溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜

王亚欣; 陈于蓝

doi:10.11777/j.issn1000-3304.2024.24259

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溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜

研究论文 | 更新时间：2025-04-01

- 溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜
- A Solvent/Light Dual Responsive Inverse Opal Photonic Crystal Polymer Composite Film
- 高分子学报 2025年56卷第4期页码：590-597
- 作者机构：
  
  1.天津大学理学院天津 300350
  2.吉林大学化学学院长春 130012
- 作者简介：
  
  E-mail: yulanchen@jlu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 21975178)
- DOI：10.11777/j.issn1000-3304.2024.24259
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7323
- 收稿日期：2024-10-25，
  
  录用日期：2024-11-15，
  
  网络出版日期：2025-02-21，
  
  纸质出版日期：2025-04-20
- 稿件说明：
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王亚欣, 陈于蓝. 溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜. 高分子学报, 2025, 56(4), 590-597

Wang, Y. X.; Chen, Y. L. A solvent/light dual responsive inverse opal photonic crystal polymer composite film. Acta Polymerica Sinica, 2025, 56(4), 590-597
王亚欣, 陈于蓝. 溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜. 高分子学报, 2025, 56(4), 590-597 DOI： 10.11777/j.issn1000-3304.2024.24259. CSTR： 32057.14.GFZXB.2024.7323.

Wang, Y. X.; Chen, Y. L. A solvent/light dual responsive inverse opal photonic crystal polymer composite film. Acta Polymerica Sinica, 2025, 56(4), 590-597 DOI： 10.11777/j.issn1000-3304.2024.24259. CSTR： 32057.14.GFZXB.2024.7323.

摘要

以结构色光子晶体材料为模板，将偶氮苯与丙烯酸酯类单体和交联剂共聚，通过聚合物亲疏水性的调控，成功制备了一种对溶剂和光双重刺激响应的反蛋白石结构复合薄膜. 通过测试薄膜的反射光谱和接触角，确定了聚合物的最佳组成. 利用不同直径的二氧化硅光子晶体获得的薄膜在不同溶剂中实现了可见光范围的宽波段反射. 这种具备双重响应性质的复合薄膜在紫外光照射下可以写入信息，并在干燥环境中加密图案，而在溶剂中能够快速、高对比度地显示图案，有望应用于高级别的防伪、信息加密与存储、传感等领域.

Abstract

Recently

photonic crystals and their composite films have attracted much attention due to their unique optical properties and promising applications in optical sensors

optical communication

anti-counterfeiting techniques and so on. Photonic crystal-polymer composite films with multimodal responsiveness are highly desirable yet still limited. In this work

a new kind of inverse opal composite polymer films responsive to both solvent and light has been successfully prepared

by copolymerizing azobenzene (AzoMMA) with different hydrophilic/hydrophobic acrylic monomers (butyl methacrylate (BMA)

poly(ethylene glycol) acrylate (PEGDA)) and cross-linking agent (ethoxylated trimethylolpropane triacrylate (ETPTA)) and using structural colored photonic crystals as the template. The optimal composition of the polymers is determined (AzoMMA:PEGDA:BMA:ETPTA = 1:4:8:1

molar ratio) according to the reflection spectra and contact angle testing. Wideband visible light reflection is achieved for films that are obtained by using silica photonic crystals with different diameters and in different solvents. This composite film with dual responsive properties can be used to store information under ultraviolet light irradiation

encrypt patterns in its dry state

and decrypt the information quickly and with a high-contrast visual effect in solvents. This material is thus expected to be applied in high-level anti-counterfeiting

encryption storage of information

sensing and other fields.

关键词

Keywords

references

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