聚醚酮酮静电纺纳米纤维的细化及高温过滤应用研究

张允; 何丽萍; 李坤鹏; 俞建勇; 丁彬; 张骁骅

doi:10.11777/j.issn1000-3304.2025.25010

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聚醚酮酮静电纺纳米纤维的细化及高温过滤应用研究

研究论文 | 更新时间：2025-06-18

- 聚醚酮酮静电纺纳米纤维的细化及高温过滤应用研究
- Electrospinning of Polyetherketoneketone: Strategy of Fiber Refinement and High Temperature Filtration Application
- 高分子学报 2025年56卷第6期页码：1002-1013
- 作者机构：
  
  东华大学纺织学院纺织科技创新中心上海 201620
- 作者简介：
  
  E-mail: zhangxh@dhu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 52373031);江苏省产业前瞻与关键核心技术项目(BE2023077)
- DOI：10.11777/j.issn1000-3304.2025.25010
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7372
- 收稿日期：2025-03-07，
  
  录用日期：2025-03-26，
  
  网络出版日期：2025-04-29，
  
  纸质出版日期：2025-06-20
- 稿件说明：
移动端阅览
张允, 何丽萍, 李坤鹏, 俞建勇, 丁彬, 张骁骅. 聚醚酮酮静电纺纳米纤维的细化及高温过滤应用研究. 高分子学报, 2025, 56(6), 1002-1013

Zhang, Y.; He, L. P.; Li, K. P.; Yu, J. Y.; Ding, B.; Zhang， X. H. Electrospinning of polyetherketoneketone: strategy of fiber refinement and high temperature filtration application. Acta Polymerica Sinica, 2025, 56(6), 1002-1013
张允, 何丽萍, 李坤鹏, 俞建勇, 丁彬, 张骁骅. 聚醚酮酮静电纺纳米纤维的细化及高温过滤应用研究. 高分子学报, 2025, 56(6), 1002-1013 DOI： 10.11777/j.issn1000-3304.2025.25010. CSTR： 32057.14.GFZXB.2025.7372.

Zhang, Y.; He, L. P.; Li, K. P.; Yu, J. Y.; Ding, B.; Zhang， X. H. Electrospinning of polyetherketoneketone: strategy of fiber refinement and high temperature filtration application. Acta Polymerica Sinica, 2025, 56(6), 1002-1013 DOI： 10.11777/j.issn1000-3304.2025.25010. CSTR： 32057.14.GFZXB.2025.7372.

摘要

基于高分子的纤维过滤材料应用广泛，然而利用工程热塑性树脂开发耐高温过滤应用受到湿法纺丝难、纤维不易细化的限制. 采用高性能工程塑料聚醚酮酮作为原材料，利用其可溶解特性，在三氟乙酸溶液中，通过静电纺丝制备了纳米纤维膜，研究了纤维直径和形貌的调控规律，及其高温过滤应用特性. 研究表明：纤维平均直径可细化至87 nm，纤维膜孔径可降低至293 nm，断裂强度可达7.77 MPa；纤维膜展现出优异的过滤性能，在6 μm厚度下过滤效率即可高于99.9%；纤维膜在300 ℃仍保持良好的形貌结构以及力、热性能，表现出优异的高温空气过滤特性.

Abstract

Polymer-based fibrous filtration materials are widely used

however

the development of high-temperature filtration application using engineering thermoplastics is limited by the difficulty of wet spinning and fiber refinement. In this paper

a nanofibrous membrane was prepared by electrospinning using the high performance engineering polymer polyetherketoneketone (PEKK)

which can be dissolved in trifluoroacetic acid. And the regulation laws of the fiber diameter and morphology were investigated

as well as its characteristics for high temperature filtration application. The average diameter of the fiber can be refined to 87 nm

the pore size of the fiber membrane can be reduced to 293 nm

and the tensile strength can reach 7.77 MPa. The fiber membrane shows excellent filtration performance with the filtration efficiency of higher than 99.9% at a thickness of 6 μm. The fiber membrane maintains a good morphological structure

force

thermal properties

and high-temperature air filtration properties at 300 ℃.

关键词

Keywords

references

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