2024, 55(9), 1155-1164 DOI： 10.11777/j.issn1000-3304.2024.24111.

摘要

马来酸酐-醋酸乙烯酯交替共聚物及其衍生物是一类非共轭光致发光聚合物，在防伪、转光等领域具有很好的应用前景. 本研究对自稳定沉淀聚合法制备的马来酸酐-醋酸乙烯酯交替共聚物(PMV)微球进行了酰胺化和酰亚胺化改性，制备出了光致发光的水溶性马来酰胺酸-醋酸乙烯酯交替共聚物PMVN. 通过对其光致发光性能的研究，发现其在室温和85 ℃下溶解的溶液及固体呈现出不同颜色及荧光特征，85 ℃下溶解的溶液及固体还呈现出蓝、红双发射的特性. 在此研究结果基础上，成功制备出荧光水凝胶，所制备的光致发光聚合物和荧光水凝胶在疾病诊断、防伪和环境监测等方面具有很好的应用前景.

Abstract

Poly(maleic anhydride-

alt

-vinyl acetate) (PMV) have been found as a kind of non-conjugated photoluminescent polymer with strong light emission and unique solvatochromic

effect

while its photoluminescence orginated from anhydride cluster interacting in a through-space manner. Besides

PMV could also be converted into highly-emissive or dual-emissive PMV salts through alkalization modification with sodium/lithium hydroxide. Yet in this study

self-precipated polymerized PMV microspheres were modified by amidation and imide to break maleic anhydride rings and prepare water-soluble photoluminescent poly(maleamic acid-alt-vinyl acetate) (PMVN) through simple ammonia treatment. PMVN not only exhibited photoluminescent properties in both solution and solid state

but also showed different colors and fluorescence characteristics when dissolved at different temperatures (room temperature

or 85 ℃). Microstructure analysis showed that the structures of PMVN-RT and PMVN-85 were basically the same

yet their fluorescence clusters were significantly different

which might be attributed to their different fluorescence characteristics. In addition

the color of PMVN-RT changed to green after heating

while the fluorescence clusters

solution color and fluorescence characteristics of PMVN-85 showed a trend of transforming into PMVN-RT after being placed at room temperature for 72 h. PMVN was a thermochromic photoluminescent polymer with reversible transformation characteristics. Besides

composite fluorescent hydrogels were prepared and exhibited application prospects in many fields such as temperature sensors

biosensors

disease diagnosis

cell imaging

bionic drive and environmental monitoring.

关键词

马来酸酐-醋酸乙烯酯交替共聚物荧光水凝胶自稳定沉淀聚合发光团簇蓝/红双发射聚集诱导发光

Keywords

Poly(maleic anhydride-alt-vinyl acetate) (PMV) and its derivativesFluorescent hydrogelSelf-stabilized precipitation polymerizationPhotoluminescent clustersBlue and red emissionAggregation induced emission

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