室温下多重交联高性能高直链玉米淀粉膜的制备及性能

马小飞; 李君; 刘正平

doi:10.11777/j.issn1000-3304.2024.24236

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室温下多重交联高性能高直链玉米淀粉膜的制备及性能

研究论文 | 更新时间：2025-02-27

- 室温下多重交联高性能高直链玉米淀粉膜的制备及性能
- Preparation and Properties of High-Performance High Amylose Corn Starch Films with Multiple Crosslinking at Room Temperature
- 高分子学报 2025年56卷第3期页码：408-419
- 作者机构：
  
  北京师范大学化学学院北京 100875
- 作者简介：
  
  E-mail: lzp@bnu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24236
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7314
- 收稿日期：2024-09-13，
  
  录用日期：2024-10-31，
  
  网络出版日期：2025-01-24，
  
  纸质出版日期：2025-03-20
- 稿件说明：
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马小飞, 李君, 刘正平. 室温下多重交联高性能高直链玉米淀粉膜的制备及性能. 高分子学报, 2025, 56(3), 408-419

Ma, X. f.; Li, J.; Liu, Z. P. Preparation and properties of high-performance high amylose corn starch films with multiple crosslinking at room temperature. Acta Polymerica Sinica, 2025, 56(3), 408-419
马小飞, 李君, 刘正平. 室温下多重交联高性能高直链玉米淀粉膜的制备及性能. 高分子学报, 2025, 56(3), 408-419 DOI： 10.11777/j.issn1000-3304.2024.24236. CSTR： 32057.14.GFZXB.2024.7314.

Ma, X. f.; Li, J.; Liu, Z. P. Preparation and properties of high-performance high amylose corn starch films with multiple crosslinking at room temperature. Acta Polymerica Sinica, 2025, 56(3), 408-419 DOI： 10.11777/j.issn1000-3304.2024.24236. CSTR： 32057.14.GFZXB.2024.7314.

摘要

室温常压下高直链玉米淀粉(HACS)在水中不能溶解，这限制了其在可降解包装薄膜领域的应用. 本文中采用四丁基氢氧化铵(TBAH)水溶液作为溶剂，实现了室温常压下HACS的溶解，并通过分子链的多重交联(同时具备物理交联、配位键交联和共价键交联)制备了高性能HACS薄膜. 采傅里叶红外光谱、原子力显微镜、X射线衍射及拉伸实验表征了薄膜的结构、表面形貌、结晶性及力学性能. 结果表明，与单重物理交联和双重交联(物理-配位键交联、物理-共价键交联)的HACS膜相比，多重交联薄膜的表面粗糙度和结晶性均更低，薄膜的力学性能更强，断裂伸长率为65%，拉伸强度达3.18 MPa. 本文工作为开发高性能淀粉基薄膜材料提供了新的思路和方法.

Abstract

High amylose corn starch (HACS) is insoluble in water at room temperature and atmospheric pressure

which limits its applications in biodegradable packaging films. This study employed a tetrabutylammonium hydroxide (TBAH) aqueous solution as a solvent to achieve the dissolution of HACS at room temperature and atmospheric pressure. Subsequently

high-performance HACS films were fabricated through multiple crosslinking of polymer chains

including physical

coordination

and covalent crosslinking. The structure

surface morphology

crystallinity

and mechanical properties of the films were characterized using infrared spectroscopy

atomic force microscopy

X-ray diffraction

and tensile testing. Results demonstrated that compared to HACS films with single physical crosslinking and double crosslinking (physical-coordinated crosslinking and physical-covalent crosslinking)

the multiple crosslinked films exhibited lower surface roughness and crystallinity

along with enhanced mechanical properties. The multiple crosslinked films exhibited a tensile strength of 3.18 MPa and an elongation at break of 65%. This study provides a novel approach and strategy for the development of high-performance starch-based film materials.

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references

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