离子液体对天然橡胶/丁腈橡胶/白炭黑纳米复合材料应变软化行为的影响

李承宇; 宋义虎

doi:10.11777/j.issn1000-3304.2024.24121

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离子液体对天然橡胶/丁腈橡胶/白炭黑纳米复合材料应变软化行为的影响

研究论文 | 更新时间：2024-12-24

- 离子液体对天然橡胶/丁腈橡胶/白炭黑纳米复合材料应变软化行为的影响
- Effects of Ionic Liquid on Strain Softening Behaviors of Silica Filled Natural Rubber/Nitrile Butadiene Rubber Nanocomposites
- 高分子学报 2024年55卷第11期页码：1549-1560
- 作者机构：
  
  高分子合成与功能构造教育部重点实验室浙江大学高分子科学与工程学系杭州 310027
- 作者简介：
  
  E-mail: s_yh0411@zju.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24121
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7265
- 收稿日期：2024-04-21，
  
  录用日期：2024-05-30，
  
  网络出版日期：2024-09-11，
  
  纸质出版日期：2024-11-20
- 稿件说明：
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李承宇, 宋义虎. 离子液体对天然橡胶/丁腈橡胶/白炭黑纳米复合材料应变软化行为的影响. 高分子学报, 2024, 55(11), 1549-1560

Li, C, Y.; Song, Y. H. Effects of ionic liquid on strain softening behaviors of silica filled natural rubber/nitrile butadiene rubber nanocomposites. Acta Polymerica Sinica, 2024, 55(11), 1549-1560
李承宇, 宋义虎. 离子液体对天然橡胶/丁腈橡胶/白炭黑纳米复合材料应变软化行为的影响. 高分子学报, 2024, 55(11), 1549-1560 DOI： 10.11777/j.issn1000-3304.2024.24121. CSTR： 32057.14.GFZXB.2024.7265.

Li, C, Y.; Song, Y. H. Effects of ionic liquid on strain softening behaviors of silica filled natural rubber/nitrile butadiene rubber nanocomposites. Acta Polymerica Sinica, 2024, 55(11), 1549-1560 DOI： 10.11777/j.issn1000-3304.2024.24121. CSTR： 32057.14.GFZXB.2024.7265.

摘要

基于橡胶共混物基体的纳米复合材料在大幅振荡剪切和循环拉伸的作用下呈现应变软化行为，但因界面相互作用、相区尺寸和粒子分布等问题而少有研究涉及其调控机理和方法. 本研究采用离子液体(IL)1-丁基-3-甲基咪唑醋酸盐调控白炭黑填充天然橡胶(NR)/丁腈橡胶(NBR)并用胶纳米复合材料的相区结构、粒子分散性、硫化动力学和应变软化行为. 结果表明，IL可促进橡胶硫化，降低NBR相区尺寸和橡胶相溶胀比，提高二硫键含量. 在大幅动态剪切中，IL可减弱高填充纳米复合材料的Payne效应及其伴随的弱应变过冲行为；在大应变循环拉伸过程中，IL可在不影响滞后能密度的前提下降低软化能密度，减弱Mullins效应. 研究结果为调控白炭黑在并用胶基体中的分散性及纳米复合材料的力学性能和应变软化行为提供了实验依据.

Abstract

Rubber nanocomposites show marked strain softening under large-amplitude oscillating shear and large strain cyclic tensile deformations. Due to the interface effect

phase area size and particle distribution

the strain softening behaviors of nanocomposites based on filler filled rubber blends matrices are more complicated and there are rare methods to regulate the rubber crosslinking

phase morphology and rheological behaviors. Herein the effects of ionic liquid (IL) 1-butyl-3-methyl imidazole acetate on the phase structure

filler dispersity

vulcanization kinetics and rheological behaviors of silica filled natural rubber (NR)/butadiene nitrile rubber (NBR) nanocomposites were studied. The effects of IL of 0.1 and 1 parts per hundred parts of rubber on the nanocomposites with different silica contents were investigated to regulate their microstructure and rheological behavior. The results show that IL can promote the vulcanization of rubber

reduce the swelling ratio of vulcanizates slightly

and reduce the sizes of the rubber phases. IL can weaken the Payne effect of highly filled nanocomposites and reduce the softening energy density without affecting the hysteretic energy density accompanying the Mullins effect. The results are enlightening for adjusting the rheological behavior and mechanical properties of nanocomposites by adjusting the interaction between nanoparticles and various rubber phases.

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Keywords

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